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). TKeuze V2~ ret te vol;;er, prCJc83.

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uit c,i.lci,lJ.':we.r1,i'2 }:C')'ll:. tierl~ tev9Es C\(OI:)2

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tierover besc>,i '. ke!'·'. er:: fleeft mem te"ens, liefs oinne> lie,

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eigen

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methoden 1-,pslo" el;;'~;'70re:t;.

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in e~n flui..c1 ~ .. ~;\,~ ''-'J.n ~lr:'-'-t. 7.1;~·.i':' (7.i{~

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inziens ,'e \'/.>Z.8 " ';o't!.''';' rclL/:>:~S ,J i.c, pat.e'rt de ,;erl:!iste l'e'lctir::Hvarrr,te \vor(~t \}er"].re ... .'er1•

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EC1, dat verorJtrt?;'~'i,Gt i'~ 'I!('!L ~,lf;)i~:e ~:":.,,,-"cl;'e·"E:Y' .:.;e,;~:lore:::r,le k.w.,

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(9)

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l~Y':(hctip é"11": ir- er f'~q)or'l, ::Ü'T i!~ l.e'-l'l',nd :',eo

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). zijn (29):

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319 ooe

000 l

b

.

=

14~

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ton.

1958 :

291)

eoo

0::0

lb

.

=

133 0('0

ton.

1

8 helft

1959 : 179

000 OCO

l t. =

21

000

ten.

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tUSS81 ~eJ11

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De ,temper,c,.tuu:ç ir het bed i

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.

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tlJs ' e 1 e 50 er. Î;O r~e:'L.

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vr rmpn

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2el:clC>El.

I' -0

--,-i:~rir! :'r-'rr'e:. "(~' e~-.lOC'!.:~1Jllt· ,~1i.c>~y~~?!~ {~8S«.e' ,.2 V~'!,~' f2e "!~C~3t. ii(lr_~'f:!zien

(3J~ l-:o-'-l-:.ptu-te:'~7lÎ.·c:e r'~i_'(~ 1 li~ .. :~?~~ z')"j ,lA t_ne\.rC~8}~_e'~8r:. t?'~icl~lo re-L·}'~{~\;-:'

,?,. !ctr~'.c'-"lr'( ret",G ", in L8t ket'üp:l'oduct en _~€. l~oevsL.',:>c'n cLloor-lm Gil<:1,ie,?ner. in ~"J;,~ des :oil':',--l rl"<;enoe,s t" ',""j";':1,:--rlo28:::'..

JiC~':lor<j'e-;~-_lec;'r er~. -tyli(~l~oc~'''otl_') r ~:.r01.",ler s·~P1~nL:{~~·F:";'T.

Tahel

4

voedir:g, rlestiLtd A ketelpro(h~ct

pol r mol ~ , mol

>

---

----

--

----

---

----

-, ..-- cis-dic'lo(~ret~:eenl'l

7

₇

C'4

, • h . . . 1 - ' \ I ',r:~'f"J. oo.::'e v.",ce"'n ) tel3.c~:J.oore Lteen

175

pe.~3.c~:J.oorettGen 295 217 !~

All'

',o:;v~

',E'.e 'en

~~pY'

l:.ur.

( 3e':0Iom. '

94 ,

3

7~()0 ~.I/

2 ,

!

174

3,0 100,0 7873

97 ,

8

5 1,

6

2,2 1

0 ,

3

295 97,1 1CC

,

e

30~ 100,0

In ~e?;e kolo::l wOl'cl:.

te:

r'lchl,''l'et:_eer, v';,n tricl'.loorethoen.

voe"i_in. : mol destiLl~<,t nol .~ l:etelproduct ,:'.01 "',

-

--

---

-

--

---

--

---

-

--

---

-

---

-

--

---

--

-

--

-

--" tric!r~ooret~le:_m 76~:\O

97 ,

e

7610

99 ,

8

89

34 ,

6

te"tr3.clclo"ret', èey

17

4

<,r::.

15

0,2 159

65 ,

4 7873

100,0 7625 100,0

242

100,0 Alle l:ocv€"'l: .w'-'-:ni l='8" 1l\) ('.

::Je) mas:;?,b!üansen z~): opc}::m(,P.l8' ir' bet blo~ schenu, z~j z',:n ~,:n\';e.~:evon

ir. inkt.

8. 'i1armtbaJ,2..."J.sen.

