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Lower Carboniferous bentonites in the Bardo Structural Unit (central Sudetes): geological context, petrology and palaeotectonic setting

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Ge olo gia Sudetica, 2008, 40: 19–31.

Lower Car bon if er ous bentonites

in the Bardo Struc tural Unit (cen tral Sudetes):

geo log i cal con text, pe trol ogy and pa laeo tec tonic set ting

Ryszard Kryza, Jolanta Muszer, Czes³aw Au gust, Joanna Haydukiewicz & Marta Jurasik

Uni ver sity of Wroc³aw, In sti tute of Geo log i cal Sci ences, ul. Cybulskiego 30, 50-205 Wroc³aw, Po land; e-mails:

ryszard.kryza@ing.uni.wroc.pl; jolanta.muszer@ing.uni.wroc.pl; czeslaw.au gust@ing.uni.wroc.pl; joanna.haydukiewicz@ing.uni.wroc.pl Key words: ben ton ite, zir con, SHRIMP geo chron ol ogy, Viséan, Bardo Unit, Sudetes.

Ab stract

The Lower Car bon if er ous Paprotnia beds of the Bardo Struc tural Unit in the cen tral Sudetes, com posed pre dom i nantly of mudstones with Up per Viséan fos sils, in clude sev eral ben ton ite lay ers. The bentonites, com posed mainly of kaolinite, illite/smectite and smectite, with mi nor amounts of quartz, cal cite and iron hy drox ides, also con tain abun dant zir cons, the fea tures of which in di cate their vol ca nic der i va tion. The main pop u la tion of the zir cons yielded a SHRIMP U-Pb age of ~ 334 Ma cor re spond ing with, and nu mer i cally con strain ing, the biostratigraphic data. The field ev i dence, biostrati- graphic and geo chron ol ogi cal re sults, to gether with min er al og i cal data from the bentonites, in di cate con ti nen tal mar - gin-type sed i men ta tion and con tem po ra ne ous vol ca nic (andesitic-rhyolitic) ac tiv ity in the neigh bour ing re gion dur ing the on go ing Variscan orog eny in cen tral Eu rope in Late Viséan times.

Manu script re ceived 9 June 2008, ac cepted 24 November 2008

IN TRO DUC TION

Vol ca nic erup tions are re corded in the strati graphic suc ces sions through out the Car bon if er ous and Perm ian in cen tral Eu rope, re flect ing in tense tectonothermal and mag matic ac tiv i ties dur ing the Variscan orog eny. We find these re cords in molasse-fill intramontane and fore land bas ins, and in ma rine sed i men tary suc ces sions. Apart from their palaeoenvironmental and palaeotectonic sig na ture, the vol ca nic ma te ri als of ten pro vide a re li able tool for geo - chron ol ogi cal stud ies and, thus, for chronostratigraphic con trol of orog eny-re lated geo log i cal pro cesses.

Spe cial at ten tion is at tracted by fall-out tephras that can be pre served in sed i men tary se quences as tonsteins and bentonites. They are mainly com posed of sec ond ary clay min er als (mostly af ter devitrified vol ca nic glass par ti cles), with mi nor pri mary vol ca nic com po nents and, con se - quently, they of ten are of eco nomic in ter est as re gards their spe cific clay con tent. How ever, typ i cally, they also con tain ac ces sory vol ca nic min er als, in clud ing zir con and ap a tite, use ful for geo chron ol ogy and thus for con strain - ing the age of vol cano-sed i men tary pro cesses.

Volcaniclastic de pos its, in clud ing bentonites and sed i - men tary rocks gen er ally re ferred to as tuffites, have been

re ported from Si lu rian through Car bon if er ous suc ces sions in the Sudetes at the NE edge of the Bo he mian Mas sif (Fig.

1; Porêbska & Koszowska, 2001; Au gust et al., 2003).

How ever, in most cases, they have not yet been sys tem at i - cally stud ied.

This pa per de scribes the bentonites in the Up per Viséan Paprotnia beds (called the “Paprotnia se ries” in ear - lier works; Haydukiewicz & Muszer, 2002) in the west ern part of the Bardo Struc tural Unit (¯elaŸniewicz & Alek- sandrowski, 2008; here af ter, for sim plic ity, the Bardo Unit) in the cen tral Sudetes, SW Po land. The dis tri bu tion of the ben ton ite lay ers is shown against a de tailed litho-s tratigraphic log. Min er al og i cal and geo chem i cal char ac ter - is tics are given to es tab lish the pri mary na ture of these de - pos its. The biostratigraphic and iso to pic age con straints (de scribed in de tail in a sep a rate pa per, Kryza et al., 2009, in prep.) are re ferred to, as well as palaeoenvironmental ev i dence, to pro pose a gen eral palaeotectonic sce nario of the late Viséan ba sin in which the bentonites of the Paprotnia beds were de pos ited, within the frame work of the on go ing Variscan orog eny and as so ci ated vol ca nic ac - tiv ity.

