Bereiding van crotonaldehyde uit aceetaldehyde via het aldol

r·

I

,. I:. -p. -1\. If [t

-

r-I

f

I

!

!

I

I·

I·

!

I

,

1

I

_j !

I

I

I

I

_,

I

{

\

1

i

i

cd

IA ol

.r

.

l . C. va. ...

C;

t e 1 -::I)eHt

~

..

__

.

.

,

~

~

~/

A4 /U'lntlU -U21""n

?t:;

%

~

~

J'

III-t,jI-

~

~

/?'7-,6~~~0 ~~~

~

~~o

&~

...L0~0~ ~a.-~~~.a;A~~

.

~V"'I-lA ~ /Y-L~4c

.

~ të~ P9~~ (/~)

~(k;2

~

&6cP

/?~()

/1',;0,

₁

1

_.!

Itf"L

(LJ

17.>:)

1

tfJJ-I

!J''t

~-trtro I

r

j-)-

.ttnro

I '

"

Jo

l

-

,

L

, - J:

,i!

Q:.:=:

-

.

-r - --;.~

-_

r"

. -

l

~"

.. '-:

-

1'

I

I(;

i~~:;'

j:f

~~~

~i~

_

~

1

I

,I

.

.

I

,i

-

'

-'

l

'

-

'(

p

-C~--

l

+-

I

...

[

--rg~"':'

~

:

q

_~

~

~

-

,

~

I

)"1

..

lu.I ..

••

,

_

_

_

._

.

J

\

I1 I

t

= T. 1 !i; .

--

'::'

f

--'

-~- I' .,

.

t

i

i :

~ 1 ' -_ -.J -r--- I ~ r- i

~-

1 ~-.;..-=­ ent . . . lil . .

I

I · --if

,

1

...

i (1Il4ll.U

lcI'8t_l...,.

lu.tle 1IIl_ -,

I

l .

••

. . r~ ayl . . . . . IIEIDIID CIIOnIMALDEHYOE -

I

:

t

il

UIT ACEETALD€HYDE VIA HET ALDOL SCHAAL 1 :15 . J.LC YAN CEEL HEI 1tIt

A

.,.

k

-t( J ,

~

j

o l 20_c.'

t

2.oè. 3l)~ 35~

[--~

I

I

te

I

I

\ Sf>

.1

L ~ ~

~I

j

_,

" I

!

\ !

\ I

' : , ,

,: \

lf \ .t:,

L-;-T

-

....

t

I

I

99 C

!

,

I

r

'---~

v

\ fl..l ,:, 0 0.-'

,

_'l:> :

r

..

a

._--, 1 ',~I

-I

• I ~I

I

____________ ._1

,

1>e

r e~ cl j"'j Cf'ot.OI'\ Q,\o\ e'-1y ol. 1.\; t. (1'e.et, ~ltAehy"'e v:~ '"'el o.\.&ol

I

I

F

_I

I

,

~

,

t

H

J '!!"

I

@

\r~

McoJl

.l

I

I

I

~

J

,9., . .

--

. _ - - - -- -- -- -- -- -- -- _ ... --

---J

~

' h ·;~~k_:;----~

--, i ' J '." , , \-\ Q \. I'o( : '\

.

'" r_--..;...---,----.~r_-.---~;. ~ ____ ~ __ J__. __ •• _~_~ .... _ _ ._ :D : (V"'ot \."- I I t i

t.;

0< \ of ., " 'f ol E2 "

'10,0

fJ . i

83

_{C c..\"} 0\) ëd,i o,ss ; 0 _I ÇS I ClCeqt

Iq,S

0..1.,1 e \..1.1e. 44,oS, ~.'n S', I S \1,11 :

\n \NClte ..

\ 8

L 0,5, O,S1 S,' ~ \, I 1I

L, '

..

U

o.s

r

-

~.l.-q

_{.' -}

'

_-I Mr·_""I "I

~

~

I

:x

I

:1 \<

.J.

_

~~.~

~

__

~~~':c~1r-4

__ __

~=-~

__

~~~~~~,.L.c-~. 04 ~~-~~~#~.

d-&<·~----;

----___

_.

__

o-=

,?

-=

~c:LI~-7~ r~~-.t-a.l-,-) eNJ CH=eNCNo

~.L. ~

/á'sl

~

~-&&..,

~o&..4."". ~e~~e..A.

..-...cM

~...e~K&.;t6404 ....+" . . . ~ /,.r~

a..&

~

...

-;t'~

tJUc.&At

~

,,-

,6 ...4 ...

....e

_~1 c~ tIL .

~~c.c.Jlr.u..

J

....

...:-

~

~

-7~~~

~K~: CH.J.C-I-I

"

H-c..-CND

~

~'kLcrr1k ---4e.~

...

~

~

~eu.AI'~

~

~...,.

-:.s

D'S. «e...

é

A.,.

~

/ 4 ' " oe:. )

.

~

~

~~?'

~ ~~

~

,-4A.. oû.

~

J'

....«~

_q.6.,~~ ~~~~~

...

...,--~

;;;?-.h ...

~ ~ ~ 4L~rtJ<.. ~ - A - - - - 4 _~4~~ ~rJ'"

.l!J'JZ.

...,.Lc."40'~/

/ 1 ; 4 -

~

et.L.~rca.(a.

_

~~

~~

.,

~Lc~

...

~...L.c... .-c.La.e~.'

B...e.

~ ~ ~ / J ' A -.-4-e.e.e.~~cau.Ar~ ~ ~-..e.L,.L 11/

~/..t!

~

~

~r*(JII.4t'

...

.e.:,

----~ ~ tJI-R~r~

(

,.

(/-

J)

~~~~~

~u-:...'p--/.4.-

~r~

~ ~~r~

__

~e • ..,t' ~

--&-;?-.-.

..