De enth2~lpieer.!. '\'":111 3.1-: e vC\I~;r}r(lf,le!l -e stC'l n=-~n

3.3Il nul. '

Je '-socr-t(.:l.~J)· v.r::;.rJrt i_oer v:::.x'; (18 ve:c3c:-lill '~l~:l~~ vloe.}.stofre' trer(~.e·-' [.:.f~·elezen

U ;

t

drJ h::()'e\TOo~i1e (',...,·fl" ,,~ .. 'li + 1 1"'~ (p)

- I _' ... IC.> Ju... ~~ _ _ '. __ :-:._-~ L.-_~ v ... \.~. ... .

;)e ver(1.J.T~pir:c:~~·'.lrmter.. st,~oJ'1. ve":::olc1. in -[::LoeI 1.

De so::'rt.el:;'e ',:::.'_rI'lter: V'3Xc de ci .. :u!J.pen '3: l:'UJ:' ~er!J.p ;rJ.Luuran:c!l1l:clijl~heid

1 1 -" 1 ' , t " 1 . , , 1" ('0) ( . ,~

',Ier~.en 7,9.ol ,x:'re'c.:'l' T')e !J':;"m p V''.L l;9,,-;";'Jc .. ms Ul-', (lP 1', /" Zl8 ,xpeYl

-d. . ';x I ) • -il1_ ' . . . . de"e """rl~'~r,f"'r"'+p", i,~ . . . L. Vt::::: ... __ ,,~ v ....

J. _

,

"0'01 W _,,--,-s .... _ ... rn .. O" ~--.; .... '. ",Y"'_.~ ;~-Pl' ~OI,:lC"" - ' . , _, ' _'-.-'_, -,"C'1",,'a:",r__ _ 1 OC'~(],... _ . ~e:"c-L(\r •

De 'l;J.teri ;".lbJ.l,j,r:;~, 'lP,) ,",.' l:-,:)a,,;'or i':) vr:;.':'iL'l,~, ir: t~:)..:cl 2.

"Tr00-~" de be'::'''~:-:e]1in~': ·"T:l.Y~ (::':3 \\'·Ll'rr ;~;~."'-.1~r18 1.~,.T I"'

-t

I_"_"_::'~I::: . L\-t>?2."'i' 11)~J ~l..y::~: :::;-l·e2:

v 'r::'(';r,voudi~~'(~: 8500 ,'lol tet",~c:,l ., r)cl "r, '.Jor" 0::<,': ':' L i:r.. 7968 ]'101

t""i0,"lron

'''e+ '''',-" + 'x',r:; nel "'''n~-, l;:'nr':ut.l.~i,: '!l, + ,2842 7101 :~l.

.L,

~

... - --

.. --

....

--. _..

( - J - " " " ,t-",. . . "

.,hTot·:, ',1 Qer.:o .. ~itj~t;-e 110':-1.r(]C'l11':ei -, y[ .:r!~t(2 o ·~ ().e t,.? !,~-,?_<}j::'(')!.~' t·~· i:l·~-'.:~~_lr:<-,retll:_\~ ~n

op re':lc;ti,::GOl'diti,~~~ te ln'·:~." r: •

.,.., , ~'n~O

a. penor' i C"O.e '\7~', rJ11'~',e on '.',Pl'l C(,i.' '_~ ':8 'u(_~,,~ '" -~c~:.l C"Te _:"~~Y'. "J.rl .::~) or te War111en

~ •. c ' , ' 0 c;o' Z~,:Y' n'" r"'.nt,= 146 • c

~ij

25~

=

188,5 joule/',cl. p bij1!l6~

=

242,0 joul9/l'lol. 0 '). LV' '1 - (,)ef'''', 'l' j Î IV. 1 \l, _J-, J\ \;.(~.J ....

='tOdiCd,è L08'-welhei,]

w'.}~r:te

is 6560 • 213,1 (1/6-25)

=

221.106 joule/unr.

È.!.. Eenor'~G(le \7'1.r~;te om de vlo,,,'bJ.r'é' tetr,:',c~.loTe:~~'i":r,~ tE-? vc:rd.mpen.

De

ver(k1!"pi:r'Csw~~1~nt8

=

38,6.10) joule/mol.