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GEO LOG I CAL SET TING AND THE LITHOSTRATIGRAPHY OF THE BARDO SUC CES SIONS

The Bardo Unit in the cen tral Sudetes (Fig. 1) is com - posed of Palaeozoic allochthonous and autochthonous/

parautochthonous sed i men tary suc ces sions (Wajsprych, 1986, 1995). The allochthonous suc ces sion con tains large olistoliths of Lower Palaeozoic (Or do vi cian and Si lu rian) and De vo nian deep ma rine strata, em bed ded in Viséan wildflysh (Haydukiewicz, 1990), whereas the autochtho- nous/parautochthonous suc ces sion is com posed of Up per De vo nian – Lower Car bon if er ous strata (Fig. 2), capped by the flysch de pos its. The autochthonous suc ces sion is in - ter preted to rep re sent sed i men ta tion in an evolv ing intra- montane or con ti nen tal-mar gin ba sin dur ing the Variscan

orog eny. The suc ces sion was folded at the turn of the Early/Late Car bon if er ous into E–W trending folds and sub se quently re folded dur ing the Late Car bon if er ous into NE–SW trending folds (Oberc, 1972).

The lithostratigraphic log of the Bardo autochtho- nous/parautochthonous suc ces sions (Fig. 3) is com posed, ac cord ing to Wajsprych (1995), of sev eral in for mal units:

for ma tions, “se ries” and se quences. Al though their age is based on palaeontological data, the re con struc tion of the pri mary strati graphic suc ces sion is dif fi cult be cause of the com pli cated tec tonic frame work. The old est sed i men tary rocks in the autochthonous suc ces sion, the Wapnica For - Fig. 1. Geo log i cal sketch map of the Sudetes (mod i fied from Aleksandrowski et al., 1997; unit and struc ture names af ter ¯elaŸniewicz

& Aleksandrowski, 2008). BU – Bardo Struc tural Unit; ISF – Intra-Sudetic Fault; KMM – K³odzko Meta mor phic Mas sif; KZG – K³odzko-Z³oty Stok Gran ite Pluton; KZ – Kamieniec Z¹bkowicki Meta mor phic Belt; LI – Lusatia-Izera Mas sif; NZ – Niemcza Shear Zone; MSF – Mar ginal Sudetic Fault; SSG – Strzegom-Sobótka Gran ite Pluton; SZ – Skrzynka Shear Zone; ŒU – Œwiebodzice Struc tural Unit. In set: hachure – pre-Perm ian crys tal line rocks; EFZ – Elbe Fault Zone; ISF – Intra-Sudetic Fault; MGH – Mid-Ger man Crys tal - line High; MO – Moldanubian Zone; MS – Moravo-Silesian Zone; NP – North ern Phyllite Zone; OFZ – Odra Fault Zone; RH – Rhenohercynian Zone; SX – Saxothuringian Zone. Age as sign ments: Pt3 – Neoproterozoic; Cm – Cam brian; Or – Or do vi cian; D – De - vo nian; C – Car bon if er ous; Pz1 – Early Palaeozoic. Rect an gle shows the lo ca tion of Fig. 2.

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ma tion (Fig. 3), are rep re sented by ma rine car bon ates (gab - bro and lime stone brec cia, basal lime stone, main lime - stone, and Clymenia and Gattendorfia lime stones); they range in age from the Up per De vo nian (the lower part of this suc ces sion prob a bly rep re sents Frasnian, whereas the over lay ing main and Clymenia lime stones be long to the Famennian – from marginifera to the Lower praesulcata cono dont zones; see Haydukiewicz, 1990) to the Lower Tournaisian (Gattendorfia stage; Weyer, 1965; Dzik, 1997). They are about 60 me ters thick and oc cur only in some iso lated out crops along the west ern edge of the Bardo Unit (Fig. 2). The next lithostratigraphic unit is the Go³og³owy For ma tion – fragmentarily pre served as dark gray or black si li ceous and clayey shales, up to sev eral cen - ti me ters thick. They con tain early Tournaisian cono donts (Haydukiewicz, 1990). These shales are over lain by the Nowa Wieœ For ma tion and the Wojbórz For ma tion, the lat ter com posed mainly of cal car e ous de pos its, for merly

known as the “Kohlenkalk” lime stone (Oberc, 1957, and ref er ences therein). The Nowa Wieœ For ma tion is found only in the north ern part of the Bardo Unit and is com - posed of coarse-grained turbidite siliciclastic- to boul - der-bear ing mass-flow de pos its, con tain ing both crys tal - line (mostly gneiss) and car bon ate (mostly bioclastic lime - stone) clasts (Wajsprych, 1995). The Nowa Wieœ For ma - tion is more than 300 m thick and it is of early Car bon if er - ous age, from the late Tournaisian to early Viséan, doc u - mented by cono donts and foraminifers (G³uszek &

Tomaœ, 1993; Chorowska & Radlicz, 1994). A strati - graphic equiv a lent of this unit in cen tral part of the Bardo Unit is prob a bly the Wojbórz For ma tion, com posed of lithic brec cias with in ter ca la tions of bioclastic lime stone and volcaniclastic brec cias (Wajsprych, 1995).

Ac cord ing to Wajsprych (1995), the prob a ble next lithostrati graphi cal unit is the “Winna Góra se quence”, which con sists of sev eral var ied fa cies, one of them be ing

LOWER CAR BON IF ER OUS BENTONITES, SUDETES

21

Fig. 2. Geo log i cal map of the Bardo Struc tural Unit and lo ca tion of the Paprotnia site (based on Oberc, 1957 and Haydukiewicz &

Muszer, 2002).

