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space Propulsion 2012, 7-10 M a y 2012, Bordeaux, France,

Model for Predicting tlie Lifetime of a Hall Effect Thruster

V r e b o s c h T . M . F .

Graduate student, Aerospace Faculty, TUDelft, Kluyverweg 1,2629 HS Delft, The Netherlands

M i s u r i T . , A n d r e m i c c i M .

Alta SpA, Via A. Gherardesca 5, 56121, Pisa, Italy

Z a n d b e r g e n B . T . C .

Aerospace Faculty, TUDelft, Kluyverweg 1, 2629 HS Delft, The Netherlands SP2012 2354244

Erosion of the acceleration channel is the main lifetime limiting factor for Hall Effect Thrusters (HETs). Impacting ions damage the wall insulation that protects the magnetic circuitry from the plasma. To improve H E T technology, it is necessary to simulate plasma behavior inside the channel, and associated erosion rates. This work presents a 2-dimensional Particle-in-Cell model, developed to predict channel wall erosion in Hall thrusters, using an SPT-100 as reference thruster, and providing estimations in good agreement with experimental values. The model allows for evaluation of different erosion mechanisms, both combined as individually. From different simulation results, erosion due to the sheath conditions has proven to be the dominant source for wall erosion.

Nomenclature

A

=

cross-sectional area dt

=

iteration time step dx, dz

=

spatial step e

=

electron E

=

energy i

=

ion m

=

mass n

=

particle density q

=

elementary charge S

=

sputtering yield T

=

temperature ll, V

=

velocity w

=

wall r

=

particle f l u x Vi

=

ionization frequency

ü e secondary electron emission

=

collision cross-section

=

electric potential B N

=

Boron Nitride F D

=

Flow Divergence PS

=

Particle Scattering SE

=

Sheath Effect

SEE

=

Secondaiy Electron Emission

I. Introduction

H a l l Effect Thrusters are a type o f electric propulsion, used f o r accurate attitude and orbit control which demands l o w thrust and high specific impulse^'^''^. For such missions, typical lifetimes o f about 3000 hours^ are needed, which is easily satisfied b y the 7000 hour lifetime of, for example, the SPT-100^''^ Hall thrusters have proven easy throttleability and scalability^'^, and exploiting their capabilities i n an expanded range o f missions, requires further investigation o f their performance and extension o f their lifetime.

Different than f o r chemical propellants, for which the propellant storage and mass limit the operation period, the lifetime limiting factor for many electric thrusters is the interaction o f the structure w i t h the plasma. Among them, HETs suffer f r o m erosion o f the discharge channel. The channel w a l l insulation protects the magnetic circuit f r o m hazardous particle. When the magnetic circuitry is exposed to the plasma, overheating or further degradation o f the system leads to decreased thruster performance. Once the protecting insulation is fiiUy eroded, the end o f the thruster's lifetime is reached.

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As l i f e tests are time-consuming and expensive, monitoring w a l l degradation demands f o r computational erosion models. Such programs serve two purposes. First, they predict the lifetime and plasma behavior for a given thruster configuration. Second, they provide design requirements to meet a given set o f specifications. Data can be acquired repeatedly f o r different conditions, cost-free, and i n a short period o f time.

Different than simplified erosion models'^''''" which only attribute erosion to particle collisions and include other phenomena by scaling factors, the aim o f the presented model is to provide erosion estimations within 15% o f available empirical data, and to produce valuable data f o r different erosion mechanisms. The program allows f o r evaluation o f all erosion mechanisms either combined or separately.

II. Channel Wall Erosion

When highly energetic ions impinge on the channel wall, they remove material f r o m insulation that protects the circuit. So far, three erosion mechanisms are Imown, all related to i o n bombardment: flow divergence as a result o f the magnetic field topology, and particle scattering and sheath effect, which originate f r o m the plasma behavior inside the channel.