~

I'

Benodi::::de ho""veühei' . "trr;l:-(~ i:, : 8)60 • 38,6.10)

=

330.10° joule/uur.

h

139no~i~(lc 1.r·'.rrrb(~ on '~.e ;.~t.rac},1(i(1ret'_\·~:~1·1,;~~p 0l) t~ ~.',;-L:rrlcn V:l.:r:

146

0

tot 'le re;:tcticj"u" ,~)pr":,h~'lr == !l:,;Oo

10 28 re 01 10-

3

(1'1 ~,.. 1/' 1/

al

l

1 " - / , r T 1 C

=

"

+ ),',.1 • L - )0, ':J. " C'

m

o

.=

WIG.!.. p 7 1'""1') r' 3~ ~:

=

10,?S(T,-T 1) + 59,91 .10-):0,5(T;-T~) - 36,16.10-°.0,33 (T2-T~) d],= 10,2.103 c:Ü/PlO::'

=

42 ,

~,

.

10)jo'..lle/'ol.

~

,..

~opr,o('l.i.::;de ~~08,;é- J, c'ül '."I='.rrr.Le is: [;,,60 • 42,5.10)

=

364.10° joule/'Iol.

Tot'>,:'l b'?!'0: i.,~""e l:r',-v(:.' 1~,'·iJ 1r,·,o;"l:té' O:,!~:~ "):'<.è ~ :!"2.' ()~:. )<'!~,c-:;i,';016::.ti,~s

'SO :-,r2Y:-;An : (:l + l> + c) == ~21.10u + 364.10'.) + 330.10;) = 915.10 joule/uur.

(15)

--I

(16)

\.J'

---~ '7arnt.eir>l:;.oud VOJ:'l de ui tst.romel'fe ë,·:",,,':~en.

'I'richl( (re i.heen.

lh. "!;:;rrd'e die 'Ir:,} ('!l1t" :':,: afkc·(?leJ

"'-'6

4600 ~,l';, lIEd, },('C}·l)lJ.YJt

=

87°.

c =

7 ,

46

+1~,,66.10-)T - 21,55.1C- T'- c3.1/rnoh = (r/dT

p

3

0 _')

?)"3

..:l~: _

7

A('(';' ' ; ' , ')') 8" 10- (" - rn' .. ) () 1" 10-u / ',\ T)

\ j . . - , q o-?: '1' + '-;-, '). ~ 2 - L 1 -./ ,

c

.

\

l '2 -. l'

dr

=

8,90.10) c::l/!llol

=

37 ,2.10)

joule/mol~

r:.

'::'ot",le '.73.rI1tn. die ,rrijl<omt

=

79'58 • 37,2.10'"

=

29G.10o jo"le/uur.

-7-h :3.r8t~ d~_e 6r~~~-·cFlt l)~~ l'~e> a=koc~l -:;:: ~'.:-ar l:'G tilloei èt1re -Lriclilooret:J.een

van 81 tot 25 •

c

bU

250

= 126,4 joule/mol.

/

P o c,., ce"id ~;ü)'

=

129,2 joule/mol.

C l'ij

87 =

133,2 joule/r~ol. 1-' /'

Tgt8.le \','é,rY'lte (li'? vrijLo,·:t

=

7<;,62

,

129,2 (87-25)

=

6,1.10° joule/uur.

'hrmteintoucl

V~1J1

de td,rL-\T'lp = (a + b + c) = 296.10

5

+ 250.10

6

+ 64.10

6

= 610.10

6 joul~/uur'

.

Pen:tachloor~)U tad~'~on. .. /' 0 ,

'3.. ~~r::trm·l,e ,h.e vrlJl:oL1t3b~; :1.f)w~"],eL v;.ill?4üC 0Ct l-'ockpunt

=

2040•

c

=

8,74 + 93,30.10- T - 59,?0."1O-0

7 '

c~l/rlol

=

rr/dCC

.

1

E

8 7 AC 'Tl ,..., \ 4/'''5 10-

3

(",2 ,.,,?) 19 13 10-

6

(",3 T3) ( 1,

=

"

'-f ! ' ) - .L 1) + '.::; , 0 . , J. ' ) - 1. 1 - , . .L 2 - 1

~r = 11

,

4 ~

1~3 G:l/r~o~

=

,H

,

6 .

1~3

joulp/-1o,.

6

.Lot?le \':~r 'v' dl? vr:,)"':'r:lt

=

2~':,: •

47,6

.10

= 14.10 jOLü::/l·ur. h "hrntc die "rij' OT:1't b:~ he-L cond'.'";1.2erelf.