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called the Paprotnia beds. The Paprotnia beds oc cur only in the west ern part of the Bardo Unit (Fig. 2) and it is com - posed of claystones in its lower part, and mudstones and greywackes in its mid dle and up per part. Car bon ate in ter - ca la tions are sub or di nate. The de pos its con tain abun dant ben thic fos sils, whereas nektonic spe cies are less nu mer - ous. The palaeontological re cord in di cates that the Paprot- nia beds be long to the ammonoid G. crenistria zone,

which cor re sponds with the Asbian (re gional substage) of the Up per Viséan (V3b) (Haydukiewicz & Muszer, 2002).

The Paprotnia beds con tain sev eral thin (2–10 cm) ben ton - ite lay ers (Haydukiewicz & Muszer, 2002). This unit is over lain by polymictic con glom er ates with sand stone and mudstone in ter ca la tions of the Wilcza beds (Figs 3, 4;

Wajsprych, 1995).

Fig. 3. Gen er al ized lithostratigraphic scheme of the Bardo autochthonous/parautochthonous suc ces sions (ac cord ing to Wajsprych, 1995, mod i fied).

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The Srebrna Góra For ma tion, up to 450 m thick, and rep re sent ing the allochthonous suc ces sion (Fig. 3) is found only in the north-east ern part of the Bardo Unit (Wajs- prych, 1995). It is de scribed as a flysch and wildflysch se - quence com posed of lithologies of the Zdanów-Bardo- M³ynów “subcomplex” (Wajsprych, 1986, 1995). The as - sumed mid dle- or up per Viséan age of the Srebrna Góra For ma tion is based on the un der ly ing and paleontologi- cally doc u mented Nowa Wieœ For ma tion (Chorowska &

Radlicz, 1994) of the autochthonous suc ces sion, and on the last find ing of the strobilus (Flemingites or Lepido- strobus) in a clayey-mudstone bed of the Srebrna Góra For - ma tion (Muszer & Haydukiewicz, 2006). Ac cord ing to Wajsprych (1995), a range of fea tures (e.g. peb ble com po si - tion, pres ence of spe cific lithological slabs, slide sheets and olistoliths) sug gest a cor re la tion of the Wilcza beds with the Srebrna Góra For ma tion.

The Srebrna Góra wildflysch is over lain by the Orzech “se quence”, which is the higher flysch unit, but com posed mostly of volcaniclastic ma te rial (Wajsprych, 1995). The up per most lithostratigraphic unit in the north - ern part of the Bardo Unit is the W³óczek “se quence” (Fig.

3), com posed of terrigenic sed i men tary ma te rial (see Wajs- prych, 1995), which is prob a bly up per most Viséan in age.

METH ODS

Our de tailed stud ies of the bentonites re fer to the pre - vi ous field and strati graphi cal in ves ti ga tions car ried out by Haydukiewicz and Muszer, and the strati graphic meth ods used were de scribed in the pre vi ous pa per (Haydukiewicz

& Muszer, 2002).

LOWER CAR BON IF ER OUS BENTONITES, SUDETES

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Fig. 4. The Paprotnia sec tion – lithological col umn and dis tri bu - tion of taphocoenoses (des ig nated as I – V). A – G = ben ton ite lay ers. (based on Haydukiewicz & Muszer, 2002).

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Sev eral ben ton ite sam ples (~ 1 kg each) from all six ben ton ite lay ers (des ig nated as A to F on Fig. 4) in the Paprotnia beds were col lected for min er al og i cal and petro- graphic in ves ti ga tions. The min er al og i cal in ves ti ga tions of the bentonites in cluded X-ray dif frac tion (SIEMENS D5005, Co ra di a tion, Fe fil ter) and com plex ther mal ana- lysis: DTA, TGA, DTG (DERIVATOGRAPH 1500Q).

Sep a ra tion of the clay frac tion and treat ment with gly col were done fol low ing Jack son’s pro ce dure (Kulesza- Wiewióra & Wojciechowski, 1980). The smectite pro por - tion in illite/smectite (I/S) min er als and their or der ing were mea sured based on the rel a tive in ten sity of peaks (002) and (003), us ing Œrodoñ’s (1984) method. The paleo- tem per a tures of clay min eral for ma tion were cal cu lated ac cord ing to Šucha et al. (1993).

The heavy min eral frac tion was sep a rated us ing the con ven tional heavy liq uid (so dium polytungstate) pro ce - dure. Care ful ex am i na tion un der the po lar iz ing mi cro - scope (Jurasik, 2006) helped to se lect one sam ple (A) for SHRIMP dat ing.

Here, we pres ent the re sults of field stud ies (re fer ring also to the ear lier pub lished data), min er al og i cal and pet ro - log i cal char ac ter is tics of the bentonites, biostratigraphic and geo chron ol ogi cal age con straints and, fi nally, the palaeoenvironmental and palaeotectonic sce nario within the frame work of Variscan orogenic and vol ca nic ac tiv ity.

The geo chron ol ogi cal data and their strati graphic in fer - ences are dis cussed in a sep a rate pa per (Kryza et al., 2009, in prep.).

RE SULTS

Field ob ser va tions

The best ex po sure of the Paprotnia beds is lo cated in the west ern part of the Bardo Unit (Fig. 2). As yet, these beds have not been doc u mented in the east ern and south - ern parts of the Bardo Unit, so they might be bur ied there un der the allochthonous suc ces sions (Wajsprych, 1995).

