Zabytkoznawstwo i Konserwatorstwo XLIV, Toruń 2013
Tomasz Kozielec*, Grażyna Szczepańska**, Grzegorz Trykowski**
* Zakładu Konserwacji Papieru i Skóry WSP UMK
** Pracowni Analiz Instrumentalnych Wydziału Chemii UMK
Przykłady wykorzystania analizy SEM-EDX
do badań zabytkowych skór
garbowanych związkami metali
Skóry garbowane związkami mineralnymi
– zarys tematyki
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Wykorzystanie
skaningowego mikroskopu elektronowego
z detektorem EDX
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Obecność w skórach
wyprawionych pozostałości
związków pomocniczych, środków używanych
do zdobień oraz zanieczyszczeń
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S +,-C8D8AH+J89=?-5+A7B:7+-8:+D-:<ADH<7-4J8AB4-4-F?<AD7+=>-L5?<1A15?UH<-:<ADH7?-C8;=D+A-8I:BI7?-A7B:3-b-8I<=589c-7<-:+H353- D+4?<:+6@=<6-
A?+:7U,G-I,- .+"K- 1234+53- ;8- C:D3AC?<AD85<E8- LHD4M- D+8AH:D85<E8,- 4+C5?<5?+- A7B: =,- KXd- D- C84?<H:D+
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?4:-*$ '(20&#)-083 :& '!"#+ -$<+(!42& (4 '240'($ P($<90.$ ?&*)&9&%&2$Q3 A)+: -*$.-*$ .-6H8 (24#-@.+./ %@ 70$'(!"2 %&'( 2+!#+2$*$ 2 <$)$*+./ 7#"<-!$./= q$<#5)-&*0$ !5#-&,3 <14(&, 0 20&94,$ 0**+,0 '5<'($*.%$,0 7#-+-.-+*0$%@ '06 )4 742'($2$*0$ .0&,*+./ *$2$#'(20&N *$ '!"#-& D&'(#$ %*)$ %+). B!1$) 70$'(!42+ -*$.-*0& 5#4-,$0.$%@ O$#<+ 5:+2$*& )4 )&!4#$.%0 2+-#4<"2 '!"#-$*+./= q0)&*(+s!42$*0& 2 $*$90-0& B^?S^CY 2+'(675%@.+./ 2 <$)$*+, ,$(�$9& 70$'(!"2 4#$- 5'($9&*0& 2-4#"2 -20@-!"2 ./&-,0.-*+./ 74-2$9$ 4!#&H908 20&! -$<+(!5 0R95< 2+!4*$*+./ -)4<0&N 0 7#-&-,$942$N= B-.-&A"9*0& 4<s.0& -)4<04*& '@ !$#(+ 7&#A$,0*5 G ,0*0$(5#$,03 <4#)05#$,0 0 7#-&70'+2$*+,0 (&!'($,0= I 2+*0!5 4)!'-($1.&*0$ '06 7&#A$-,0*53 !("#+ %&'( ,$(�$1&, <$#)-4 2#$:902+, *$ -,0$*+ 209A4(*4H.0 74-20&(#-$3 *$*0&'04*& 70A,&*(+ 4'+75%@ '06 0 '@ 0)&*(+s!42$*& 2 74'($.0 7+15
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Uwagi końcowe
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Summary
Examples of application of the SEM-EDX technique to examination of antique mineral tanned leathers