A. Erosion Meclianisms

1. Sheath Effect

Through the boundaries, energy and particles enter and leave the system. Due to their l o w mass, electrons have a much higher thermal velocity than ions, and the electron flux to the boundaries o f plasma exceeds the ion flux. Given this flux imbalance, the non-conductive channel w a l l acquires a negative charge, which repels electrons and accelerates ions such that the ion and electron flux at the wall becomes equal. This process thus generates a sheath, also called Langmuir sheath, w i t h a negative potential (p„ that regulates the particle flux towards the walls and acts as a barrier to shield the plasma f r o m the different conditions near the wall. The total potential i n the sheath is equal to

<Pt„t=(Po+(P,v=9t 1 + l n m,

v27im^y - l n [ l - G j ]

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w i t h (po the pre-sheath potential, (p„ the potential drop i n the sheath and Oe the secondary electron emission (SEE). Parameters W; and represent

the ion and electron mass, respectively. Ions enter the sheath w i t h a minimum normal velocity called the Bohm velocity:

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w i t h Te the electron temperature and k the Boltzmann constant.

As the sheath is created to control the ion income at the wall, the generated potential is strongly related to the ion impacts due to remaining erosion mechanisms. A second important parameter is the re-emission o f electrons into the plasma. From experiments, the SEE is found to be related to the plasma temperature, and conversely, the temperature depends on the number o f re-emitted electrons. Combining a formula used by Y i m ' ^ and data found by Raitses^ yields the applied equation for the secondary electron emission:

40 (3)

From recent experiments performed by Gallimore and H o f e r ' ° , large density gradients are measured at the plasma boundaries. These gradients shift the acceleration zone close to the wall fiirther upstream, which results i n a defocusing o f the electric field. During test w i t h a discharge voltage o f 300 V , a radial electric field o f about 50 V was established near the thruster's exit. This radial potential drop is very similar to the theoretical Langmuir sheath potential (eq. (1)) o f about 70 V for the same operation conditions. So far, i t is not clear to what extent the sheath effect and the electric field deviation due to density gradients are interconnected. Even when considering the observations as two separate phenomena, a radial electric field o f the same strength is generated, attracting ions that impact the insulation. Therefore, either process can be simulated by introducing a general electric field which drives ions towards the wall. As the measurements are performed recently and the process is poorly understood, ion deviation due to a radially established field is allocated solely to the Langmuir sheath.

2. Particle Scattering

While being accelerated, ions encounter other particles before escaping the thruster. Although plasma is only slightly colUsional, fi-om time to time, ions are diverted f r o m their path due to

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space Propulsion 2012, 7-10 M a y 2012, Bordeaux, France. collisions w i t h neutral atoms. A f t e r colliding, they

might hit the channel wall thereby damaging the insulation.

The number o f particles that are scattered, is determined by the collision cross-section a-m. One unambiguous formula does not exist since the collision cross-section is derived f r o m experimental data. However, a common characteristic is that the cross-section for collisions depends on the size o f and the relative velocity between the two colliding particles. The adopted formula'' (for xenon) for this model is

a , „ = 1 . 2 0 - 1 0 - ' « - 1 . 9 6 - 1 0 - ' ^ - M u , , , ) (4)

where M,.^/ is the relative velocity between the colliding particles. The coefficients i n front o f the exponentials stand for the atom size, and thus depend on the propellant.

3. Flow Divergence due to Magnetic Field Flow divergence can arise f r o m a misalignment o f the magnetic field. The equipotential lines o f t h e electric field tend to aUgn themselves w i t h the magnetic field lines, which causes the ion beam to diverge near the exit i f the magnetic field has a defocusing effect. Deviating ions impinge on the w a l l and deface the insulation layer. However, i t is apparent that the erosion originating directly f r o m flow divergence is zero for properly designed magnetic circuits^''^ (i.e. converging the ion flow inside the channel), which classifies flow divergence due to the magnetic field as a negligible erosion source.

B. Sputtering Yield

When impinging ions are sufficiently energetic, they remove one or more atoms fi-om the chaimel wall. The sputtering yield depends on several factors, such as the impact angle, i o n energy and insulation properties. The formula used to model the sputtering is a semi-empirical formula derived f r o m experimental data and based on the theory o f Yamamura and Tawara^'*. As Boron Nitride ( B N ) is the insulation material used for most SPT-100 experiments, formula derived f r o m l i f e tests is

S = (0.0099 + 6.04 • 10-^ - 4.75 • 10^"* )

where y is the impact angle (degrees) w i t h respect to the normal to the wall, Ei the impact energy (eV) and E^}, the threshold energy for sputtering (which is estimated'' at 58 eV). The coefficients i n front o f the impact angle are typical for B N . Hence, i f a different insulation is to be modeled, new coefficients have to be derived f r o m experimental data.