.-h&ruL~

~~~

.

~~

..

~ ~aL~r..c....

_ _ A~ Pt!-e~ .-e- ___ ~~.~ ~

~~~~e-~ ~."-0-<- ~

~A.~

.-e

f"

J

ó10 -

Y

ti-o 0,- ---",~. ~ .

L:J...rz

~~

_k.

~·c.c:..::...p..A4r---

;r(;lL.~

~p&.L~r ~

..--:;/.'

~

MIl/i.

I

~

zj

~-...e~r~ ~

__

.4e. ___

°Uo - - - = 0 6 .. -c.-ec&A"'

-~ac..e.-t'r~ ~c:a..-~

_.-13;"

~~.~~OC ~ ~

~~~. ~~~..M

~

~IU&-~

~iÄ--~~d.

&d-tl

~~~ ~ aJ~re4. _ _ a-.. -e. ...

....-.c.&.

~~~/~ a.t440_~ .-8~

Lr" -

.J.rro. c. ...---.c- ~_ ... .: .. ...:..-. _ ~ á,J

'at..t.

(~)

~; ~ P c - ~ ..-R~~~ ~~

-...:.... -...

~~

•• '"'

~~

<U!.~ --4e~

....

·'10~

_~4~

•• ; ..

-!I

/37

~

~~~

~~

-,4.

..

&"C..~J'

....A'4-. ~ ~~4I-Ca. ~~ ~?JA~ ../Y~

~e.e..~ta-e~r -.Ga.. (_Q.,c/1' .. "--~-~;-4- A ___

.6.)

_.&

..

~

_____

~ _~~.4'a~c'l..,c. ___ ~ -"~~.t'.

..

~

~"

... 40..-

_«

~~

-47

".J°e

~

~.,-#,,~

~

~---

u,.

Ss-

~ ~ ...,...~..-&-t'

~~'~cD-'«c1Y~

~I!UA' ~ ---..,t!'~

--c?e. ...

~.

~A-....c.c--..4t _ _ ~ ~~ ~~~

~~ ~ .-a..L~ - ~ ___ ~e.~ --.:...- _4.A .~~ ..

G_:cK

...-Y'~ ~ ____ ~ - ...,....a.e-....-c..c.- ~/~~0&.?'4

~~.

~h~

.-..~~

_ , ... e~o-I!~ ~~--=- ~ ~

~~~Q.-~~" ...,.,a.tk ~ _____ ~ ~~OLCJ(y~ ~4IL

~

~

~~ ~/~~.

~.A-.~~

~fILA/' ~Pt..a:... ~ J~ ~ ~~ _ _ . . .

.-GÁ.. --"!~'l o.û

0&..4

~ ./YA-. ~ ~OGr-L ~)' ~ °

~.e.A,-..-.:..~

~~

~

~~

. _ _ _ i U .

/?I~

~ .&J~~ iK- ,,_ A.& _ _ Q.-. U:"'-' ...Ja.- o . û -

....k.-( 6

-

/ D )

~~F~~

'

../"rJl&-

~

41L~rD4..

~/a..~caGL ~ ~«..e~r~

~..-:-~~tao..-~ ~ ~~L<-Mt'

/.!/

t5:....<,....~~~

Aa-.

~~fÁ:

~

~tK

~~ ~ ~ .~o-e-~ ~~~f ~

~~/~

.,;~~~.,é.A~~

~~ ~ ~~A-t"p~.

~QL.L~I"~

~a-

---

~

~~r/k.(..

~~~.4.... ~ ~ _4LA!-&c..A"~~T'~

J.

~JJ...u~ ~~~~

.30

~

~~~

~

{~

~

r

~ ~

~

~

i

~

r

l

!"

t.

!

~ ~

~

r·

t

~

t

r

~

f

t

1

~ ~

~ ~

r

~ ~~

~

_

~

~ ~o

~~

~~~.

~~

,}J

~t"

f~;~

)}~1t~J

~

~~~~

.

)~

t

l~~~ltl

r

ti'·r

~t~

t~

1

1

~

,t,

I

.,,:('

F

..A4

~~

---

~

---... - ...

,<.~M

..

~<..,.

.... -

~

~~-L-I! ~~4.k7k ~

..

~.~;'

.-..,.,...

~~~c.:. ~7~o.ea.- ~

-G.~~ ~

..A../~ ~

-~~~r..c-

~~...--~

- . c -

~

.-8 -

cP lP / ' ~ ~ -~/..A-. a.~<-<

,6~

dJ: .:

11 - : : : ; - -

~o ~

y

\ I

j

_,

---

---, I,' cP .

..-e:e-:c.

~

7~-.N ~

...

~

."

~~

~/ ~ ~4R·«~<_·-~1

~.;~~~~~

(/~

/3/--d(.

~

~·~~~r:u. ~04-. ~

~~

~

---4~/~ ~

-e...

~

~

a..Lc...

-7~.-.k ---~ .--CA..r~ ~.

+-So,L Lc~ eNt!>

!/~~~

-~~~~ /'Ya.- Q.<.c..

.1

~~

o-r4n.

, ,>

~~

~~

-"Md~~:

~~~~/~ ~

--4-/

.-c..<..~ ~

c

'"'

cAt.~ •

!I

///?~~" ~..4- ~;tdr-L...::../ ~

~/.u.,

~~ ~ #'I1.a.~_~ ~~., ~,..."...,i ~J!LA

...

~

0/'

4'

~~

~

_

~Uc.'~

p..A;J

r-

~ ---~ ~

~

~~

~

~.~

~

.It1~/«&

AA"~P-~~

~~~04..J

Q c ....

