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Geo log i cal Quar terly, 2010, 54 (2): 257–266

2-D mod el ling of pe tro leum pro cesses of the lower Paleozoic strata in the Pol ish part of the Bal tic re gion

Magdalena WRÓBEL and Paweł KOSAKOWSKI

Wróbel M. and Kosakowski P. (2010) – 2-D mod el ling of pe tro leum pro cesses of the lower Pa leo zoic strata in the Pol ish part of the Bal - tic re gion. Geol. Quart., 54 (2): 257–266. Warszawa.

2-D mod el ling of hy dro car bon gen er a tion, ex pul sion, mi gra tion and ac cu mu la tion pro cesses was car ried out for the four (Mid dle Cam - brian, Up per Cam brian–Tremadocian, Caradocian and Llandovery) source rock ho ri zons. The pe tro leum po ten tial of these source rocks is dif fer ent, the high est be ing ob served in the Up per Cam brian–Tremadocian ho ri zon and the low est in the Mid dle Cam brian one. The ma tu rity of or ganic mat ter within these source units in creases from the north-east to the south-west of the Pol ish part of Bal tic re gion. The pe tro leum gen er a tion from these source rocks was high est in the Darłowo and Słupsk blocks as well as in the on shore part of the Łeba Block. Ex pul sion took place mainly from the Up per Cam brian–Tremadocian source rocks and these rocks sourced al most all hy dro car - bons ac cu mu lated within the Mid dle Cam brian sand stone res er voirs. Mi gra tion of hy dro car bons pro ceeded along fault zones. Al most all pe tro leum pro cesses in the study area took place be tween the end of the Pridoli and the end of the Car bon if er ous. More over, dur ing the Perm ian and the Me so zoic, part of the hy dro car bons remigrated within the res er voir. This pro cess changed the set ting and the vol ume of hy dro car bon ac cu mu la tions. It was caused by the tec tonic re build ing of the ba sin and, in most cases, it led to the mod i fi ca tion of ac cu mu - la tion range or to the dis per sion of hy dro car bons.

Magdalena Wróbel and Paweł Kosakowski, Fac ulty of Ge ol ogy, Geo phys ics and En vi ron mental Pro tec tion, AGH Uni ver sity of Sci ence and Tech nol ogy, Mickiewicza 30, PL-30-059 Kraków, Po land, e-mails: wrobelm@agh.edu.pl, kosak@agh.edu.pl (re ceived: De cem ber 12, 2009; ac cepted: May 17, 2010).

Key words: Bal tic re gion, lower Pa leo zoic, ac cu mu la tion, mi gra tion, gen er a tion, pe tro leum.

INTRODUCTION

Pe tro leum pro cesses in the lower Pa leo zoic strata were mod - elled along two re gional cross-sec tions (Fig. 1), lo cated in the west ern Pol ish part of the Bal tic re gion. These stud ies aimed to re con struct the depositional his tory of the se quence of rock units and to pre dict their be hav iour and pe tro leum prop er ties. The main task was to re con struct the oil and gas gen er a tion, ex pul - sion and mi gra tion. As a re sult, we de ter mined the com po si tion and amount of gen er ated, ex pelled and ac cu mu lated hy dro car - bons in each time in each level as dis played in cross-sec tions.

Ad di tion ally, the 2-D mod el ling in di cated the di rec tion and rate of hy dro car bon mi gra tion. It should be men tioned that some of geo log i cal and phys i cal data needed in that kind of re con struc - tion could not be mea sured hence, we had to use as sump tions.

Some pre vi ous stud ies of pe tro leum pro cesses in the Bal tic re - gion car ried out by Górecki et al. (1979), Witkowski (1989), Karnkowski (2003) and Zdanaviciute and Lazauskiene (2004) were ex cel lent sources of in for ma tion (in ter preted seis mic sec - tions, geo log i cal, geo chem i cal, po ros ity and per me abil ity data).

The mod el ling of pe tro leum pro cesses is, as Waples (1994) said “...a com pro mise be tween what we would like to do and what our lim ited knowl edge per mits...”.

GEOLOGICAL SETTING

In the study part of the Bal tic re gion, the Pre cam brian crys tal line base ment is cov ered by lower Pa leo zoic strata, in - clud ing Cam brian, Or do vi cian and Si lu rian rocks. In the south ern part, Perm ian, Tri as sic and Ju ras sic sed i men tary rocks are also pres ent.