De COYJr.ler..satieW5tr'ntfO! belcl.'.=;t -4:::,5.10)jo~e/uur •

.-To+a·le u "7"'r1'11Ie • ,.. ., - r'io . -~ v'i;1'o1'l: , 1J' '.. . = "-.-' ~cc:: ~. 4') " .... c:; • 10 = 1":>: 10..) • b J'oule/'''ol , •• c •

c

₌

P èr~

=

oT

₌

3. Reactiev7~:.rmten. I ., 1 - , ' ' ' ' / , ) P""" __ . L . I ,r:"1 --, "_~A_,~ "uV'"'"" ~v., .. ' l _ 'f-,..r':: J. C "·"~· ~.~.J! = (!._ L 1 + (' _ + \_ G -_ 1 , 1r~ 1~ 10'~ 1") 1Cv 39 '1CJ , .. 1 / LJ .• ,~' + ) . + '-. " = -. I Jo1lJ..e/ UI!r. 6 610.1(0 ~ ~ ~ + 3;..10~' + 115.10;) = 7ó'1.10'· joule/uur.

a. De re?" ,tie tetJ:3.c~:l; (r,,=, t,·':\.,x + f::, : 'l,)

==

tl'ichloC're'L:~:;, + l,Cl

b. De rC:-.ctie2 te':~r'>"chlooret::'L~.:, ;- b',{~ b) ==11 :::34-p'è'n L.Gl~oorhl),tJ.dieen

A

}~

=

Ij.

~

*-

+ A)\.. T + 1/2. L\

~

.

T" + 1. .' ó C. T3

+

3

IiC:l.

" . (.-). ~ ';' F'S::

An

~~

r

,

-3

voor rA'~C Gle

r:""

!:::

J;i.

= +J,~u ~ " - J),41. ~v

-3

'

voor react~e \ ,-,): Ij. A

=

+8, -:t ~ , = -24,[;/1. JO ,

1\ C

=

8"1 10- 6 x)

u ' + , 'J . (". x)

bC

=+13,12.10-";.

x) .~ erek -nd uL~, (; r~ soc"'. I~L,~:'e ",r,t.,",~.1 L '':1'.

-- ',·c"-'.--- "_._--.. --.-... "... " ' , , '

bij

"25

0 is

IJ.

E( 2,)

=

13,.Q. "10; c",l/ol

~ ~(,1')) = 1') ,:, 1

n)

c l l "c,1 . •. _, '-' . ... 1 ' -b():.>:,)J,~!.,;~·~d 1. 1.. i ~ r;., l..l.i -! 1 it.. ( 1 ) ,

::-

A

T'*

+

3,':<[

•

?9C - 6,70 •

8:'

...

?

,C7

•

26 ,5

1316

3

~: ?l /rw 1. 1316~ + 3,88 .• 733 - 6,70 • 573 + ?,87 • 39~ =

13,5.103

c~ll/rllol

=

56,6.10

3

joul8/mol.

(17)

(18)

\.J -8 -1?600 =

.

2,Q ./ +

4 ,

37

•

26 ,

5

TIK

=

111':13 "Dij 4600:

r ""'

111'"":) + C,'"":2 •

₇₃₃

- 12,'12 •

537 39L1

=

1-:2,';).19) cal/mol

=

51',0.10) joule/mol. ,- _I' Lo:i~:450.10J +

1

5 .

10°

=

465.10u jOl.Üe/uur.

De

17a1~!nte

di,,, totJ. 1 per lmr moe

~

WC:r'rèn ='. 1'8

"012 .... '.'1.

"

nG

p

':

~

':.st:

915.106 + t1.6S.10Ó

=

138C. îO':) je'v,le/uuy_,_.

,- ,- ,.

'TolgeYls de t (;0':8 r,':Ou' : 764.10'0 + 1\77.10')

=

1241.10u joule/voue.

Eet

versc~êil

"'e ::.

5;f

vol'::;"!l'J i>';

.?,~,o~J (~

'in,;

~·e\'OrC:.FT

bc: "]".J.._. is;

,-

,.

(; 0

13[0.10 - 1: /11.1C

.

iOO~

=

10"~

132.0.1(J

~ t',TEtr:-1tea:.:3"ifr:be ).r:.x~ c"Lc.:' ov~~e. i.rl:";.