~~-~-~7~

~~

~~~~

(J~-~t#~._v~)

U-.

c ... .o(<<CC41J-~ é~ ~~

-

..-L~~{' Dt:c. ~/:)~ {.A'«è"~

_______

~I&A.o.

.--6'/

~

.;

t:-~ k--~

/

----Lc:a-

o.

~

~

...-

~

~~

....

...e.c.-

~

a.Gc-..

_

~"

,

;

Pf)

%

~.-A-V~ ~

oU...

~/-~~

~

~

~L

"~f

~ ~

~~

~c4

f

,Ic-' ~ ~ ~d--c.

J.

-, \ , '. ,

-" ','-" . ~t:t' ' . • "

Ij

/J"~~ ..AMLc~Vlk

.:J

~~~

....u-

~

~p­

~~

~~

~/

~/-o~J'~~

D<A... ~ ~~ ~ ~ ~J ... ~~"",~ ~~~

~

~

(/') ---~

~ /W~~"

JIJk,..

~

~CW-4.p ~~~

~

~~

~~"'. ~~

".-.e..~c4

t

~

~

~

L

ii ~

~a.... ~f

~/~

-"

~~f'.

- - ~-~ ---~--

----/D.

,

~~

04.

~

~~C·~eh.~oL

(yD%)

~~~~

----~ ~ ~. t?d~...e ~r~ 0< .. _ ~..-:....

~La... ~,

t/..Ap'

PQ..,O<.~a. ___ .k~t:IH-~_

/ r

__

~ ~~~ ~~ro.-r...,...,....#-~---ta.~

~

'~

4'~

...-z---.

~r

~~/p.Lc.

;

-~

.*,.e~~

( ' ~~/ .6r<.~'"LOÛ- ..e~.-./ .-.-,~ ~?~.~

---~~~

~..a-

...

~

ftr

a:.LQ.,~~ ~CIIo4. ~

~ ~ ~ O!t.LO<.-<Al. / ' a<... ..,/'YQ.GP

L

~ ~

~~ ...-v-a..-.. .~~~~~...c... ; ~./:4:)C1/t...L~

~~--7~,fa.& ~.~ ~~-.A'~~

.-B-L

~

c.<.L

J!.e--~"

$ Û A -

~

.-...-....,~~~~

.

g

...e~~

,;~A:.~

.-A;"~?

~

~~

·

~<-...-t:-ç.~f

./"YW- a...t-L

~~~

~

--k.~

--6

6 ",-

~

a~~~

~~

-8j'~/~" ~~~~

~ _/~2.~ ?~~~« ~ ~ ~au,...(?"&.

(-~a..R

~;'.

",

6

%

/

--7~c.·~r

-./

~~~/~

....

"'4

..

.-u~

~~~./JM-.

_~-o.-<

~

OL~/,___

~

~...Ar ~

...

{?~~

~ea.- L.l----~.:J ~/

~

_/"~~

~

~~~J'

~~r-fA.

~

~pLr-~ ~"

~~~/,k

.P<A

~La.a:~

.

L

",il \ /.} , L: /~.

~~4i-~t-

-

~

-

~~

.JA.~

ll4.

~"'-K

LY~ ~/

~~~

.(.

~

( k

-

(h-

)

I'~'i ~

.8

(r-

~....RJ--

(

~;-~%

:.'

~~~­

~/ .A' ... ~~~r~ -e- ~O&A' ~

r--

....

~

/

-7

~ ~

~~

~./YY~

~s-da~

':z;" ....c-..."'7r"'...--v~ c,.G.(, ~

0/

~

-'7"

h.; /

h

"C a..e.~ ~ ~ tM.e...-LL~ ~~

(

~~~·c 71M:~---'-V1

)

8~..._.__aA' ~~o/

~r~ ~~~ ~rJ-~C ~~f~.L-o-""'-~ ~ ~~/ _~

.-vz.?

L.o--.. • ---

_____

~

~~

~~

~

cK.c....

~~~/

.-Y~ ~

~~

-e;;'.-&..

~~. ~~~

~r~

~a.~ ~ _.~ Ot-L~'/' ~

.

~~.~~

-.e---

~~~raLc..·

-

~

~0L4 ~

-

~a...t:..~r~

---

~~

.

~~~-'-

-'

~1fUI/Ik.--t;/ ~

~-4A!e.L"té~~r~

~J~.A... ~~ _-"P7at:4 ~ ~Q:..evt'.&. (~:a:t../

~~~r~

(/

~~-.L~r~ -~~

~

a..e~/

~

L~

~

~

~-..Lc

...

tU

-Rf

3S"'c.... / ~ ~~

6..J

~~

~ ~~b... ~tI=a:c ~

~~pY~

.J!..c-. ..A'V~ ~ ~ ~ ~

.b

ç

dJ,- Oe

...-a-

~~

~

;/./é

~~

(/J.J~c

/

~~

...

~eb

tU.e....L~ ~~ ~t! •• ~ ~~~ ~ ~ ~

~~A-.

~~a:.-td

{'

~_

~-.J~?,M.l.J ~_a...+

~1!A--?-~~/oJ"°c.

_

---=-

~

c

?~~.

~_

~

~~~~/~/

_

~0AA'A4-.;~ ~

~~ ~~eK..

~

~~A~~.c.

( ..