De scrip tions of ba sin ge ol ogy and evo lu tion were pub - lished by Witkowski (1989), Poprawa et al., (1999) and Poprawa et al., (2010).

Ac cord ing to Poprawa et al. (2010) and Kosakowski et al.

(2010), two main ero sion events had an im por tant im pact on the evo lu tionary his tory of the re gion. The De vo nian and Car - bon if er ous strata were eroded dur ing Car bon if er ous up lift and are ab sent from the study area. In the off shore part, the Up per Si lu rian strata were also partly eroded dur ing a Late Car bon if -

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er ous–Early Perm ian ero sional event. The mag ni tude of this ero sion was de ter mined to be 1350 m in the east ern part and 1600 m in the west ern part of the study area. Both the post-Tri - as sic and post-Cre ta ceous ero sion events re duced the Tri as sic and Cre ta ceous de pos its by ap prox i mately 300 m in the south to 450 m in the north of the Bal tic re gion.

MATERIAL AND METHODS

Mod el ling of pe tro leum pro cesses was car ried out by BasinModTM 2-D soft ware (BMRM 2-D, 2006). A re view of the meth od ol ogy of BasinModTM 2-D was pre sented by Wróbel et al. (2008).

The 236-M2-76 cross-sec tion be tween the A8-1/83 and the B6-1/82 bore holes is 127.3 km long and lo cated in the off shore, north ern part of the Darłowo, Słupsk and Łeba blocks (Fig. 1).

The in ter pre ta tion of seis mic sec tions iden ti fied the top sur - faces of the Pro tero zoic, the Lower Cam brian, and the Or do vi - cian suc ces sions as well as re flec tions from within the Si lu rian suc ces sion. In de pend ently of seis mic sec tion in ter pre ta tions, the top of the Up per Cam brian strata was po si tioned in the cross-sec tion on the ba sis of depth data from bore holes.

The 39.5 km long 83-01-93T cross-sec tion is lo cated on - shore, in the south ern parts of the Słupsk and the Łeba blocks.

It in cludes the Białogóra 3 and the Dębki 3 bore holes (Fig. 1).

The in ter pre ta tion of seis mic sec tions iden ti fied the top sur - faces of crys tal line base ment, and the Lower Cam brian suc ces - sion, the base of the Up per Cam brian and the top of the Or do vi - cian se quences, the re flec tions within the Si lu rian suc ces sion as well as the base of the Zechstein, the Tri as sic and the Lower Ju - ras sic suc ces sions. The ages of the ho ri zons and faults are based on Gradstein et al. (2004).

It should be men tioned that geo log i cal mod els cre ated from in ter preted seis mic sec tions are not as ac cu rate as geo log i cal pro files based on data from bore holes. This is caused by the low res o lu tion of the seis mic sec tions and prob lem atic ve loc ity mod els due to the old source data (Pokorski, 2010).

The geo chem i cal, po ros ity and ki netic data were in ter po - lated be tween the bore holes in which pa ram e ters were de ter - mined. A sim i lar ap proach was ap plied to the lo ca tion of the source rocks where par tic u lar sec tors were as signed ad e quate thick nesses and TOC contents.

LITHOLOGICAL MODEL

Lithological dif fer ences rec og nized from bore hole pro files and lithofacies maps (Modliński and Podhalańska, 2010) pro - vided the in put to the mod els for each strati graphic for ma tion as a per cent age of sand stones, siltstones, shales, lime stones, dolomites and evap o rites. In the east ern part of the 236-M2-76

Fig. 1. Sketch tec tonic map of the Pol ish Bal tic region

and lo ca tion of an a lysed bore holes and cross-sec tions for 2-D mod el ling Fault sys tem af ter Pokorski (2010)

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cross-sec tion, for ma tion lithologies were taken from the B6-1/82 bore hole pro file and in west ern part from the A8-1/83 bore hole. Lithologies were de fined as per cent ages of par tic u lar types of rocks. Anal o gously to the off shore cross-sec tion, lithologies were set out on the 83-01-93T cross-sec tion, where the east ern part of sec tion was de fined by lithological in for ma - tion from the Dębki 3 bore hole, and the west ern part from that of the Białogóra 3 bore hole.