01: bl1..i·'(:)rc:~'-~(=~'·".rl·'Jc II-f; ,~.t~ Y':-:-?.G-::O--' i cn~}::·.,'::.;

;)c., tel::p~v"Y:'Ll'!" v ' de l-".Li·~e(! ·Cl.'·~ s",~:,

c':

e: cp

2

7 a

'

.

r '1'7

'~1-De tel'lpe·,o;:d~1.::' r \"Ul cL 'Lu' t ·',h'.e·" s: 81' .']1 Y.'<: o~; 15 •

'!Ol e;erls (2) pa~~ 471t ü; c'e or'er'en W~tr"I'i:;emTe (~r::w::~tscoef:':ïcien t v~m

e8n vertic:~,," f-'; pl q:":.t '.: ':'x: ('~"~ ~'I!'~ ;:~è\·iy--:.. __ ; :

h..,

=

5,68 • 0,'27

(9/5

d T)1/11 JIJ?

°

c

8'3C.

1 I",

- 1

,

S3

(9/5.2i$0) / ,,+ = 7,î2 .I/ra or; sec.

7,12 • 260

=

1850 sec.

Cant ~~_,,-, of dt:3 r}llitpr.\7-i,}'d t'_~111)8~,,··:t'.1.p.r ,~ .. :or:~\~. i:-,; r}:;~ ::lJ~t. "'"{ij (~r;ten ,'..-,,:_X1

r:1.at (~ 1.Tê.l..r;ntol':T·,·--",:~·1::·;J'lll. iJl 1;,;, rc~'.::.,·:7·0].·"i·,.Ln(-~ ";.11 F~~"~~2J. 8e~!l:j_l-t il~ .. -~~ VlJ.LJ.r

-vaste st;:;c:n.:X

V'

.

:~l1

.

r-r::ste

st,::",,:",' = 1J/"l sen

oe

.

Cl <= 0,1m

1 850 _.

1/0,1 •

!~

T :

'\ T

=:

1

856

'.'hlit8r1\f ;0(1'

=

4GO

-

18:-.

=

275

0•

,.

'i'r~tale W3.l'!'1t'2S !',rOOTIl pe.c U'.U'

=

1S50 .

?

7 •

:,6C

1

o

=

180 •

1

0

0 joule/uur.

Tot" -ü Y100 t (J_e , ~.>e~1.c';_C-·· ~·.~F:'!'··

, 132C.1C' ~ o :: + EO.10 = 15I

SO

.

10'.)

~ ':l-r,::;,::>.,':tor. ,.

'Je;3A moei; 15GO.10-'jo"üe/,rr' 'J'.

Je~.o VtJ..rrît:; rl01"~1_t ,:-~(:::l~\r~~r(J. d_ol;Y' 1.Ll ",,-'Ç.."lr.+.l P • . 1 __ '. + .,-, t · , . - ;" r. Ö ".. .. ~ ,'J -_ . . • - '2 ';8 re:3.C ,l~~ï_·(~~!lpG:~~~""SllllJ.-' = r)_,I...' Cp

E?

=

6 ,

62

+

O

,

B

1.

10 -

3~

C

,.

-3~ c _p l~_.::= 8,~8 + 0,5~.10 ~ C

FC1=

6,70 +

0 ,

84 .

10 -

3T

p :Cl

-

' ) - '-"'''1'1 '" 0'" ,:' 'v +

e

i,

1. 1 c:11 •

1h.. ;'.'3.rY1tc rlie r.oGi.:.; i s 0

'1

r]p t(~ rel,,r.::,'8:',"J' st.orfc. op '.-2 ',7_c',p!I'?TI tot de

re,tcti(Jt.!)11P8)."~"tl.J.1'P = 63Co_•

~\0

Lew

~u... ~0<

,~v.,

Î

(19)

/

(20)

TT cf' " --? dE

₌

3 ') ')

~ :') (~ ~) + C'

41 10-

(T~_~L) 0 ,.)-._ '-?--~1' , . ~ '"? 1 4,3.103 c"tl/rnol

=

18,4.10) joule/r:lOl. 7 ') 'J "_v1 _:?. _' dIl

₌

ar

₌

8,~8 (~?_T~) + 0,?8.10-~ (T;_T~) 5,?10) c:ü/':ol

=

21,7.10

3

joule/mol. b. Joac t,i ~'é'"rr.1 +e. De f0actie'l,Y'r'lte 1)ij

')5

0 =

'~1,1

.

103

:.>\,1/.10l. Ij, Hc= L\ H* +

11

A. T b. A

=

-0

,

75

+ 1/':. Ll"R.'I" ') A "8

=

+0,00016 Dij 25°:-21100

=

BU900 oK

t..

l'

=

.a

l:?\: -

0 ,

75 . :298

+

0 ,

oceoe.