-

~

...

o..eoûJl.J

~~

",/7'?4 ____ c,re.-6ele:Sh ~ ~ -~~ aLa...4 ~7~

.--8;:'

~

~

~~.k...-&

~

~~~/

~

~/~

M'--:--" AoGc..

/U~.

é

~

e)

CRI . t ( \~ 1 . . . 1 \. ,", )':.~I ,.. I , " • -1f-- -lk) /.1.

c

;?'~

eH

('ell-() C ~ C A ' O I>$"% c~ CHlON)C~ CHO ---~ C HZ C",,::= C ~/ C N 0 -- ._, '-

---_

..

_ - - -

-c~ 1-- -.:....;:...---41 _ _ _ _ _ _ _ _ _ ---.

- -

-l_

~,;"~ h )~.;<'I ,-c.',p .... , '.' . A ' . '" .1 ~ I_I I, .... {, ",cd ..id, t lE)

I

IFJ

- -

--

.. -~ -- - - -- - - -~

-?, ~ a '~< • . . . . ; • . . ' • • _ _ _ ~ {\o)

~

I I . I _,

j

é-) I I ~t I 1 ", ti. / \ (.1"1',,1 ' • •

I , , I I

_

.. ~.ID I;. ~.-.-..~ a4 ~4 .. - ,.-rl!~'.:"'J /Y~ ~ H

r

~ ~ V7-Vl) - e - / ? ' ' ' " -~ J--- k {~-e4- ~_~

_ _

/

~.,l. ..

d'.

9~~:

~..T ~~

~

J. tJ

~ K~

~

...

eo<cy~4

~ ~A.~ ,;

4M.

~r

("....4/.;

r . u - ? ~ J,~6, N~ ~~ r~"f) ~-" 4.&~r/-~" /~,...,...CL ~~ (ey(~/~,"

8Jl

.4A-~"'---~/ (~2:1) ~I/il~~ - " - 41'&'I'J

Lr~% ~~?

.

~~j

~-- ~DC.L~/~.

~

~

f

.,..",a.-. o..(.c..

~1

_

oe-:

/

o.f..4.

~

.... «.

~

L--'

~

/??-~JrJ ~ ~~" - - - .

-e. .. ..

,~A...: AA

~/a~~/~(,YJ"""'E. h-c.~d ~

1'9

~~

-;P.k~ a.4.~~~7~/.A."

(~r";

z

~/2."

I.J)

~ a(.A.. AÀ-ca4!~.·c. ~~r~1 (I..) ~ ~....er~~

~,?/,~a..? ~r ~~ ~

.. --

e

IS

es ,,'

.

.lh

=

".~1' /r~ ~~

,,~~

~

...

,...k~.-..-~o<.<.,~~ ~ ~ /< ...-...-...,1'~--- ~ .J, ~,

1

l-x .D,S JII"~ ~~4

t:$~~.,u.~ ~-*'- ~ ~-.<-..

~cu.c.. ~~

~r

(e)

~A-..---..~

/

J.~'

J7"

.J

-P..

.J.

~ 0., _ ~D, J" ~ • Je

/lV1

~~~,e

(it)

~~

':J ~4f P'-:J '"

7ïö

(4

I~J

.8a4....

Q.I!.c.

~

~~J'

---

,I$"

~

~

_ _ _

~p

;

~~"

~

/Ya.-

~Qt.L~rfU.,.. ~~~

(1'''':1)

~ij.D5 (k.-J.t6J N~

..L

=

..J -

---

---\ l~ _

(_~

LC ' \ '..

.-1

_ _

/~-~=

_IJ,.

A

- - e

/?'Y~4 (~~ E)

Y

=

S,

/~ j.(~ a..t!-.~ ~~(~ /"'~ 73/ '7' :; _{6~ s6 /(~ ~a..L~/"-t4 l~}

_HJ

~~

a. ..

.Le.4'~..--(/~ ~

~

.:e

::

E

---.. ~ 7.3 --'- é. ~~ ~

J

-;

/J

.-

~~ ez..-G~...L~-4.

~~~

~

~~rOLc.

h' ...

~:::

Z>

~

~ -:z> ~a.A ~

J-r

,.

J

:

/ r

~

/

"-7::2

A-~ ~aL-e<.~j' ~

#tf

:

~

~

~

/r-

~o.A' ~ ~ cP

y

.

~

/.

~ ~c:0.-4-~

.J.

2.(

*~a':±:-/~

I'

A.TrT1

~

~~

~~ ~,.-...-e.~ ~/

(-9/

2:J.--cA

~

a

~ 0...4 tP 9 . ..;, - ~. :2

C

=

tPb

.

/~ k~ . .A"V~~

.A~~

__

o...

...aA' ~o..-,t' ~ ~ t.;LL~i" ~

~ ~c. .f~% ~~~~ / ~~

\ --z3> ~~

\

~

~

~

,-ya..L...

~a-tt'

--<A<.t_.. ...

~ ~r

__

Ç;

~~ ~

c9y

21'

"I

~

...,..,...~/..L

~

r~

~..../...-vvQAÛ..

Clt) C

=

<J -

.$.

~ ~

,C ~AÁ

ó',"

~1'

-

.J.

L

,

=

t?6.

D I fi~ /yv~/~

C}--J'

\

'

-

~

ê~aA ~J"r /f~ ~~4

~~--4/ ~~ ~~: é = ~= ~ ~~

~-A-

7'

~~~

"

...

.r7~~

~/~

~

~~

/Y>?">

~

oû~

0:.

A-

r C (=-

?>.J

~

k

~

a....4

J.

~

b xe,S":!,

~ ~

0

~ ,f~~/.L

cP

9. 4

~

~

C --L-.::2>

~

~

-GL.-"'"

~

s-7-

0. 0

~

:a-~

J-r

/('~ ~/f< - - -

-,

tJ-e..f:

~

J

~~

..1.

e

~ k~ ~

~/~

~..A./~

pU~/~ ~~:

J = P

A.-..

~ ,c~.4 ..1_ ~ ~ A~ ~..-!~.-./--L..

...-. Aö2,..o

~

-"" 4.4' C&'

A--&.

t:-«

cP

9'.

.y

.k

~

~~/-L.

.&:..~~

~~o-<.& ~~

_

~~~~-"7~

_

~~/

nn~~.

_

~a...~

~~~

~~

,."...~

~

~~_ ~ ~~/&.o<.<... ~~

-

...'<c7--L-<.c •

~~

Acr

'~~

...c.c..

.

~~~

~~

~CUc.-~~ ~a.-.. -~ 1'~

'-fo

/?'YAA4-~

~

---?~

h-J

---

~

~

(/,l) //.y

At!

/7''''"-.. y~ ~

..