III. Model Description

The simulation is based on a Particle-in-Cell (PIC) method. Particle motions are modeled i n a 3-dimensional grid, whereas the erosion is modeled in 2-dimensional reference frame, as w a l l degradation is considered axisymmetricaP•"''^ The primary input consists o f the 3-dimensional mesh grid, the magnetic field topology and the operation conditions. What follows, is a description o f the program structure and the numerical methods that simulate the erosion processes.

A. Program structure

Figure 1 shows the flow diagram o f the program. First, the initial operation conditions and thruster dimensions are set. From the selected input, plasma and electromagnetic properties are determined for every cell o f the grid. Then, the simulation loops the different algorithms that model the erosion processes. One can distinguish clearly the aforementioned erosion mechanisms.

Although the program allows for separate simulation o f each phenomenon, investigating each mechanism individually needs careful attention, because the processes erode the insulation simultaneously, and therefore influence each other. Furthermore, evaluating erosion due to the sheath, requires simulation o f the other erosion mechanisms as w e l l (see * i n figure), because the sheath conditions depend on the incoming ions due to these processes. Even though flow divergence due to the magnetic field has been omitted as erosion source, the process is still incorporated i n the program, i n order to allow designers to investigate the influence o f the magnetic field topology.

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Input thruster dimensions and operation conditions

Scaling magnetic and electric field

I

Plasma parameters

Y/N Y/N

Particle scattering Y/N Flow divergence Particle scattering Flow divergence

Sheath effect

Update channel dimensions

Figure 1: program flow diagram

A f t e r a given operation period, the thruster dimensions are updated and the plasma properties are recalculated. The electric and magnetic properties for each cell do not have to be reseated after each update o f the channel dimensions, because the shape o f the magnetic field is not altered as the insulation materials i n HETs have a relative magnetic permeability" o f 1.

B. Physical Relations

The discharge is modeled assuming quasi-neutrality throughout the plasma. Electrons are treated as a fluid, whereas ions (and neutrals) are dealt w i t h as discrete particles. I n every axial section o f the channel, the total and partial particle number densities are determined. This means that each type o f ion i n a certain section, i.e. having a mutual ionization position, is treated individually. Particle motions are simulated during an iteration time step dt, and averaged over a given period T i n order to update the channel dimensions, and accordingly, the plasma properties.

To model the behavior o f stationary quasi-neutral plasma along the discharge channel, a set o f differential equations is used. The seven unlcnowns i n the system are the i o n number density w,-, neutral number density n„, i o n velocity Ui, neutral velocity u„, electron velocity M„ electron temperature and electric potential 9. These parameters are all evaluated solely along the thruster's axis. When all plasma parameters are

determined, ion scattering, flow divergence and the sheath effect are simulated.

The continuity equations only account for singly ionized particles. The effect o f doubly ionized ions is not considered i n the simulation.

dx dx

where A is the cross-sectional area and Vi the ionization frequency (s"'), which is defined b y

(7) w i t h (7/ the ionization cross-section and Ve the electron thermal velocity.

Next, the ion momentum equation describes the forces influencing the ion motion.

du, dm

dx dx •Vim (8)

where d(p/dx represents the electric field. The ionization process has no influence on the momenhim o f single ions (PIC method), and therefore, the ionization term can be omitted f r o m the equation.

As electrons are modeled as a fluid, introducing the electrons i n the model is achieved by setting the electron density equal to the ion density (quasi-neutrality) and replacing the momentum equation and energy conservation for electrons by experimental values for the electron temperature Te. The corresponding thermal electron velocity

2/f7;

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Further, i t is assumed that the neutral velocity is constant, as they are not susceptible to electromagnetic forces.

du^

dx (10)

Important to notice is that the magnetic field is not included i n these fundamental equations, and yet, i t is stated i n the introduction that the magnetic field has an important influence on the motion o f particles. I n H a l l ttu-usters, the magnetic field has no direct influence on ions due to their large Larmor radius. Consequently, ions only feel

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space Propulsion 2012, 7-10 M a y 2012, Bordeaux, France. the magnetic field b y its eflEect on electric field. O n

the other hand, electrons do feel the attraction o f the magnetic field, but their motion is simplified b y the introduction o f experimental data. Therefore, the magnetic field is omitted f r o m the fundamental equations that define the plasma, but directly implemented into the program.