The Mid dle Cam brian, Up per Cam brian–Tremadocian, Caradocian and Llandovery source rocks were de ter mined and char ac ter ized by Więcław et al. (2010a). These source rocks were in tro duced into the model at the base of rel e vant strati - graphic ho ri zons. Geo chem i cal data for source rocks were taken from the B6-1/82 and the A8-1/83 bore holes in the east - ern and west ern parts of the 236-M2-76 cross-sec tion, re spec - tively. A sim i lar ap proach was ap plied to the 83-01-93T cross-sec tion, where the east ern part was de scribed by geo - chem i cal pa ram e ters from the Dębki 3 bore hole and the west - ern part from these de rived from the Białogóra 3 bore hole.

PHYSICAL MODEL

Ther mal con di tions de scribed by Poprawa et al. (2010) and Kosakowski et al. (2010) were ap plied to the 2-D mod els by in - ter po la tion be tween boreholes. The mod el ling also used ki netic pa ram e ters cal cu lated for the lower Pa leo zoic strata of the Bal - tic re gion by Więcław et al. (2010b).

Po ros ity and per me abil ity data on the Mid dle Cam brian sand stones were de scribed by Najdionow et al. (1984), Weil (1990) and Semyrka et al. (2010). For the Mid dle Cam brian res er voirs in the off shore part, the po ros ity var ies be tween 1.2 and 2.2% in the A8-1/83 bore hole and be tween 1.5 and 26.7%

in the B6-1/82 bore hole. In the B6-1/82 bore hole the me dian value of po ros ity is 10.1%. Po ros ity in the on shore ar eas var ies from 1.4 to 8.5% in the Białogóra 3 bore hole and from 1 to 9.6% in the Dębki 3 bore hole (Semyrka et al., 2010).

The thick ness of res er voir was taken as the dif fer ence be - tween the to tal thick ness of the Mid dle Cam brian strata and the thick ness of shales and mudstones in that for ma tion. The main fac tor in flu enc ing the res er voir qual ity of the Mid dle Cam brian sand stones is the quartz ce ment, which re duces both the po ros - ity and the per me abil ity (Domżalski et al., 2004; Molenaar et al., 2007).

The as pects of pe tro leum mi gra tion mod el ling were de - scribed by Ungerer et al. (1990) and Welte et al. (2000), and the role of faults in hy dro car bon mi gra tion and en trap ment was dis cussed by Aydin (2000) and Lopatin et al. (2003).

REGIONAL TRANSFORMATION RATIO OF THE LOWER PALEOZOIC SOURCE ROCKS

The ma tu rity of dis persed or ganic mat ter de pends on the lo - ca tion in the Bal tic re gion (Karnkowski, 2003; Zdanaviciute and Lazauskiene, 2004; Kosakowski et al., 2010; Więcław et al., 2010a). Source rock ma tu rity changes con sid er ably from

the north-east to the south-west of the Pol ish part of the Bal tic re gion, as shown by val ues of the trans for ma tion ra tio.

The changes in the value of trans for ma tion ra tio are no tice - able in the 236-M2-76 cross-sec tion, which in cludes three blocks and which pro vides an in sight into the ar eas where ma - tu rity was at dif fer ent lev els. At the end of the Tournaisian, in the off shore part of the Darłowo and partly of the Słupsk block, the trans for ma tion ra tio reached 50% for the Mid dle Cam brian, 30% for the Up per Cam brian–Tremadocian and did not ex ceed 20% for the Caradocian and the Llandovery source rocks. At the same time, in the east ern part of the Słupsk Block and in the Łeba Block the trans for ma tion ra tio for all source rocks was be - low 10%. In the Visean, in the west ern part of the 236-M2-76 cross-sec tion the trans for ma tion ra tio in creased and in the east - ern part of the Słupsk Block, and in the Łeba Block, it did not ex ceed 15% for all source rocks. At the end of the early Car - bon if er ous all source rocks in the west reached com plete trans - for ma tion, while in the east trans for ma tion did not ex ceed 20%.

These conditions have not changed until the pres ent.