~~~ ~...:.., ~~ ~ ~~ ~ ~..-. ---T~

-~~

~

yt!J

/r.J'

..Kr---

~

o.-~

-.9-<.

('cP

,4~

___

/

~~~~~

.R~/p-'%

~

..;

~

/2-~4--'

~3~%

a.~...ec.Ä.

-~IL ~~ ./ J ' t a . - ~...-..~ ~ee..-< lUA-1

~

~

~

~o..-L.~/--... ---~-~ree.

-~

~~

/o.x

cP9.

~

..r "cP '=-

/~

0 Ar

.Kr'"

-o

/ / 7

~

o.c"~.:I..Ä-/-./a...

~

";:;::?,.,..3

A~,IC~

~

~

; . / . ..-C- i

~

t:I He

~

9".

~

3

"-.-..e

~/é'.

~""~---...A

.

~

: ; / ( ' < • »)

~oA'-'-o t?O~ Je /IJOO -=~, 0 ~ , ;? .. Dp ~~y,D~C ~~r~/~

A-~ ~ ... -LtI'C~) o.c..

/----L

_.~~...d ~o,,f~

~~

~

~,I'

"'"'c.

~:

"c(::

E)

;

9

-/'

J ~ ~ ."c - e -

e

__

~~ ~ ~

&19

....

~ ~6 """

3"

s~-

A--..t'

~

-_~/"u..../L ~~~~~a..L~r~ <:: .... .rr~ .-4l"Q.-~ ~~ ~-.-' ~ ~~~O<c.~

/~~..J ~a- ~-~

~(

~

)

<'~%

~ ~~j"'~ ~~. ~ ~

"-'

---

---~~---·

.

b .

~ OCAI'" ~~ ... I . . . , - '"= J tI-;"

'.t~,a (>,IP .: .J?'"Y A~ ~ ..

~_-~ , #

---~ '2e. • • 44 _ _ _ _ _ _ -

f

__

~ -:z:, ,4,..-#',/ ~ .... c ~..4 __ ... .. ~.:: 19+<3.,. <; . -st-r.-.-.. ~I--~-tO-f---r--~ t -~ --- --~~~=--k----el-~

---,-

9

-

·

-

,.,1 ..

--'----

)-;-

--

1

A Jo _,~o j.s _ I~o~

;10.

09 , 0, 0!l

I

..

c9~ I ~~

___

I

______

,,

___ _

//9 ~ ..s S" I 4-G-~ 'r r lP'.

",

1

1

S 1,9 • .t K )(

'9.2,7

=-

/ 9 ' G ~~ -y"~.L ,~ w ~ vel I o.s.z~ / cft. IZ 0 I

+,

.z j .. }-~Q

;

1&'.1

.

.56,

'/h~

.1{

lIj'

~

b

t:J

,

.

I'

.2.,

o ~ ~ ': /o~. 3 c.. / j,I'- / 0 3.! 1: S-~,r De..

---~ _{- - -} -

----~---,

,.;L-

-:::1t>

~

"""""'-"'1

~~"'----..A ~o.ec.-

...".0..-

/~O~t:"-'"

/ h " c ~~ __ ~ ~ _ 1 / 1 > _ _ ~·c __ ,,~&~.

/3~1

~O-<-;;-oC.c...- ~.~

----~

..

At.- L,00c.

... .1. 0 ' -~I l"Io---l

---T

I-~/ A Ic..a - , ft

___

'

_

~

_

~

_ _ _ _

__:_

'

__

'a-=-~_-_+

i---

-

--

ïl--~--

-

~

-

....

__

I<coo<.

_

~--"-,-,,

_ _

~~

... _ ... _ {

~

_ _ _ _ _ _ _

-

I !

~~.uJ.../d.c

1

1-_'"

~O,. ~,j7 cvR~ d''''. 1 ~

n-

'(dl, 'f~- • 4.eec"'~~~'7 ..c... ~~ Y~.O~- . 11.

J

L-IeP

d'6,

I~

D,J

/

JL..%

l'Y~k o..f~

..

~;..,...Dc- cK.o...-...c..~ t:A,.""-' - . . . ~~j

M :!'

+"

0"'tHJ Ic eA-I/-L (_--~ ~ t:.\:.4. .J D )

#I - ,

~~~rf

___

. d

~

_~~ t..À. ~cz.4!""'~~

~o....e".-' <Ä.. ~,~ ~ ....--:... ~ ti. Dt.-I! .

- - - - ---1-- - - - -- ---+

!

- - -

----Î- ---

-

-!

fn.t.eIA-

f

'J.

/?~

~f

:

JL.-·0

, 4 /

:rl

.

/

DJ e",.. ~---. Ir!:

.7 (

t

3

I>

,

I I --- _ I

h~ /~~.

-

ijt

i

I

~

'I.

.3 / ~ I I j

9.

"1

Ojl ---~ -_.~--- - ... - _. - -J / ,zl..t ,.f/I~ é ~a..a/I

~~~r--~~~

J~. !l/~

AeA.Rá

,

6

.

6.3

b

.-f.-e-..I/-L ~

=

5.n-

~ 6,/)1 . l t l 3 ... .t!.3~ IIIS3!j ==: •• ~ ~ ,3 ~ .]~. ~/~ -:::

I

I

I

I

I

I 1

-~~

P.3...e.

e.k-..:...

I

"-~.

~

.--h

aLc-.-

~

«-e-/.

~-4~/~~"",-~ ~~/

_cc

~

';-""'f

'-4-. .:r

~ ~~

~

~

/'

b

~

7' 1

".,.,.,~.

~

A ,j. 14 t- ::

y

X , 11"0 ~ IJ. S ~ -= D ;' J

'C..

~ ~

_..c_,, ____

_

, ; 6 ~r

'

~/-

:. /trU - .-, / l .::

~d.l

oe

~

..A--o~r-.oe ~

.&A'.

('~

,.:-

J

.6 {,. d'g.

r -

/'1.P :: G7. 9 :

c;, t () ~ Mo I.~ __ _{I~/.Q.. ~'i {JI.} s ...