The sec tion stud ied is ex posed on the south ern slope of Papro- tnia hill, about 1.5 km east of the vil lage of Czer- wieñczyce, in the road-es carp ment of the path from Czer- wieñczyce to Wojbórz.

The ex posed sec tion of the Paprotnia beds, about 13.7 m thick (Fig. 4), are mainly com posed of shales (claystone and mudstone), greywackes and sub or di nate car bon ates.

Six in ter ca la tions of thin pale-yel low ben ton ite lay ers were also ob served in sev eral ho ri zons. The strata dip at 50-60° to the north. Un for tu nately, the con tact with the un der ly ing suc ces sion is not ex posed. In the top most part of the sec tion, the Paprotnia beds pass grad u ally into poly- mictic con glom er ates of the Wilcza beds (Fig. 3; Wajs- prych, 1995), ap par ently her ald ing the allochthonous successin.

The low er most part of the sec tion com prises green - ish-grey and grey clayey and silty shales. Their in di vid ual lay ers are sev eral centi metres thick; some of them are thin lam i nated. The shales are mainly com posed of quartz, feld - spars, chlorite, clay min er als and cal cite. A few in ter ca la - tions of thin dark-grey micritic lime stone (beds up to 3 cm thick) oc cur within the shales. These de pos its are over lain by dark-grey and dark-ol ive shales. Up wards, they are in - ter ca lated with thin (2–4 cm) lay ers of grey claystones and greywackes. In this part of the sec tion, six ben ton ite lay - ers, as signed as A–F, and 1–10 cm thick, were as cer tained (Fig. 4). Also, ir reg u larly dis trib uted small mudstone nod - ules can be found within the 5.3 m thick shale pack age.

The mid dle part of the sec tion com prises sandy- muddy shales and greywackes with lenses and nod ules of dark-grey organodetrital lime stones, which usu ally form dis tinct ho ri zons. The abun dance of the car bon ate lenses

sharply de creases up wards. In most cases, the lower part of a given lens is com posed of bioclastic packstone, whereas its up per part con sists of poorly fossiliferous fine-grained wackestone. The lenses are up to 40 cm thick.

The mid dle part of the sec tion is over lain by grey- wackes con tain ing rare sandy and muddy shale in ter ca la - tions. These greywackes ter mi nate the Paprotnia beds and are over lain by the polymictic Wilcza con glom er ates (Fig. 4).

Biostratigraphic ev i dence – a re view

The Paprotnia beds con tain a very rich palaeontolo- gical re cord, stud ied ear lier by many ge ol o gists and palae- ontologists (see Schmidt, 1925; Paeckelmann, 1930, 1931;

Kuhne, 1930; Górecka, 1958; ¯akowa, 1963; Górecka &

Mamet, 1970; Fedorowski, 1971). In most cases, these in - ves ti ga tions were re stricted to de ter min ing the spe cies com po si tion of se lected sys tem atic groups, and to de fin ing the chronostratigraphical af fil i a tion of their host strata.

Only Górecka (1958) and Fedorowski (1971) de scribed the ver ti cal dis tri bu tion of cer tain groups (flora and cor als) and most abun dant other fos sils pres ent in this sec tion.

More re cently, Haydukiewicz and Muszer (2002) stud ied the beds and their palaeontological re cord in de tail. Anal y - sis of the strati graphic dis tri bu tion of the fos sils, the char - ac ter of their ac cu mu la tion, their state of pres er va tion and their tax o nomic com po si tion were used by these au thors to re con struct the en vi ron men tal con di tions un der which the or gan isms might have ex isted.

The age of the Paprotnia beds were de ter mined based on the find ings of brachi o pods, goniatites, cor als and fora- minifers (Schmidt, 1925; Paeckelmann, 1930, 1931; Gó- recka & Mamet, 1970; Fedorowski, 1971, Haydukiewicz

& Muszer, 2002). Goniatites are poorly pre served and most of them rep re sent the gen era Goniatites and Nomi- smoceras. The pres ence of Goniatites crenistria Phill. is ev i - dence of a Late Viséan age (IIIa crenistria dobe) of these de - pos its (Haydukiewicz & Muszer, 2002). Ac cord ing to

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Górecka & Mamet (1970), foraminifers that oc cur in this lo cal ity are char ac ter is tic of the Archaediscus karreri-How- chinia gibba-Valvulinella youngi Zone co in cid ing with the crenistria IIIa Zone. Fedorowski (1971), ana lys ing the fre - quency of var i ous spe cies of rugose coral, rec og nized a few as sem blages that are typ i cal of the D2 coral zone of the Brit ish no men cla ture. Fur ther more, the sclerotioid grains oc cur ring in these de pos its (see Haydukiewicz & Muszer, 2002) have never been found in de pos its older than the Up per Viséan (Bless et al., 1976). Con se quently, the palae- on to log i cal re cord in to tal in di cates that the beds be longs

to the ammonoid G. crenistria Zone which cor re sponds with the Asbian (re gional substage) of the Up per Viséan (V3b) (Haydukiewicz & Muszer, 2002).