In on shore part of the Słupsk and Łeba blocks, along the 83-01-93T cross-sec tion, time and val ues of trans for ma tion ra - tio dif fer con sid er ably from those of the off shore part. In the east ern part of the Łeba Block and partly in the Słupsk Block the to tal trans for ma tion ra tio was reached by the Mid dle Cam - brian source rocks at the end of the Si lu rian. At the same time the youn ger source rocks reached trans for ma tion ra tios of up to 80 and 70% in the Łeba Block and in the Słupsk Block, re spec - tively. The Mid dle Cam brian source rocks reached total trans - for ma tion ra tio along the en tire 83-01-93T cross-sec tion at the end of the Emsian. The Up per Cam brian, Caradocian and Llandovery source rocks reached to tal trans for ma tion ra tio along the whole cross-section in the Famennian.

Con clud ing the re sults of ma tu rity and ki netic mod el ling along these two cross-sec tions, in the north ern part of the Łeba Block source rocks are im ma ture and in its south ern part these are ma ture. Due to this dif fer ence, trans for ma tion ra tio ranges from 15% in north to 100% in south. In both the Darłowo and the Słupsk blocks the source rocks reached al most to tal trans - for ma tion in the De vo nian in the on shore part and in the Car - bon if er ous in the offshore part.

ARRANGEMENT AND TIMING OF REGIONAL HYDROCARBON GENERATION

In the north ern off shore part of the study area, re con struc - tion of the hy dro car bon gen er a tion pro cess for the Mid dle Cam brian source rocks re vealed that in the Darłowo and Słupsk blocks its ini ti a tion took place at the be gin ning of the Tournaisian (355 Ma) and has lasted un til the end of the Visean (326 Ma) (Fig. 2), to tal ling up to 400 mg HC/g TOC. Max i - mum gen er a tion of oil and gas took place in the Darłowo Block, near the A8-1/83 bore hole and in the cen tral part of the cross-sec tion, in the Słupsk Block (Fig. 2). In the east ern part of the Słupsk Block and in the Łeba Block gen er a tion from the Mid dle Cam brian source rock did not ex ceed 100 mg HC/g TOC (Fig. 2). In the on shore part the same source rock ho ri zon, along the 83-01-93T cross-sec tion, started hy dro car bon gen er -

2-D modelling of petroleum processes of the lower Paleozoic strata in the Polish part of the Baltic region 259

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a tion in the Lud low (419 Ma) and the pro cess lasted un til the Lochkovian (414 Ma), near fault zones in the neigh bour hood of the Białogóra 3 bore hole and in the Słupsk Block. How ever, an ex cep tion was found near the fault zones, where gen er a tion ended at the be gin ning of the Tournaisian (460 Ma). The to tal amount of oil gen er ated from the Mid dle Cam brian ho ri zon reached 350 mg HC/g TOC and that of gas reached 50 mg HC/g TOC.

In the off shore area within the Up per Cam - brian–Tremadocian, Caradocian and Llandovery source rocks, the hy dro car bon gen er a tion pro cess started in the Tournaisian (352 Ma) and ended in the Visean (326 Ma). The amount of hy - dro car bons gen er ated var ied from 350 mg HC/g TOC for the

Caradocian and Llandovery source rocks to 450 mg HC/g TOC for the Up per Cam brian–Tremadocian source rocks (Fig. 2). In the east ern part of the 236-M2-76 cross-sec tion the amount of hy dro car bons gen er ated did not ex ceed 50 mg HC/g TOC (Fig. 2). In the on shore part only the Up per Cam brian source rocks are pres ent whereas the Tremadocian strata have not been pre served. Gen er a tion of hy dro car bons within the Up per Cam - brian, Caradocian and Llandovery source rocks started at the end of the Lud low (419 Ma) in the east ern part of the 83-01-93T cross-sec tion and reached a max i mum in the mid Lochkovian (414 Ma). In the re main ing area gen er a tion lasted un til the be gin ning of the Tournaisian (360 Ma). Along the en - tire 83-01-93T cross-sec tion the vol ume of hy dro car bons gen -

Fig. 2. Amount of hy dro car bons gen er ated along the 236-M2-76 cross-sec tion in par tic u lar time steps:

A – af ter Tournaisian sed i men ta tion, B – af ter Car bon if er ous sed i men ta tion and C – pres ent

Cm1 – Lower Cam brian, Cm2&3 – Mid dle and Up per Cam brian, O – Or do vi cian, S1 – Llandovery and Wen lock, S2 – Lud low and Pridoli, Dep. D – De vo nian de pos its, Dep. D&C – De vo nian and Car bon if er ous de pos its, Q – Qua ter nary, wavy vi o let line – base of de - pos ited sed i ments re con structed in model

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er ated in the on shore part reached a max i mum of 450 mg HC/g TOC for the Up per Cam brian source rock, and 350 mg HC/g TOC for the Caradocian and Llandovery source rocks.