~~~

?-

.

Q'I

.

!

'J-

t

J

"IJ ~ cPcJI. I

~~r

. JO

_,

.! . ....A-"V~

nP

lP'!

.

.

l.}

l

/606. 9

/

J!/.

.

f;1

I

~.

'j

19 I

~_

~~~

.

1-tP

.

~

'.---

I

/

~2..

bI'"

~./~:. /~2. b7~

..

~~616 -6~./9;'= /?~./o3k""4

4

...-...-a.< ..

y __

7~

~

/;7'.2 . /t!)J

,LC4.I~

_ _

~

.;4.

a<4_.

~~~~ _~ /Yt:1c- 1lArfI.-..I-- t?~_

~

;::-

~

M' ....v'I!ra...u-

~-

0<C.t-

7'

~

~

,44

ti.> ê

.&..e.

~r

~

« - - -

--~

kA....-

é?';:'~-c.-_

'

~

~~ - - 0 - . - - ~- .,: ~ ~ ,..,...,,~. /tJ. .,.

b

J-1.

3.)

-

Y

/~.(.

S,9

- - -

---

..

-~.--.--.-.---

- ---

----

- - - 1

st c ~ I "1.L

q....

'"

<'401.1 tl

~

~/<S(.>. ~.

('

1 /(~ 10," ~r ~

---

aLc.- ".,."..~ ~ Á. ... ~ ~;..,-:

ye..

nP.t , V1:I

~ .~._---

----I

J~,

I

~~

..

~

--;

--~

---:...<...--,

~

,t..

---

r

--

"

-

.'~' ~

~

hr-....

.J.,,~

T..û

i

'f.,.

(;> 9'

3.

4/Y

2

~/. ~

0.

'1'

/

6

cP,

cP

.

__

~

_____

i_':"!

.

~

._-,-_

'1

_

,

_~_.j._-"--_

/

b_D

_O_~_t1_.

_3...:...9 ....

1_&.---_)_9_' __ _

r~·· - ~ .. ~~---... ~ : .... C. ... /~ ~/ l..

.A S

bS-"

ó'

----~

;;..,

4..c..«.

~

,,' :

_ _ _

_ _ _

_

~

~

..-..vt.

r/~?

. - - A - oGe.

~

~

- - -

-A---..«--'\ ....e-.. ~ ~~~ /y~ ~,c I-/~ '"

.--v~ ~~ _,~ --A4.. ~ ~~ ~ .: ~~~~~ ~~ a...-a-L ~4--z... ~ a û - . ~ .t: ~ H.

/

/

~

.

~

~.

_~~

~.J-0.-4 ___ ~A-. 7tP,7~

._

.. ~~ -~ ---~~/~ ~

---

~ ~ '-~ ~ cP I!) Oe ~. ?

/ 4 ./'-"'"

IOIt--L---.-J-Y~ _~,)....t:_eQ...O,~ ~ _.- --- ~---

~-~

A~~

-

~~~

-~

~?

_~

_

~

..

. r a -.J- D . / -'

.:J c:::: ---l) cf1v c ~ JI'-e.- _'-1-y~ ~~ f!I&-.&,~:

-j.,.~ J~- ,

r6

/

.Ke~

.

.

~C~~~

~ .15 ~ _-y~... ~ . / ' Y A - cP ~ 6 ~ ~ 3r oe.

~

---4-

~

.--v~ -A~A.4.r·'

Y~6 IC ~~~_ ~ ç

=

~q.6.c; /"tPocP ';

cP~.

6

'I'

r;

/é.

c~~

JL.-....

..y

( / ' 5

0

c.)

_

JA-.

~

~-

(óLo°c)

~~.

~

k Á D o - c w -

~

?S'"°C

~

...

of/'i'

~

a.C&

...-v~

~~

~-

"

~

.. .t.P.1·

c

~ ex-' ~~~_ ~ d20 or 2.U?~ ~

/otP,y

è

~N

~~

~

....

a..-

7roc:~

Jf"°c

~c::P-~.c.<~.

$c- "'/

A

~ ~.«~ L. . ~ ~~ ~ x. ~a,...---'c.

~~~ H ::

6o.x

'YtPJ'.cf? ':: !l~. ,tyt!'. kc~/~

,

I

I

.

~~I

~~

1 - )

--

I

j·~rf

l

~

r"

.

/Y?p..~7Z!:

,j~.516

1

~~ IJ. Jlf)

I

rl

<f.~

_

~

_ _ _

.

__

. ___

~l'.

II

_

~

_

~J

~

"

~

/0

6',1

~

~a.-

...

~

~

I..-.oi

,4."--

~.

::;

s6.t:.cP~

~....-:.- ~a..er-"--

/y~ ~.;

-'k~t:l.a..J9./

( ' /(J

óJ./-

/t:>~. ~)

x

r

6.5; cP " .3. ~

Y.l'

.kc~/.L C-~~

z:z:=

(~ ~1IcA

.

J6.

)

7~«~~

..,...,.,..-A-

~._~ -:B

.-tf.c.~QA.r

3 x

~oL~r-~

~K.A~r .-v .... ...4 ...-b-'fIh_

p~-~~,",,-::

/.t~.:s

..t:~'ïf

~

~

....e.--

o<cA...-a

zz:~-...;'

J

)t -',

~

AIr.

07

x

/~~.!J

:. cl' 4- . .

r/

t

,k~ r~tK

.

8~

~-h~

__

eA.

(~

~/~

/sroc

~ ~ ~~ ~ ~ ~~ fjr-/t!I~~) ~ .AVA1. ... 4~~ ~o<. ~ ~ -:: .!I~.tP ~ ~t!J.slcP _ /1. ~/t!J /~

~~: cI'~

.

