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Związki porfirynowe niklu i wanadu jako wskaźnik warunków środowiskowych przy powstawaniu i zachowaniu bituminów i rop w skale

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LITERATURA

1. Diemienkowa P. Ja., Zacharienkowa L., N. !I. in. - Nie1mtoryje dannyje 0

rasprostranie-nil wana'dIJa, niktielja i porfirynow w IIlidiach

ta-dZiksko! diepriessii Sredniej Azii. Trudy WNIGRI,

Wyp. 174, Geochim. sb. 1961, nr 7.

2. Diemienkowa P. Ja., lZalCharienkowa L. N. - Porfiriny w nieftiach , 'bituminoznych k<lmP<d.entach organiczeskogo wleszczestwa porod wolgo-uralskoj nleftien-osnoj oblastL Ibidem, wyp. 279, ab. [969, nr 10.

3. Dun n f n g H. N. - GeIOOhemiJsltry

at

Gl'gan:ilc

pig-menJts.

International Senies of Manographs on Eal'Ith Sciences. vol 16. Organic Geochemistry, 1963.

SUMMARY

The paper deals with the research on the geo-chemical interpretation of rthe porphyrflls found Ito ocCUr in ·the dlesemliinated bdtum~us substance of rocks. On :the basis of ample <reSearch material some corre1ati;o:ns have been analysed, and a confrontation has been made between the occurrence of porphy-rim and the organJic carbon cODtent !in rocks, the metamorphism degree of bituminous substance, the oxidation-reduction character of rock environment, :and the liithaloglcal -develxlpmenit of deposifts. The general mterrelations mve9tig~ revealed a func-tion of the parphyrins in the evaluafunc-tion of p~ro­ leum conteat in rocks.

It has also been ascertalined that any interpre-tartion of !the differenltaltion in porpbGTins observed to appear in the profiles lis !to be made always fill a conlfrontation wilth other geochemical exam6.nallilons. The research has demonstrated that porphyrins are one 01. very senstlive inddC8ltor1:l for Ithe

determina-lbion of the environmental conditions, syngenetical and epigenet1cal nature of bituminous subSltance, and mother character of rocks. The study o.f variations :in occurrence of porphyrlns is also very important in detennination of 'the general difTecrtions of

hi/tU-men migration, and !in definition of genetical rela-tions between the bitumens of different

&tratfgraphi-ca! 'h01'li2oos of the area studied.

On /the basis of a drilliog made withIn the Pod-lasie depression an antllysis hBlS been made of Itbe variaddon in the occurrence of porpbyrins. Moreovet", an ,interpretation is presented of the results obta-ined, dn terms of ~ and migreMon of bitumens.

4. Dunnltng H. N., Moore J. W. - Porphy-rin research and origin of !peItroleum. Bull Assoc. Petrol. Geol. 1957, vol. 41, No. 11;

5. G 0 n d e k B. - Stopie1l zmetamorfizowania bitu-min6w ~ladowych jako wskdnik

w

poszukiwa-niach ropy nldboweJ. Kwart. geol. 197~,

.or

2. 6. H'O d g S -0 D G. W. i in. - Geochernistry of

por-phyr;lns, chlorins and policyclic aromatic !n soils, sedimenbs and sedimentary rocks. Geochim. Cos-mochdm. Acta 1968, vol. 32.

7. Nagy B., Colombo U. - Fundamental

as-pects of petroleum geochemistry. Amsterdam, Lon-don, New York, 1967.

8. R

a

d c zen k

°

O. A. - W-oprosy gieochimfi

par-firinow niefiiej. Dokl. AN SSSR. 11960, ,to 134, .or 3.

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