The Darłowo, Słupsk and Łeba blocks dif fer in the amounts of hy dro car bons gen er ated and in the time of the gen er a tion pro cess. The best con di tions for hy dro car bon gen er a tion ex - isted in the Darłowo and Słupsk blocks, and in the on shore part of the Łeba Block. The off shore part of the Łeba Block and east ern part of the Słupsk Block seem not to be gen er a tive enough to in clude them in the mass bal ance of hy dro car bons in this part of the Bal tic re gion.

EXPULSION, MIGRATION

AND ACCUMULATION OF HYDROCARBONS

Ex pul sion mod el ling re vealed that all the hy dro car bons gen er ated in the Up per Cam brian–Tremadocian source rocks sat u rated the Mid dle Cam brian res er voirs. Fault sys tems pro - vided the con nec tion be tween an older res er voir and youn ger source rocks. As for the hy dro car bon gen er a tion pro cess, the ex pul sion, mi gra tion and ac cu mu la tion pro cesses have been stud ied sep a rately for the off shore and on shore parts of the Polish part of the Baltic region.

In off shore part, the main phase of oil and gas ex pul sion and mi gra tion took place be tween the mid (345 Ma) and the late Visean (326 Ma). Tec tonic events oc cur ring dur ing the Perm ian and the Me so zoic caused some move ments of hy dro car bons within the res er voir and changed their po si tion in the ba sin (Fig. 3). The stud ies of pe tro leum pro cesses along the 236-M2-76 cross-sec tion re vealed that the ex pelled oil in the Darłowo and Słupsk blocks mi grated to the Mid dle Cam brian sand stones through the faults. These faults show thrust move - ments from 50 to 200 m, which guar an tees con nec tions be tween the source and the res er voir rocks. The fault with the high est thrust move ment (about 500 m, over 42 km; Fig. 3) forms a bar - rier for hy dro car bon mi gra tions from the east ern part of the Słupsk Block. In the up lifted part of the Słupsk Block ex pelled hy dro car bons mi grated to the west. The anal y sis of oil mi gra tion in the off shore part show that the mi gra tion dis tance var ied from a few to even 30–40 km, at an oil ex pul sion vol ume of up to 0.15 m3/m3 rock. Ac cu mu la tion of oil took place mainly in the Słupsk and the Łeba blocks. The vol ume of oil ac cu mu lated in the Mid dle Cam brian sand stones var ied from 0.13 m3/m3 rock in the west ern part of the Słupsk Block to 0.16 m3/m3 rock at the B6-1/82 (i.e. B6 field) in the Łeba Block (Fig. 3). The ex pul sion of gas oc curred ev ery where ex cept for the Łeba Block, and its max i mum vol ume reached 0.027 m3/m3 rock. In the cen tral part of the Słupsk Block ex pelled gas mi grated to the east to wards the Łeba Block. Gas mi grated along the 236-M2-76 cross-sec tion partly un der went dis per sion. Gas losses were caused by ver ti cal mi gra tion through the faults, mainly dur ing and af ter Car bon if er - ous in ver sion of the Bal tic re gion. Domżalski et al. (2004) de - scribed this pro cess as a re sult of gas dif fu sion or ef fu sion. Gas was ac cu mu lated in the res er voir in the amount of 0.02 m3/m3 rock with 20% losses (Fig. 4). An ti cli nal traps along the Smołdzino Fault formed res er voirs for the gas ac cu mu la tions.

Gas yielded from the source rocks in the Darłowo Block and in the west ern part of the Słupsk Block mi grated to the east, to -

wards the fault with the larg est thrust move ment. This fault cre - ated a bar rier to fur ther hy dro car bon flow to the east and, as a con se quence, sub stan tial gas ac cu mu la tion was dis closed in the 236-M2-76 model (Fig. 4).