The macrofossils from the Paprotnia sec tion rep re sent tax o nom i cally di verse ben thic and nektonic as sem blages (see Haydukiewicz & Muszer, 2002). The rich ben thic fauna is clearly dom i nated by brachi o pods and cor als (mainly co lo nial rugosa). Pelecypods, gas tro pods, frag - ments of cri noids, bryozoa col o nies, and trilobites are com mon. Nu mer ous ichnofossils, the rich ness of which in creases up wards, are also pres ent. They are mostly rep -

LOWER CAR BON IF ER OUS BENTONITES, SUDETES

25

Fig. 5. Mod els of com mu ni ties (taphocenoses) in the Paprotnia beds (see text for de scrip tion). Taphocenoses: I – mid- or outer shelf, ox y gen-de fi cient wa ters be low wave base; II – ox y gen ated wa ters, be tween the storm wave and fair weather wave base; III – tur bu lent en vi ron ment, well-ox y gen ated, warm shal low wa ter of subtidal sea; IV – shal low sea floor, short pe ri ods of low-en ergy in ter rupted by rapid terrigenic in puts; V – land-prox i mal en vi - ron ment, short trans por ta tion dis tance.

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re sented by bur rows, feed ing (fodinichnia) and dwell ing (domichnia) traces. Fos sils of nektonic or gan isms, such as goniatites and nautiloids, are less com mon. The strata of this sec tion also con tain microfossils: ostracods, foramini- fers, nu mer ous frag ments of cal car e ous al gae, dif fer ent kinds of cal car e ous tubes and spines (some of them are prob a bly of polychaetid and brachi o pod or i gin). The macrofloral el e ments (larger frag ments of fern leaves and lycopsids, sphenopsid and horse tail stems), di min u tive plant de bris and sclerotioid grains are dis trib uted in nearly all the lithologies. Small frag ments of fos sil char coal are also com mon through out this sec tion.

Five taphocoenoses, dif fer ing in the rel a tive abun - dance of par tic u lar tax o nomic groups and the size and state of pres er va tion of spec i mens, were de scribed in the the Paprotnia sec tion (Haydukiewicz & Muszer, 2002).

Their ver ti cal suc ces sion is co in ci den tal with changes in li - thol ogy (Fig. 4).

The main com po nents of taphocoenosis I are gonia- tites and orthoconic nautiloids, small spiriferids, thin-shel- led chonetids, productids (Chonetipustula), gas tro pods (Ptychomphalus) and scarce pelecypods (mainly Aviculo- pecten, Streblochondria, Protoschizodus) (Ta ble 1). Terres- tial plant de tri tus with some dis tin guish able frag men tary horse tail stems and fern leaves are also abun dant. The ben - thic com mu nity is mainly rep re sented by epifaunal sus - pen sion and de posit feed ers, which in hab ited a clayey- muddy soft ground.

Taphocoenosis I may have been de pos ited in mid- or outer shelf con di tions. The low tax o nomic di ver sity of this com mu nity, the small size of ben thic taxa, the thin shells and lack of bioturbation may in di cate ox y gen-de fi - cient bot tom wa ters (see Kammer et al., 1986). The thinly lam i nated sed i ment and lack of signs of trans port of the

ben thic skel e tal ma te rial sug gests a quiet wa ter en vi ron - ment be low wave base (Fig. 5).

Taphocoenosis II, com pared to the pre vi ous one, is en riched in sol i tary rugose cor als, frag ments of cri noid columnals, trilobites and bryo zoan col o nies, whereas the rel a tive abun dance of cepha lo pods de creases (Fig. 5). The fos sils of this com mu nity are usu ally ir reg u larly dis persed in a pack age of shales con tain ing greywacke in ter ca la tions and thin ben ton ite lay ers. A de crease in the amount of ben thic fauna is no tice able within the greystone in ter ca la - tions (con tain ing only scarce shell de bris and plant re - mains) and in the in ter val of shales with thin ben ton ite lay ers (A–D), and just be low the thick est one (E). How - ever, above this last layer, a pro gres sive in crease is docu- mented (Haydu- kiewicz & Muszer, 2002).

Taphocoenosis II was most likely ac cu mu lated in an en vi ron ment lo cated be tween the storm wave and fair weather wave bases, in ox y gen ated wa ter. The pro gres sive in crease in spe cies rich ness in this taphocoenosis com - pared to the pre vi ous one, the dom i nance of epifaunal sus - pen sion feed ers, and the pres ence of bioturbation in the host sed i ment may be re garded as ev i dence of aer o bic con - di tions. The ben thic or gan isms of this taphocoenosis may have ex isted in an en vi ron ment with a grad u ally in creas - ing in flux of terrigenic ma te rial and bot tom wa ter tur bu - lence. In ter ca la tions of greywackes con tain ing only shell de bris and flo ral re mains (horse tail stems, fern leaves) may in di cate short ep i sodes of rapid clastic de liv ery from the in shore part of the sed i men tary ba sin. The pro gres sive in - crease of fos sils, re corded above the thick est ben ton ite layer, may in di cate wa ter fer til iza tion, which could lead to in ten si fi ca tion of phytoplankton and zoo plank ton de vel - op ment, which in turn could en cour age the growth of sus - pen sion-feed ers.