IV. Erosion Model

Evaluating the fundamental equations f o r all sections individually yields a solution o f the behaviour o f all plasma parameters. From these parameters, the number o f collisions Ncou is found, and successively, the number o f free particles Nfree (i.e. particles that w i l l do not collide but f o l l o w their (diverging) path towards the exit).

A. Particle Scattering

The true number o f collisions that occur i n a period dt and over a distance dz is

^coU = {niiiiA)-{n„ai„dz)-dt (11)

i n which the first factor is the ion munber flow rate and the second factor the probability o f an i o n hitting a neutral over a distance dz. Once the number o f collisions i n each cell f o r each type o f ion is known, the motion o f the ions is simulated. The elastic ion-neutral coUisions are modeled by a Monte Carlo method. The scattering direction o f the colHding particles is represented by one random angle p, and a random collision coefficient a:

- a: determines the magnitude o f the collision. Its value ranges f r o m -1 to 1, where -1 indicates a head-on collision, and 1 signifies that the ion only grazes the neutral.

- p: indicates the scattering direction i n the plane perpendicular to the thruster axis. Its value ranges f r o m 0 to 2%.

The resulting i o n velocity vectors are

"z,co;/ = 0 - 5 k +«„)+0.5(i/, -u„)-a

Uy^,„i =0.5{u, - ü „ ) ( l - a 2 f % i n ( p ) (12)

= 0.5(i/,-i/„)(l-a2)'''cos(|B)

A number o f colliding particles T i s simulated, and the eroded material volume i n a time interval dt is

= Sq 'coil (13)

B. Flow Divergence

The simulation o f flow divergence is very similar to the simulation o f ion scattering. The true number o f free ions, i.e. the ions that do not collide w i t h other particles, is the total number o f ions minus the colliding ions.

Nf,,,={niAdz)-N, coll (14)

A number o f free particles K is simulated, and the eroded material volume i n a time interval dt is

-Sq- I fre, K

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C. Sheath Effect

For each position along the channel w a l l , the sheath potential that is required to balance the ion and electron flux, is calculated w i t h

9,. = — I n l 9 T, F o+ T, p . 2nm, I-a. 2nm, i m, ( 1 - o J (16)

Next, i t is computed what the corresponding electron flux Tg (m"^s"^) is towards the walls:

= 0 . 5 n ^ - e x p 99»

2%m, ( l - a e ) (17)

The total i o n flux to the walls must coincide w i t h the net total electron flux. The number o f ions attracted b y the sheath (per second) is therefore

Ir, -N. coll 'free K N free dt (18)

where is the surface area o f the individual axial sections, Icoii and fyee are the number o f simulated w a l l impacts due to particle scattering and flow divergence, respectively.

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Ions that are not diverted towards the wall due to scattering or f l o w divergence enter the sheath w i t h the Bohm velocity (eq. (2)) i n nonnal dnection, while their tangent velocity is determined by the applied electric field. Once they enter the sheath, they are further accelerated by the negative sheath potential. I f the impact energy is adequate, the eroded volume per second is

,=Sq N SE

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where S is the sputtering yield, Nse the number o f particles entering the sheath, and Q the number o f simulated particles. 4.6 I 3.6 i 3 £ J 2.6 f 2 1.5 11¬ 0.6 a:

Radius Increase at Channel Exit

• »» simulation ^ Absalamov

0 100 200 300 400 600 600 700 600 900 1000

Time til]

Figure 3: increase o f the outer radius at tlie exit plane

V. Results

Figure 2 shows the simulated erosion o f the outer channel B N insulation for different f i r i n g periods w i t h an SPT-lOO'-'^ operating w i t h xenon. Measurements performed by Absalamov' are added to the graphs to ease the discussion and the validation o f the model.