In the on shore part of the study area, ex pul sion was ob served mainly in Up per Cam brian strata. Oil ex pul sion pro cesses started at the end of the Pridoli (416 Ma), and lasted to the end of the early Car bon if er ous (326 Ma). First, at the end of the Pridoli ex - pul sion started in the east ern part of the 83-01-93T cross-sec tion, and in the Famenian (375 Ma) ex pul sion be gan in the cen tral and west ern parts of the cross-sec tion. The vol ume of oil ex pul sion var ied from 0.04 m3/m3 rock in the west ern part, to a max i mum of 0.065 m3/m3 rock in the east ern part. Gas ex pul sion in the on - shore part started at the end of the Lud low (418 Ma) in the east - ern part of the 83-01-93T cross-sec tion and in the Lochkovian the ex pul sion be gan in the west ern part of this cross-sec tion. At the end of the Pridoli (417 Ma) gas ex pul sion ended in the east - ern part, but in the rest of the cross-sec tion it lasted to the Frasnian (380 Ma). In the on shore part gas ex pul sion was ob - served also in the Caradocian source rock, over a wide time span, from the Frasnian (382 Ma) to the Cre ta ceous (70 Ma). It is worth not ing that ex pul sion from the Mid dle Cam brian source rock ap peared in small amounts in the on shore part. Oil mi gra - tion from source rocks to the res er voir in the Mid dle Cam brian sand stones through faults be gan in the Pridoli (418 Ma) and lasted to the Cre ta ceous (65.5 Ma). How ever, the main stage of that pro cess took place at the end of the Car bon if er ous (299 Ma).

Later only 20% of hy dro car bons changed po si tion within the res er voir (Fig. 5). Both the Perm ian and the Me so zoic oil mi gra - tion was con nected with fill ing of al ready ex ist ing Białogóra and Dębki traps. The ac cu mu la tion pro cess be gan in the Pridoli (417 Ma), mainly near faults in the vi cin ity of the Białogóra 3 and Dębki 3 bore holes in the Łeba Block and in the Słupsk Block (Fig. 5). In both the De vo nian and the Car bon if er ous the al ready ex ist ing Białogóra field was sup plied with oil mi grat ing from the east and the west (Fig. 5). Fi nally, oil was en trapped in the Łeba Block near the Białogóra 3 bore hole and in the east ern on shore part of the Słupsk Block. The vol ume of oil ac cu mu la tion var ied from 0.11 m3/m3 rock to 0.13 m3/m3 rock (Fig. 5). Gas mi gra tion was ob served mainly in the Pa leo zoic, but as men tioned above it also took place in the Me so zoic. The main phase of gas mi gra - tion lasted from the Pridoli (418 Ma) to the end of the Famennian (359 Ma). Dur ing the Car bon if er ous gas losses were ob served in the res er voir, reach ing 25% of the ini tial gas vol ume (Fig. 6).

Dur ing the next stages of ba sin evo lu tion fur ther losses took place, mainly from the traps around the Białogóra 3 and the Dębki 3 bore holes un til al most to tal dis per sion of gas in this re - gion took place (Fig. 6). In the Słupsk Block only slight losses of gas vol ume were ob served, how ever, the range of this ac cu mu la - tion was re duced. Fi nally, the vol ume of en trapped gas in the east ern on shore part of the Słupsk Block, amounted up to 0.027 m3/m3 rock (Fig. 6).

CONCLUSIONS

Re gional anal y sis of pe tro leum pro cesses in the Pol ish part of the Bal tic re gion in di cated that al most all hy dro car bons were gen er ated and ex pelled from Up per Cam brian–Tremadocian

2-D modelling of petroleum processes of the lower Paleozoic strata in the Polish part of the Baltic region 261

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0

0

0 1000

1000

1000 2000

2000

2000 3000

3000

A8-1/83 B6-1/82

Darłowo Block Słupsk Block Łeba Block

Depth [m]Depth [m]Depth [m]

W E

Dep. D

Dep. D&C S2

S2

S2 S1

S1

S1 Cm2&3

Cm2&3

Cm2&3 Cm1

Cm1

Cm1

0 20 40 60 80 100 120

0

0 1000

1000 2000

2000

3000

Depth [m]Depth [m b.s.l.]