.r/6

~

/1. 'SlO -

3.677

=

9

Y.

/~9

Á'~

~ ~ .c..-_~

__

x:

~ ..i'~.

/

<r,

.k

e--...4!'/..e

...,..~-~

a.a:-.

~

~~M./

~

~./YA-

/c:.o-r-.e...

- - - - -- - -- - -- - - --

-Jo.

_ .. - -~.==:----

-"-:::-~ _ _ _ ~__..:._..._eA."'""_. _~-fL2-/ ~ -~

~'7#J1-{~_ J/ ~./Y1Jc.- rl'~It9c ~ 3J-oc ~

at::t....-

___

~

_-

~

/"

~

f

r:-

y

R .IC

~~{.iC

~/09,IC

0,7=

/~

.

14-

9

~eoJ/~

~~

....

-7t/;:</f:

-

~~

<>'-c.

~;

A r - : > /~ oe /

.

~.A+-~

/J:"

,I:.

e

~

é~~

-)

..e..o

x

/~;(

~

.:=

~.

/ 0 S

A:c~

~

~

/~

.-:--eT

~

~".

~L;

~

~

~.c-. A.~~~ ~.

,e"---<'-"'l-<"&'

t!'

,;:;;;0

___

~ ~ ~

J..2.

ti. ,,~ ~-z...-.-f<-I:--'"""",~IG.C..~~ oLc. ~ ~ ol ~ ~.-... ~ ~

r.t

.,k eac-.C../~ ~

...

~

-A

~-...-4...

~.~ /"Y"'--. ~ ~~ ~

---lil' 732501 • 514 A4 . 1 x 1 mm

'-, I:) \..,." 1I,;'1à otoo

- -- .. X

OIO c~ .\.' t, ':: .:~

.:U.

-~~~~--~~

~c::7 - - --=::.. --~'. ~ --

-~~

a-a.

a....~c. .... .

-

_{---_.}

---

.. - . " . ---- - _. ---4. ... ''''~~I'''

i

~~.

I

S. /~

I

~2,. S

(/)~j

P

/601

.

.t

~. ~

~(.l

l

0.

J'S.!

I /,11).1 ! ~ oe.c. ~ ._~/ ~ ---:... ~ __

...,...4-.2..;t.

,z

~

/

t;.

1::

~f..J.9. ~ ~..J

..Aa.--~: ~~.-....c.~

b _

~ ~ ~ ____ ...c... __ A--__ - - - ~ ~~a..-..r

4 4 - ; : . .(" =.

r

J,

9

'I

~ol

--~ oe...~~

_...t....

~.:

.... H-t =

9.7°7

a.J

~

--#~~

/YP&- tKA-

~

~---'r

/

oû&-.. e>C....-

.-.2.x

~

1

J

17

t-.?.h.

-i

q??~

r

oK

6

=

/~

!

..t

/h'I

~ (j:t

)

.b~ ~)

,g~~

K~

(4./ -... .-.'.

--_

.. - " ;

-g-r~

.~

.

R .. .(

~..L

~.JJ(f,/s-

A-

/

~

~~c..l..y~

-::

";c

~/rlC~~."S

/cf ...

J~~5 ~J/

t..&

~ JLt~('./o3_

604...1/ /, '16 K 10 -

~ I't~/..!

/lr.1 -

a

--3---:Ç-UO- - .!l

/~

a~~

oL. y= 1),9

~~_

~--#~~

,-

~

~et-«c.

~~.,...c...-

/~

e<.L.

~

~~Q..4.

Q.,L:

g!::-

I()

bl.~)

(:T" ~ I

~ ~'~ , 3. 6cJ>5 ~

t/3~;,

~~4~ ~.s"

.

~

fjl1J.?

UH

JI.

/~.-te.

T - x

r/uc.vo

Áa-

~

y-Jt

/-/U,~

~_oL~~.

.