T7790.$(04* 4O (/& B^?S^CY (&./*0{5& O4# )&(&#,0*$(04* 4O &9&,&*(' 0* $95, $' 2&99 $' ./#4,& ($**&# 9&$(/&#' )0'.5''&) 0* (/& $#(0.9&= f/&'& 9&$(/&#' $#& O45*) 0* ,5'&5,3 90<#$#+ $*) $#./0j$9 .499&.(04*'= T95, ($**&# 9&$(/&#' $#& !*42* '0*.& $*.0&*( 7) 2/09& ./#4,& ($**&# 9&$(/&#' O4# Jc(/ .= ^p$,79&' 4O (/& 5'& 4O 9&$(/&# '$,79&' &p$,0*$(04* $*) #$*A& 74''0<090(0&' .#&$(&) <+ (/& (&./*0{5& 7#&'&*(&)= T))0(04*$9 '5<'($*.&' D*4( <&0*A ($**0*'E (4 <& O45*) 0* 9&$(/&# '(#5.(5#& $) '5#O$.& '5./ $' $5p090$#+ $A&*('3 )&.4#$(0j& 9$+&#'3 .4*($,0*$(04*'3 O4.5'&) 4*= f/& B^?S^CY (&./*0{5& 0' 5'&O59 *4( 4*9+ O4# ./$#$.(�-$(04* 4O &9&,&*(' .4,74'0(04* 4O 9&$(/&#'3 <5( $9'4 .4*(#0<5(&' (4 7#&'&#j$(04* 4O .59(5#$9 /�($A& <+ A0j0*A 74''0<090(0&' 4O 79$**0*A .4*'&#j$(04* (#&$(,&*(' $*) &p$,0*0*A 0*z5&*.& 4O .4*'&#j$(04* ./&,0.$9' 4* 9&$(/&#'=
g4(= J= B!"#$ A$#<42$*$ A90*424 5:+($ )4 47#$2+ !'06A03 '($#4)#5!3 4!1$)-0*$ 7#-&)*0$3 -<04#+ ]0<904(&!0 ^9<9@'!0&% DO4(= f= W4-0&9&.E
g4(= K= B!"#$ A$#<42$*$ A90*424 5:+-($ )4 47#$2+ !'06A03 '5:+-($#4)#5!3 '(#4*$ A#-<0&(42$3 -<04#+ ]0<904(&!0 ^9<9@'!0&% DO4(= f= W4-0&9&.E
g4(= M= W$O($* 74) !49.-5A6 2+!4*$*+ - (!$*0*+ 0 '!"#+ A$#<42$*&% A90*424 D,4.*4 -$-<#5)-4*$E3 '(#4*@ ,0-)#42@ *$ -&2*@(#-3 4!= Jnee #=3 -<04#+ ]0<904(&!0 aT` 2 W"#*0!5 DO4(= f= W4-0&9&.E
g4(= d= W$O($* 74) !49.-5A6 2+!4*$*+ - (!$*0*+ 0 '!"#+ A$#<42$-*&% A90*424 G -<90:&*0& .-6H.0 '!"#-$A$#<42$-*&%3 4!= Jnee #=3 -<04#+ ]0<904-(&!0 aT` 2 W"#*0!5 DO4(= f= W4-0&9&.E
g4(= l= a#"<!$ <0$1&% '!"#+ A$#<42$*&% A90*424 74./4)-@.&% - 7$'!$ '74)*0 D74) !49.-5A63 4!= Jnee #=E= U<#$- 7#-&!#4%5 7#"<!0 5-+'!$-*+ 7#-+ 5:+.05 )&(&!(4#$ ]B^= |"1(@ #$,!@ -$-*$.-4*4 4<'-$# 74-,0$#5 7#"<!0 )4 2+!4*$*0$ $*$90-+ ^CY= q$2$#(4H8 A90*5 2 *05 ^CY D7$(#- 470' O4(= mE 2+*04'1$ K3dlw $(4,42&A4 )9$ <$)$-*&A4 4<'-$#53 74206!'-&*0& Jle p DO4(= _= f#+!42'!03 f= W4-0&9&.E
g4(= m= a#"<!$ <0$1&% '!"#+ A$#<42$*&% A90*424 74./4)-@.&% - 7$'!$ '74)*0 D74) !49.-5A63 4!= Jnee #=E= U<#$- 7#-&!#4%5 7#"<!0 5-+'!$-*+ 7#-+ 5:+.05 )&(&!(4#$ ^CY G ,$7$ #4-,0&'-.-&*0$ A90*5 2 .$-1&% 7#"<.& H20$).-@.$ 4 2+'(6742$*05 A90*5 *$ .$.$-1&% A#5<4H.0 7#"<-!0 '!"#+3 .4 %&'( '7&.+s.-*& )9$ (+./ '!"#3 74206!'-&*0& Jle p DO4(= _= f#+!42'!03 f= W4-0&9&.E
g4(= n $ 0 <= a#"<!$ :"1(4S!#&,42&% '!"#+ A$#<42$*&% A90*4243 74./4)-@.&% - 9$,"2!0 -$-<+(!42&A4 '04)1$= U<#$- 7420&#-./*0 7#"<!0 5-+'!$*+ 7#-+ 5:+.05 )&(&!(4#$ ^CY G ,$7$ #4-,0&'-.-&*0$ 2$7*0$ D!494# .-*+E 0 '0$#!0 D!494# -0&94*+E 2 .$1&% 7#"<.& H20$).-@.$ 4 4<&.*4H.0 A07'53 74206!'-&*0& Jeee p DO4(= _= f#+!42'!03 f= W4-0&9&.E