The contribution o f the individual erosion mechanisms is demonstrated by the erosion rate graphs i n f i g . 4. As f l o w divergence does not occur f o r a focusing magnetic field, only the effect o f particle sputtering and the sheath are plotted. Comparing the individual rates to the total erosion rate, it is apparent that the sheath effect has a great impact on the erosion process.

Erosion Outer Wall

O aiGh + ECO h (Aisalsmav) + lOOOh

A-dal disiance from ihs anode [mm]

Figure 2: erosion o f outer channel w a l l

110"^ Erosion Rate Comparison at Channel Exit

X l . + Total + PS • S E 100 200 "' 300 400 600 soo 700 800 900 1000 Time [ll]

Figure 4; erosion rate f o r Particle Scattering and Sheath E f f e c t versus total erosion rate, outer channel w a l l

VL Discussion

Both f r o m literature and obtained model results, flow divergence as a result o f a misaligned magnetic field was discarded fi-om the erosion processes i n Hall thrusters. The contribution o f ion scattering amounts to barely 5%, and hence, the dominant source o f wall deterioration is found i n the interaction o f the plasma w i t h the wall.

Figure 4 demonsti-ates the significance o f the sheath effect. Especially after 300 hours o f operation, ion scattering almost disappears as erosion source, and the sheath conditions take over completely.

Figure 2 indicates the saturation o f the erosion rate, which can be directly linlced to channel widening. The velocity parallel to the wall, which is acquired by the appUed electric field, lowers when the angle o f the channel wall increases, and consequently, diminishes the impact energy as

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Space Propulsion 2012, 7-10 M a y 2012, Bordeaux, France. time proceeds. A second reason f o r decreasing

erosion rates is the plasma density which becomes gradually lower w i t h an increasing channel radius.

The erosion graphs i n fig. 2 and 3 are i n fair agreement w i t h experimental values for the first 600 hours o f operation, but after this period, overestimation is observed. Comparing w i t h the empirical data obtained by Absalamov\ the overestimation o f the maximum erosion is as high as 10%. I n addition, the erosion onset is shifted towards the anode.

W i t h the sheath effect as the dominant source of erosion, different reasons can explain the overestimation. W i t h the secondary electron emission defined as a function o f the temperature"'", its value remains constant because the temperature distribution is held constant i n the model. Further, according to Keidar and B o y d ^ the temperature distribution varies w i t h a change o f the SEE coefficient. Temperatiire variations influence the electron flux to the w a l l and the ionization process, and therefore the erosion o f t h e channel wall. Furthermore, the electron flux to the w a l l can alter because o f sputtered insulation material forming a lose layer on the channel wall, or b y backsputtered material f r o m the walls o f t h e vacuum chamber. Last, variation o f the surface stmcüire and electron bombardment" can increase the electron emission or lower the sputtering yield, thereby reducing erosion.

However, comparing theoretical results w i t h experimental data is not straightforward, as many variables such as the collision cross-section, ionization cross-section and the sputtering yield are all characterized by a statistical approach; any deviation f r o m the real values affects the erosion prediction. Additional experiments are required to perform f u l l validation o f the results, and to improve the model.

VII. Conclusion and Recommendations

The presented model i n this work forms a solid basis for the simulation o f erosion i n H a l l Effect Thrusters. It provides valuable information on how w a l l erosion originates. As ion collisions cause littie erosion and flow divergence does not occur for properly designed magnetic circuits, w a l l conditions have proved to be the dominant cause o f channel erosion, which has also been observed by recent experiments, and different theoretical models.

The simulation outcome shows a similar trend as obtained f r o m experiments^ and the erosion estimation is within 15% o f the measured values.

which was set as the goal accuracy f o r the erosion prediction. The difference w i t h empirical data becomes more significant w i t h increasing f i r i n g time. Different reasons clarify this behavior.

First, during life tests, the electron flux to the wall can alter due to interaction o f the plasma w i t h the environment. Next, during operation, the surface properties vary and thereby influencing the erosion rate. This effect is not simulated b y the model.

Study o f the literatiire reveals littie on the behavior o f plasma near a sohd surface. Recent experiments'" show potential drops near the wall, in radial direction. The developed model attributes this radial electric field completely to the sheath conditions. However, the source o f the generated electric field needs a thorough investigation because it seems closely related to the sheath effect as it is known to this day.