Distance [km]

Dep. T S2

S2 S1

S1 Cm2&3

Cm2&3 Cm1

Cm1

3 3

Oil accumulated volume ratio [m /m rock]

0 0.04 0.08 0.12 0.16

A

B

C

D

E

Q

O

O

O

O

O

POST-TOURNAISIANPOST-CARBONIFEROUSPOST-PERMIANPOST-TRIASSICPRESENT

Fig. 3. Vol ume of the oil ac cu mu lated along the 236-M2-76 cross-sec tion in par tic u lar time steps: A – af ter Tournaisian sed i men ta tion, B – af ter Car bon if er ous sed i men ta tion, C – af ter Perm ian sed i men ta tion,

D – be fore Ju ras sic sed i men ta tion and E – pres ent Dep. T – Tri as sic de pos its; for other ab bre vi a tions see Fig ure 2

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2-D modelling of petroleum processes of the lower Paleozoic strata in the Polish part of the Baltic region 263

Fig. 4. Vol ume of the gas ac cu mu lated along the 236-M2-76 cross-sec tion in par tic u lar time steps: A – af ter Tournaisian sed i men ta tion, B – af ter Car bon if er ous sed i men ta tion, C – af ter Perm ian sed i men ta tion, D – be fore Ju ras sic sed i men ta tion and E – pres ent

For other ab bre vi a tions as in Fig ures 2 and 3

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Fig. 5. Vol ume of the oil ac cu mu lated along the 83-01-93T cross-sec tion in par tic u lar time steps: A – af ter Lud low sed i men ta tion, B – af ter Car bon if er ous sed i men ta tion, C – af ter Perm ian

sed i men ta tion, D – af ter Ju ras sic sed i men ta tion and E – pres ent

Cm2 – Mid dle Cam brian, O&Cm3 – Or do vi cian and Up per Cam brian, PZ – Perm ian (Zechstein), T – Tri as sic, J – Ju ras sic; ab bre vi a tions as in Fig ure 2

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2-D modelling of petroleum processes of the lower Paleozoic strata in the Polish part of the Baltic region 265

Fig. 6. Vol ume of the gas ac cu mu lated along the 83-01-93T cross-sec tion in par tic u lar time steps: A – af ter Lud low sed i men ta tion, B – af ter Car bon if er ous sed i men ta tion, C – af ter Perm ian sed i men ta tion,

D – af ter Ju ras sic sed i men ta tion and E – pres ent Ab bre vi a tions as in Fig ures 2 and 5

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source rocks. Only in the on shore area did Caradocian source rocks ex pel some hy dro car bons. The pe riod of ex pul sion pro - cess de pends on the re gion; in the off shore re gion it took place be tween the Visean and the end of the Car bon if er ous, while in the on shore re gion the ex pul sion be gan ear lier, at the end of the Si lu rian and lasted to the end of the Car bon if er ous. It should be em pha sized that in the Perm ian and the Me so zoic slight mi gra - tion of hy dro car bons took place in the Mid dle Cam brian res er - voirs, re sult ing ei ther in the fill ing of the traps or in dis per sion of hy dro car bons. Ac cu mu la tion was nearly con cur rent with mi gra - tion. Hy dro car bons were en trapped in the Mid dle Cam brian traps de scribed as struc tural traps, e.g. faulted anticlines. Mi gra - tion from the youn ger, Up per Cam brian–Tremadocian source rocks to the older, Mid dle Cam brian res er voirs was guar an teed by many faults with throws cre at ing con nec tion be tween these ho ri zons. Ex pelled hy dro car bons were en trapped with in sig nif i -

cant losses as only gas yielded in the on shore part of the re gion un der went dis per sion.

2-D mod el ling of pe tro leum pro cesses re vealed per spec tives of the dis cov ery of new oil and gas fields in the study area of the Bal tic re gion. The most gen er a tive are the Up per Cam - brian–Tremadocian source rocks, lo cated in the Darłowo and the Słupsk blocks, and in the on shore part of the Łeba Block where fa vour able ther mal con di tions were achieved. The study in di - cated a dom i nant west-east mi gra tion path way, hence the Słupsk and the Łeba blocks are per spec tive for pe tro leum dis cov er ies.

Ac knowl edge ments. The re search was un der taken as part of a pro ject of the Min is try of the En vi ron ment (No.

182/2005/Wn-06/FG-sm-tx/D) and the Pol ish Min is try of Sci - ence and Higher Ed u ca tion grant No. N N307 2498 33.

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