F+'= J= B./&,$( <5)42+ '!"#+ 2+7#$204*&% DM 2$#'(2+ 4))-0&94*4 4) '0&<0& 90*0@ 7#-&#+2$*@E D#+'= f= W4-0&9&.E
F+'= K= a#-+A4(42$*0& 7#"<!0 )4 <$)$N 7420&#-./*0 2#$- - 7#-&-!#4%&, '!4H*+, D#+'= f= W4-0&9&.E
g4(= [= a#"<!$ '!"#+ A$#<42$*&% ./#4,424 74./4)-@.&% - 1$(!0 D74 YYS20&.-*+./ #&7&#$.%$./E 5:+(&% )4 2("#*&% 47#$2+ Pq14(&-A4 W4)&!'5Q DT#./025, T#./0)0&.&-%$9*& 2 _*0&y*0&E= U<#$- 74-20&#-./*0 7#"<!0 D7$#(0$ 4) 74142+ 2 )"1 G %$H*0&%'-$E 0 7#-&!#4%5 '!4H*&A4 D7$#(0$ 4) 74142+ 2 A"#6 G .0&,*0&%'-$E 5-+'!$*+ 7#-+ 5:+.05 )&(&!(4#$ ]B^= q$-*$.-4*4 d ,0&%'.$ 74,0$#5; M 4<'-$#+ 7#4'(4!@(*& Dn[[K3 n[[M3 n[[mE 0 %&)&* 4<'-$# 75*!(42+ Dn[[dE )4 2+!4*$*0$ <$)$*0$ ^CY3 74206!'-&*0& Mee p DO4(= _= B-.-&7$N-'!$3 f= W4-0&9&.E
g4(= c= a#"<!$ '!"#+ A$#<42$*&% ./#4,424 74./4)-@.&% - 1$(!0 D74 YYS20&.-*+./ #&7&#$.%$./E 5:+(&% )4 2("#*&% 47#$2+ Pq14(&A4 W4-)&!'5Q DT#./025, T#./0)0&.&-%$9*& 2 _*0&y*0&E= U<#$- 7420&#-./-*0 7#"<!0 0 7#-&!#4%5 '!4H*&A4 5-+'!$*+ 7#-+ 5:+.05 )&(&!(4#$ ^CY G ,$7$ #4-,0&'-.-&*0$ :&9$-$ *$ 7420&#-./*0 '!"#+ D74./4-)-@.&A4 - .-&*0 :&9$-42&%E 4#$- ./#4,5 *$ 7#-&!#4%5 '!4H*+,
g4(= Je= a#"<!$ 74./4)-@.$ - 7&#A$,0*5 5:+(&A4 2 Pq14(+, W4-)&!'0&Q DT#./025, T#./0)0&.&-%$9*& 2 _*0&y*0&E= U<#$- 7#-&!#4%5 7#"<!0 7&#A$,0*5 D- 0,0($.%@ -14.&*0$ *$ %&A4 7420&#-./*0E 5-+'!$-*+ 7#-+ 5:+.05 )&(&!(4#$ ^CY G ,$7$ #4-,0&'-.-&*0$ ,=0*= ,0&-)-0 0 .+*!5 D'(47 (24#-@.+ ,4'0@)-E3 74206!'-&*0& Klee p DO4(= _= B-.-&7$N'!$3 f= W4-0&9&.E
g4(= JJ= q$-*$.-&*0& 4<'-$#5 7#-&-*$.-4*&A4 )4 $*$90-+ ^CY -$ 74,4.@ 90*00 )47$'42$*&% )4 !'-($1(5 7#"<!0= U<#$- 7#-&!#4-%5 7#"<!0 5-+'!$*+ 7#-+ 5:+.05 )&(&!(4#$ ]B^3 74206!'-&*0& Kle p DO4(= _= f#+!42'!03 f= W4-0&9&.E
g4(= JK= B!"#$ - )-0!0&A4 -20&#-6.0$ D7#$2)474)4<*0& '$#*$ 95< %&9&NE A$#<42$*$ A90*4243 20)4! 2 ,0!#4'!470& '(&#&4'!4742+,3 H20$(14 4)<0(&3 74206!'-&*0& n p DO4(= f= W4-0&9&.E
g4(= JM= B!"#$ - )-0!0&A4 -20&#-6.0$ D7#$2)474)4<*0& '$#*$ 95< %&-9&NE A$#<42$*$ A90*4243 <$#)-4 0*(&*'+2*0& -$<#5)-4*$ 7420&#-./-*04243 .4 -206!'-+14 -$2$#(4H8 A90*5 2 7#"<.&3 20)4! 2 ,0!#4'!4-70& '(&#&4'!4742+,3 H20$(14 4)<0(&3 74206!'-&*0& n p DO4(= f= W4--0&9&.E