Ta ble 1 Gen eral char ac ter is tics of the five taphocoenoses de fined in the Paprotnia beds

(based on Haydukiewicz & Muszer, 2002)

Taphocoenosis I II III IV V

Com po nents

goniatites, orthoconic nautiloids, small spiriferids, thin-shelled chonetids, productids,gas - tro pods, scarce pelcypods, ostracods, foraminifers, al gal de tri tus, cal car e ous spines, terrestial plant de - tri tus, epifaunal sus pen - sion, de posit feeders

sol i tary rugosa, crinoidal columnals, trilobites, bryo zoans, few cepha lo - pods, spiriferids, productids, chonetid valves, foraminifers, ostracods, cal car e ous al gal re mains, ichnofossils, ses - sile epifauna (brachi o - pods, cor als, bryo zoans), free-bur row ing bi valves, shal low bur row ers, rare cri noids, trilobites, gas - tro pods, cephalopods

fre quent benthonic or - gan isms, de creas ing amount of goniatites and nautiloids, bush cor als (Lithostrotion, Diphyphyllum), productoid valves, brachi o pods, chonetids, rare spiriferids, al gal de bris, ostracods, foraminifers, trace fos sils (bur rows)

scarce brachi o pods, infaunal pelecypods, bryo zoans, crinoidal stems, foraminifers, ostracods, small gas tro - pods, cal car e ous al gae de - tri tus, trace fos sils (burrows)

plant fos sils only, fau nal re mains ab sent, asterocalamite stems, lepidodendron, fern leaves and seeds

Dom i nant li thol ogy

lam i nated clayey-muddy shales

muddy shales, greywacke in ter ca la tions,ben ton ite lay ers

mudstones,organodetrital lime stone lenses

greywackes,muddy shale

in ter ca la tions greywackes

En vi ron ment

mid- or outer shelf, ox y - gen-de fi cient wa ters be - low wave base

ox y gen ated wa ters, be - tween the storm wave and fair weather wave base

tur bu lent en vi ron ment, well-ox y gen ated, warm shal low wa ter of subtidal sea

shal low sea floor, short pe ri ods of low-en ergy in - ter rupted by rapid terrigenic in puts

land-prox i mal en vi ron - ment, short trans por ta - tion dis tance

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The fauna of as sem blage III de vel oped in a tur bu lent en vi ron ment of well-ox y gen ated and rel a tively warm shal - low wa ter. The rel a tively high fre quency of par tic u lar ben thic or gan isms, the de crease in the amount of gonia- tites and the grad ual dis ap pear ance of nautiloids is char ac - ter is tic of this taphocoenosis (Fig. 5).

The di verse ben thic biota, the rem nant of which is rep re sented by the fos sils of taphocoenosis III, oc cur ring in the mid dle part of the sec tion, is one which col o nized a shal low subtidal sea floor with mod er ate to pe ri od i cally higher en ergy con di tions. It can be as sumed that the or - gan isms of this com mu nity lived in tur bu lent con di tions in shal low well-ox y gen ated wa ters, and that the abun - dance of cor als and dasycladales may in di cate a rel a tively warm-wa ter en vi ron ment.

The or gan isms of taphocoenosis IV re flect re newed set tling of the shal low seafloor dur ing a short pe riod of low en ergy con di tions in ter rupted by the rapid de liv ery of a large quan tity of terrigenic de pos its. It is com posed of scarce, di min u tive brachi o pods, infaunal pelecypods Edmondia, frag ments of bryo zoan col o nies and cri noid stems (Fig. 5). The macrofossils are usu ally fragmentally pre served and as so ci ated with foraminifers, ostracods, small gas tro pods and cal car e ous al gae de tri tus, which is only dis trib uted in the lower part of this sed i men tary pack age. The dras ti cally re duced fos sil as sem blage (tapho- coenosis IV), oc cur ring only in the thin mudstone shales in ter ca lated with the greywackes over ly ing the host de pos - its of taphocoenosis III, re flects re newed set tling of only the eurytopic or gan isms. The poor state of pres er va tion of shells, and the scarce pre served trace fos sils point to a high- en ergy en vi ron ment of near-shore con di tions. The re peat - edly chang ing con di tions gen er ated by sed i ment-laden cur- rents could have made col o ni za tion by ben thic or gan isms im pos si ble.

The up per most part of the Paprotnia sec tion is com - posed mainly of greywackes, which con tain only the re - mains of terrestial plants (taphocoenosis V), in di cat ing prox im ity to land. This group is only rep re sented by plant fos sils; fau nal re mains are to tally ab sent (Fig. 5). Among them, the most nu mer ous are asterocalamite stems. Lepi- dodendron re mains, fern leaves (mainly of Sphenopte- ridium and Cardiopteris) and seeds are less abun dant. The flo ral re mains of taphocoenosis V sug gest prox im ity to land and a short trans port dis tance.

Both the lithological and paleontological fea tures of the Paprotnia beds in di cate grad ual en vi ron men tal chan- ges from off shore to on shore con di tions. The Paprotnia beds, to gether with the over ly ing Wilcza con glom er ates, ter mi nate the autochthonous suc ces sion of the Bardo Com plex (Fig. 3).

The bentonites: min er al ogy, or i gin and trans for ma tion

The six ben ton ite lay ers (Fig. 4) are eas ily vis i ble within the gray shales and graywackes in the lower part of the Paprotnia beds through their bright yel low ish col our.

Their thick nesses vary from less than 1 cm to ~ 10 cm.

Lo cally, they are vari able in thick ness and slightly faulted (Fig. 6).