Research on the approximation o f plasma parameters, and the properties o f insulation materials and propellant, w i l l lead to a more detailed characterization o f the plasma. Moreover, thorough investigation o f the w a l l conditions and its interaction w i t h plasma is needed to further develop the program and to provide a more accurate prediction o f the lifetime o f H a l l Effect Thrusters.

References

[1] Absalamov, S.K., et a l . Measurement of Plasma Parameters in the Stationary Plasma Thnister (SPT-100). Plume and its Effect on Spacecraft Components, 28th Joint Propulsion Conference, A I A A - 1 9 9 2 - 3 1 5 6 , Nashville, T N , U S A , M y , 1992.

[2] B o y d I . D . and Dressier, R . A . , "Far field modeling o f the plasma plume o f a H a l l thraster". Journal of Applied Physics, V o l . 92, no. 4, p . 1767, August, 2002.

[3] Cheng, S. Y . , Modeling of Hall thnister lifetime and erosion mechanisms, Ph.D. Thesis, Massachusetts Institute o f Technology, 2007.

[4] Hofer, R. R., MikeUides, I . G., et al., BPT-4000 HaU Thruster Discharge Chamber Erosion Model Comparison with Qualification Life Test Data, 30th International Electric Propulsion Conference, IEPC-2007-267, Florence, Italy, September 1 7 - 2 0 , 2007.

[5] Keidar, M . , B o y d I . D . and Bellis, I . L , "Plasma flow and plasma-wall transition i n H a l l thnister channel", Physics of Plasmas, V o l . 8, no. 12, p. 5315 - 5322, December, 2 0 0 1 .

[6] Manzella, D . , Y i m , J. and B o y d , I . , Predicting Hall Thnister Operational Lifetime, 40th Joint Propulsion Conference, Fort Lauderdale, A I A A - 2 0 0 4 - 3 9 5 3 , F L , U S A , July 11-14,2004.

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[7] M i s u r i , T., Modeling and Scaling of Plasma Thrusters, Ph.D. Thesis, Pisa University, 2009.

[8] Raitses, Y . , Kaganovich, I . and Sydorentco, D . , Complex phenomena in magnetized plasmas in the presence of electron emission from the wall, Princeton Plasma Physios Laboratory (PPPL), August 1, 2008.

[9] Roy, S. and Pandey, B.P., "Development o f a Finite Element-Based Hall-Thmster M o d e l " , Journal of Propulsion and Power, V o l . 19, no. 5, September - October, 2003.

[10] Shastry, R., Gallimore, A . D . and Hofer, R.R., NearWall Plasma Characterization of a 6kWHall Thruster, l E P C -2009-133, Presented at the 31st Intemational Electric Propulsion Conference, University o f Michigan, A n n A t o r , Michigan, U S A , September 20 - 24, 2009.

[11] Sommier, E., AUis, M . K . and Cappelli, M . A . , \ t e x t i t { W a l l Erosion i n 2 D hall Thruster Simulations}, 29th Intemational Electric Propulsion Conference, IEPC-2005-189, Princeton University, October 31 - November 4, 2005.

[12] Taccogna, F., Schneider, R., et a l , "Kinetic simulations o f a plasma thruster". Plasma Sources Science and Technology, l O P Publishing L t d , U n i t e d K i n g d o m , M a y , 2008.

[13] Tondu, T., B e l h a j , M . a n d Z u r b a c h S., Total Electron Emission Yield of electric propulsion materials, 32nd Intemational Electric Propulsion Conference, IEPC-2011-105, Wiesbaden, Germany, September 11 - 15, 2 0 1 1 .

[14] Yamamura, Y . and Tawara, H . , "Energy Dependence o f Ion-Induced Sputtering Yields from Monoatomic Solids at N o r m a l Incidence", Atomit Data and Nuclear Data Tables, V o L 62, p . 1 4 9 - 2 5 3 , 1996.

[15] Y i m , J.T., Computational Modeling of Hall Thruster Channel WaU Erosion, Ph.D. Thesis, Massachusetts Institute o f Technology, 2008.

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