Quantum Mechanics List of Problems, Section 3 Problem 0 ) A warm up.
Suppose we have a free quantum particle confined in [0, d]. The corresponding Hamiltonian takes the form
H = −¯h2 2m
d2 dx2 ,
acts in L2(0, d) and the functions from its domain satisfy u(0) = u(d) = 0.
Find available energies and associated eigenvectors.
Problem 1)
Assuming that ˆH = 2m1 ˆ~p2 + ˆV (~r), find a) [ˆpj, ˆH] ,
b) [ˆxj, ˆH] , (j = 1, 2, 3).
Problem 2)
Suppose ˆH = 2m1 ˆ~p2 + ˆV (~r). Find the form of operator ˆx1(t) = ˆx(t) in the Heisenberg picture and position representation for
a) a free particle — ˆV (x) = 0,
b) harmonic oscillator — ˆV (x) = m ω22 xˆ2. Problem 3)
Check whether the operators ˆx(t1), ˆx(t2) expressed in the Heisenberg picture commutate.
Hint: use the result of Problem 2.
Problem 4)
Using the Schr¨odinger equation show the continuity equation
∂ρ
∂t + div ~j = 0, where ρ = |ψ(~r, t)|2. Furthermore, show a)
∂
∂t
Z
R3
ρ(~r, t) d3~r = 0, 1
, b) calculate div~j for the stationary states,
c) calculate ~j(ψp~(~r) where ψ~p(~r) is an eigenfuction of operator ˆp.~ Problem 5)
Find the eigenfuctions and eigenvalues of the energy operator for a particle moving in the potential field
V (x) =
( V0 if 0 ≤ x ≤ a, 0 if x < 0, x > a,
where V0 > 0 a > 0 (the barrier potential). Find the reflection and transition coefficients.
Problem 6)
a) Find the eigenfunctions and eigenvalues of the energy operator for a par- ticle moving in the potential field
V (x) =
( 0 if 0 ≤ x ≤ a, V0 if x < 0, x > a, and V0 > 0 (the well potential).
b) Consider the case V0 → ∞.
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