The min eral com po si tion of all the ben ton ite lay ers is sim i lar. The ma jor clay min er als in the bentonites are: I/S mixed-layer min eral and kaolinite, both oc cur ring in sim i - lar pro por tions (Fig. 7, Ta ble 2). Smectite and illite have also been de tected in two of the six ben ton ite lay ers.

All the sam ples ana lysed con tain small amounts of iron hy drox ides. Sec ond ary cal cite (up to 10% by vol ume) oc curs as: (a) small grains dis persed in the groundmass, (b) lens-like small ag gre gates, and (c) thin (up to 4 mm) veins of fi brous crys tals, par tic u larly com mon in the up per parts of some of the ben ton ite lay ers. No rel ics of pri mary mag matic min er als (e.g. feld spar or bi o tite), ex cept for ac - ces sory zir cons (see be low), were ob served.

Sum ming up, the min eral com po si tion (clay min er als, cal cite) of the bentonites from the Paprotnia beds sup ports their pyroclastic der i va tion and points to a prob a ble in ter - me di ate com po si tion of the par ent vol ca nic ma te rial.

The mea sured pro por tion of smectite S (20–30%) in the mixed-layer I/S pack ets, based on the po si tion of peaks cor re spond ing to (002) and (003), is be tween 20 and 30%

(Fig. 7). Such a pro por tion and Reichweite R ³ 1 in di cate that the max i mum diagenetic paleotemperatures in these rocks could have at tained ~ 130–160°C (Au gust, 2006;

Œrodoñ, 1995).

LOWER CAR BON IF ER OUS BENTONITES, SUDETES

27

Fig. 6. (a) – ex po sure of the Paprotnia beds. (b) – the thick est ex - posed ben ton ite (no tice tec tonic de for ma tion).

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SHRIMP ZIR CON GEO CHRON OL OGY – A SYN OP SIS

The re sults of geo chron ol ogi cal in ves ti ga tions are pre - sented and dis cussed in more de tail in a sep a rate pa per (Kryza et al., 2009, in prep.). Here, we re port only the ba - sic zir con char ac ter is tics and their mean con cordia age that con strains their strati graphic po si tion.

The zir cons in ben ton ite A are subhedral to euhedral, short- to nor mal-pris matic, colour less and trans par ent, with fairly com mon oval and nee dle-like in clu sions (Fig.

8). In cathodoluminescence (CL) im ages they of ten show reg u lar “mag matic-type” zonation. 232Th/238U ra tio is rather uni form, be tween 0.33–0.62, typ i cal of ig ne ous zir - cons (Kryza et al., 2009, in prep.).

The main pop u la tion of thir teen zir cons (out of the to tal 15 grains ana lysed) yielded 206Pb-238U ages scat tered be tween 313±5 and 343±5 Ma. The mean Con cordia age cal cu lated for nine points of this main pop u la tion (ex clud - ing sig nif i cantly youn ger grains and a pos i tively dis cor - dant one) is 334±4 Ma. An al ter na tive in ter pre ta tion is that the age of one sin gle grain which is nearly per fectly con cor dant: 337±4 Ma (dis cor dance D = –1%) is the best ap prox i ma tion of the true mag matic age (Kryza et al., 2009, in prep.).

DIS CUS SION AND CON CLU SION

Ac cord ing to Wajsprych (1995), the up per most part of the autochthonous suc ces sion (the Paprotnia beds) ac cu - mu lated dur ing the ”crenistria trans gres sion” and is re - garded as a tem po ral shal lower-wa ter equiv a lent of the crenistria Lime stone (cd III a, Up per Viséan). The creni- stria Lime stone is wide spread in the Kulm fa cies of Varis- can Eu rope and forms a set of three lime stone beds (see Jack son, 1990; Warnke, 1997) that con tain, pre dom i - nantly, a pe lagic fauna rep re sented mainly by plank tonic, pseudoplanktonic and nektonic or gan isms, whereas fos sils of ben thic or gan isms are usu ally rare.

The li thol ogy and the suc ces sion of bi otic com po - nents (taphocoenoses) in the ex ca vated part of the Pa- protnia beds re flect a grad ual change from deeper to shal - lower wa ter sed i men ta tion (Haydukiewicz & Muszer, 2002). Con se quently, the Paprotnia beds rep re sent the shal lower fa cies equiv a lent of the pe lagic crenistria Lime - stone. The sim i lar ity of the Late Viséan lithological and paleontological re cords of the Bardo Unit to the ad ja cent Intra-Sudetic Ba sin (the Szczawno For ma tion; ¯akowa, 1968; Bossowski et al., 1995) and the Góry Sowie Mas sif (Sokolec beds, clayey-greywackes se ries, ¯akowa, 1966, Fig. 7. (a) – XRD pat tern of ben ton ite A (air-dried and glycolated sam ple); (b) DTA, TG and DTG curves of ben ton ite A, Cc – cal cite, I – illite, I/S – illite-smectite, K – kaolinite, S – smectite; R – Reichweite in dex.

Ta ble 2 Se lected min er al og i cal char ac ter is tics of the ben ton ite lay ers in the Paprotnia beds

Ben ton ite lay ers Smectite & I/S

%

Kaolinite

% Quartz (sil ica) FeOOH

%

Cal cite

% Euhedral zir con

A 30 35 + 2 3 +

B 30 50 + 1 0 +

C 25 35 + 2 9.5 +

D 20 35 + 3 0 +

E 35 45 + 2 4.5 +

F 35 45 + 2 2 +

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1968) sug gests a shal low-wa ter en vi ron ment in the Sudetic part of the wide mid-Eu ro pean Variscan ba sin at that time.