~~

~J~

/Y~

.A1Û

~

~~

~

~

.--?,

~tW.-::? ~/,ü ~

~

~

a~

~

~~

~~~~.

t2~

... "

~

~A~

/AY4,.

-

!'-<--

~.J

~Jf.::>o-L

tP,6~%

?J :::.

:z.

Á~~I

H ~A~ ~ ~.&./~~/ c.Lc. _ _ _ _ _ _ ~ ~:: 0 , 0 5

~

r i

A-

~

_E)

C!

~

~

_{'4Aq.-( -.LM. )} ~ ~ ...,...v .... _ .. ~ ~~:, _ _ _ ___ ~J' . - : - # ' C - .

_~

.4

~?-.

.,/W~ ~

L.-~ ~

I'

(-~

E) :.

/.P~ó'

A:.t9.D-L/~

~

I

t

/h-C,~I

;;

~,.

De

~

~

...-a... .. _-A

~...c..-/

_____

4>4..~? ~

-b-Á

-.

~~

--<A.~c..U'2.

d'S.

4'

/

(J

1<e4lA!4

-A.

~,r ~-"t:4 .. ~ " , - .r~7)K/?~tP =

~

~~

....--...0

a-:.,

,

~a.r:

IDI.2. 11, tP ~~.t"- ~ ~ >e.,{..~/.") ( 4 . -t. \, \. "'.:.,

:-

aQ.;_

...

~

....

..."...,L __

t."~

_ _

/-.4-.

Nc~

+

~

.'

...A-o..- 4IoCc.

---4.-:~.

"cc.

/ Y C -

~ ~

e

G

oP

':

~

.

!.~~

I' JcP)

g~

...-~a....r

~

c<--. ..

~

."..." • . -..., lIoGL

~_~

~i._

~

..

~~ ~

fY~(,r

.

:

/ C , f

r::

3.

~

/?">->.

$~

d.,. ~

.

~~

.

~/

_

9~a.Al-A ~.

t8~

et

./'1'--- -'&.. 0.<... -eJ.o.... ..

~

... A - -<..a

~

-l>-~ ltS' 73 2501 -514 A4 - 1

!s;>r

x1mm

i\ _{. !}

.1' .

. Û_{D •}

9.

4-05

K~~

=-

;r.,,;~ ~

/fWdX~ ~

~::

cP?O

~~

Pc.

=

rP9. I

Y

fl'~4 =

A;

G

3

-L8/c-,Hl

u

e ' = .1, /

~~

...

1

0'"

~ tIJ ~;( b.t, J = r~. S-"7

&/

~

..

' ~,

,

~

t*A'

.

-Ei

Q.Lo... ,An.

~

iA

Q.Á

,

~

--e-,6 ; ; .7

J~

0

~

A ... ·

~

~

~4

- - "

~ ~~

~..te-

a....&-.

? -... .

~~.4- ., :: //, r-Ç ~ (UA,'~ ~~ J , J - /

tJh-~~~

~

-<...

/~

...

~~

....

~

..

l'

NET

D

~

/

N E r 4' .::

J

u-.

~

--G.-r-

,-y~

e.C.4.

.

~

~-r

'

:

7.IC.J

~

~,

~

-=

~

-

~

--

~

"

7~~

.-

~r--~~~

-

~ ~-

-

.,,~

~ ~~ ~-c--- {~

._---~-:::::-::='

.-Y=~7- ~/~ ~U~~....,.-..-....

~A-~ ~~

~

--<---_

yt:S.3=

.

/IO~~

~

'J'

<'-<..<..~

A-~

~

1S3

~

(/j~/ A-~~ ;~"

~

/-.~

z:z:-

~4Z4

Jr.

d&

~~

.

'l---~a..- ~ ~7S

4 e

--c!7::

~r-o.-

_

~~

,uJ.

~

~

x.r-- -

~

~7--

'

$re , = 1 : ' _

..

/

I

~...

_'&AA

~~

.. I

~/

~--=-;

,Y.

4-J

A-~

~~.

,

aA1 ... ., .

.' J. ~'it

A---,-

~ ~~7- ....c.-..---? N::- O .. .z

~

,4-"

jJ,

t ."

~

/

"Y·

c

L -.-:..

/0

I

:rV~

~~~

~t:A-AI' _./~ ~

.K~

•

~/"1.~A..a..4' ~~

~

L

/

~

%

~

~~r..c..&

.

11-=

:l

:J

=

vv- _

I

:

~.J!. ~~

--..oo.c.-c.)

'

_ _

0<...

~

/ /

~

. /

.-,.ac.-/ocP.1Z~

/27

~

- ?

--L..

~~

...

~ ~~A.""p

(-/0"'- ., ~ ~~y) x ...-.-~ .A-- A.-...~ ~ c ' ; / ~ 3 .IC S6l: rP ... /~ JJ"~k~

~

~.:

.4

~~.--y:>

___ h

r~--

_.c...J'

---~---

--

-- -- ---

---

-

- -

- - - -

-MoL. , ....

!

kS

'-lt....

I ; ~...uU~I..c..

~'09

i

~

.y-:~

hl {. 1 ('1'"0

-

~~

-

--t- -- -- - -- , -- .. - - - -J, ~~ 9.~') - -_._--_._'.-1.1 3. oS ,t

c~J

'

L-.

~~

.-

~"-/

/fl-,

9

= = ~ 0 f~ OD_r't D

L

~~

....coc.c.

~..:

' / /'1'4-- - . . "

~.>=::

9-1 := /1.

?

_

~

~;-zr6/.J~M,,--, ~

~~~~

A~-.L

--~~~.

~~~~~9

0:~)

/~oJ

~~--;N~::

:8'"

~

~

~

....-<-c-

~~

~

""'- cK&

~

--... 3"0,&

0

=

/-_~ -..A. ~,...c:&..L;.s t' ..

tP#

('

NP/ ?r~~~

-'.,66

__

~

~

JI:,c . .

~

. . "

~

IJk..

~

Q..A.s../u&/~ ~~

-.-ÁI'

~IJU!.# ~4

tJt.R _

_.4t.

~~---

_---'

~ ~

r

~

a.

~

-, \ \

~a~

••• I

A'Hk

~

\I

~

f .t

f

rra..WL

r

~

t

--UIIHAl

6t!1tP

:t

~'d

_e4..

__

·c.A J

V~

~u.d.~.

~,Pfi~

C~.J

Ja ( 1 ' 3 " ) ~ "7). 1{.

-p

..J

'-I !I

9

I

.s

.f

.ILo.

-P

o

ó'

1'1

.> tP /!/Lo / ' J I

/7.1

'1

If~6 / f

Y$

t

7). 'R.

-p

1-60 J 10

1

cP

7). 1l -p

_5g

r.J

_fó'

~.~

l..t~ 5tPf

f

E

."F

6Jt

$6~/bJ 10

Il."?

Ltt.J3 SL ~

/9

~ ~

"

Co.

III'f

.f1~1'

I I.{

_/9

~~

_{t I '}

~s-; 13

/It

2

.7

o

.

S

l?ej:Jo,..t

11~ /650

15

~

ca-

~

A-.. «. .5

6

I 4- (' / , J' +,)

/t

./'J'

a-

d-1 ../Z<-P~ J

9

J-'r

./~~

~

~&...;....

?J~~~~

~~

1«4.d-/tl

/~

~~

~

.

..-e-"

.

eA'~~

(/ , r o )

~

~

~.~~

-~'ea...e

-

/a4'~?

"-

~

""'-

-',---te

L/

~~4L-

-

Lr-~

~

~~--

306-9é:'cP

OtfEt)

~r

6é

r

~

~ --r=~e~;.r

/?'-h

-,

'.