A scheme of palaeotectonic sce nario for the cen tral Sude- tes in late Viséan times is shown in Fig. 9. The Paprotnia beds were de pos ited in the shallowing-up con ti nen tal mar - gin (or intramontane) Bardo ba sin, lo cated south-east of the up lift ing, since Famennian times, Góry Sowie Mas sif.

The K-bentonites in the Paprotnia beds are re cords of synsedimentary vol ca nic ac tiv ity and sub se quent diagene- tic al ter ation of the fine-grained pyroclastic sed i ments.

The pyroclastic der i va tion is con firmed by the pres ence of fresh zir con crys tals, with fea tures typ i cal of vol ca nic or i - gin. The min eral com po si tion of the Paprotnia bentonites (mixed-lay ered illite/smectite, kaolinite and illite, and cal - cite), as well as the abun dance of vol ca nic zir con grains, sug gest a likely in ter me di ate vol ca nic magma. The pro - gres sive in crease in fos sils, ob served above the thick est ben ton ite layer, may in di cate fer til iza tion of the sea wa ter, lead ing to in tense de vel op ment of phyto-plank ton and zoo plank ton.

The volcaniclastic ma te rial con tained, as a ma jor com - po nent, vol ca nic glass which in the shal low-ma rine en vi - ron ment was quickly changed into smectite. This early smectite was sub se quently trans formed partly into illite, and the mea sured pro por tion of the smectite S, ~ 20–

30%, in I/S pack ets, and R ³ 1, in di cate that the max i mum diagenetic palaeotemperatures in that rock suc ces sion could have been around 130–160°C (Šucha et al., 1993).

The lack of ma jor mag matic com po nents, such as feld - spars and bi o tite, in the ben ton ite in di cates a strong diagenetic trans for ma tion of the pyroclastic ma te rial.

The SHRIMP ages of vol ca nic zir con grains from the ben ton ite stud ied fit well with the Viséan age based on biostratigraphic ev i dence. The ra dio met ric ages for the Asbian (lower part of the Up per Viséan) in cen tral and west Eu rope, de rived mainly from ash lay ers, us ing U-Pb zir con IDTIM dat ing, are be tween 337 and 332 Ma (Menning et al., 2006). Our data of 334±4 Ma are in good agree ment, within an a lyt i cal er ror, with those re sults.

LOWER CAR BON IF ER OUS BENTONITES, SUDETES

29

Fig. 8. Zir cons from ben ton ite A, (a) – in trans mit ted plane po - lar ized light, and (b) –in cathodoluminescence.

Fig. 9. Palaeotectonic sce nario for the Bardo ba sin dur ing the late Viséan. BB – Bardo ba sin; GoFm – Go³og³owy For ma tion; GSM – Góry Sowie Gneiss Mas sif; ISB – Intra-Sudetic ba sin; NWFm – Nowa Wieœ For ma tion; Sb – Sokolec beds; SFm – Srebrna Góra For ma - tion; SzFm – Szczawno For ma tion; Pab – Paprotnia beds; WaFm – Wapnica For ma tion; Wib – Wilcza beds.

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The new geo chron ol ogi cal data from the ben ton ite fur ther con strain vol ca nic ac tiv i ties in the re gion dur ing the Viséan. The Paprotnia beds are a con ti nen tal mar gin (or intramontane) ba sin suc ces sion doc u ment ing a grad ual en vi ron men tal change from off shore to on shore con di - tions (Haydukiewicz & Muszer, 2002), and de pos ited dur - ing the on go ing Variscan orog eny. By the late Viséan, in - ter nal parts of the orogen (“klippen”), such as the Góry Sowie Mas sif, must have been partly ex humed (start ing al - ready in Famennian times) and sup ply ing de tri tus to neigh bour ing bas ins, in clud ing the Bardo ba sin and the intramontane Intra-Sudetic ba sin (Fig. 9).

The vol ca nic source sup ply ing ash ma te rial to the ben - ton ite lay ers could have been lo cated in the Intra-Sudetic Ba sin, where Lower Car bon if er ous andesites and rhyoda-

cites were doc u mented (Awdankiewicz, 1999). How ever, their ef fu sive, i.e. sensu stricto vol ca nic na ture has re cently been ques tioned in some of the lo cal i ties, us ing SHRIMP zir con dat ing that in di cate their youn ger age and, con se - quently, subvolcanic, in tru sive char ac ter (Awdankiewicz

& Kryza, 2009, in prep a ra tion). We should also keep in mind that the fine vol ca nic ma te rial can be trans ported over thou sands of kilo metres, so the ac tual source could have been lo cated very far from the place of de po si tion.

Ac knowl edg ments

The study was sup ported by the in ter nal grants of Wroc³aw Uni ver sity, 2022/W/ING and 1017/S/ING. Jan Zalasiewicz is thanked for care ful cor rec tion of an ear lier ver sion of this pa per.

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¯ELAZNIEWICZ, A. & ALEKSANDROWSKI, P., 2008.

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LOWER CAR BON IF ER OUS BENTONITES, SUDETES

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