89

-2067~ -0,75.90C + 0,00008.810

A

1/'

=

-20~7::;

-- - ?,-1 , . 0" 10 C"1/"101 -~ J --7 = -91

,

e

.

iC

J joule/mol. ;.~ r?f=~j IJe(~_r'!,,: V·-11'l:

\"'"n de tni:'~l e r,"" c; t,i.'Ö"-i'-U' 'ip k,',f'1~_

91,0.10J -

(18

,

4 .

10

3

+

?1

,

7 .

10 3)

=

sn .,; .... , G / . 10

3

J'ou1e ~ ---j .. 1"'0 1 , ... 'c'

F~1"

_., bC'flC"'i J ~ . . . . _1-,l·--i-v:r" -_·~ ~..I.--u

'13,1' de,) trj .. -r('''ctor. ,

"e to": "I" l.'P~o \ 1" '11;.> "I"'" t", ",,"" 11' ." l' .". ("_"0'" 'I r.L~ - re:' . ct,o" ~ Q 1

c:;t;e,

1 C"IJ J' OU" ejl]' 11""

....J ;"'''_\.0 ç LI .•. l ___ .... _" \ " . . . . _ .1.1 ____ . _ '. _ '.,-.) ,Ir ...I...l . . . _ j !..J.. ...

.L

.

In d", '::-:l-r'_'.ctol' :"or;·I., ;:'1_:; c'n"-,::'t, '::1 P'~l' 1.,--'~~ 1560.100/5C,9.10 = 30600 mol/uur.

stellerl _{':Ii~ ~'-0t}_{'r'lY',,,t,,,"v,?-('lic:s} _v-'x, _d,-' _--:;l_-_{Y'~·".c-::O"I·} 'I,-'Y' cl,? c'-':.::,'rin.-~· op

t

Ct,'~,,;"; [t", ' ,'

15'~1.q~ moet PR" '..,11 p on ::"c: t,,--nlO('/C5 • 3C6CC ... 36(1CO mol/uur. :. .-' ...

3 ,

2

kg/sec.

1 e twarm e''Vl.Sé.'e , 1 ".~'.r. ('" '. --, " '. IJ

Dit is eer~ ,r:?,-.~ror~l;?T.· "{~-'_'-:.!_"'i~· rl·? l~~~tJ'3 ~:~':-;,s'C:~"'r, ·L\f1(0T18...!-i,:~ .. Ul-C cle re-·-Lc-~:.cr,

wor,leY! afE::9l":cr:Ü(1 tot 0" hun rl ',1..l,WPllY1t =

,5

,1°

.

_'Joc','':1e l:.i'::-r onder vol zende

l~er8~\eni1~~\~Yl vifof'l-lJrJ. elF; zel.f(le ,'·1ri-::·~rlvo'l"!.1~.i'J\"-~e stofst,rouell Sët1l'llikt ~L13

bij d~ ber0'kel1i:r':_}:,y, _{V1X: (i8 f'0.lC'+,or.}

,-.1.:.."'ar'n-l.einüoud v ']' di" i~""-!-::'rC":-,':'n'.!'2 ,;.s:'-'e:;n

=

760.10'J joule/nnI'.

'2. ~})-,3.rrr~te di(~ 1.','or·rJ~. ~-l~{"é}?qt-'!.tJ·-' irl. (:(-, l:oeler': T

=

I1f~OO '"Tl _ 6~o

2 ,~ , -1 - '--i

... ~ ... ~--,-,_._--_._._-

.-/

103 .

1C?

jou18/unr.

~ot:!.le ~1oevfé~'-'.l~_?ll \~'.-~"!'.·r:I~,c-.: di(~ ir~ d':3 l':e,::;lPY' JflO,pt r.ror:f?\ ;-~.f-S·(~ :"t.:'\ _y::

~" 0

6

é; ,~ I

::1'.1

+ ~0.10 + 103.10~

=

435.1C

·'

jmüf'/l'.l"é'.

l.t.,. -,'armteinhoud va,n de uitstrooeE' c g?sser

=

764 .1

06 -

435 .1

06

=

329 .1

06

j /uur.

~ KoeLnter.

In[':'1.TIC'stp;(lpeT',h1'lr ::- 15~

,

uit~':~l}':;TI-olnper'l,t-llr

=

50

0 •

(21)

(22)

',---,J

-10-e

1 kol.Q.m~

In deze kolom worclt l,et HGl van

de ruwe tric1_'1loorethe_'_n

den. De mat~ri ,",'11 biü?J1s van deze

kolorJ sta'lt vermeld in tabel 3.

, De voedin'" best'l'lt uit verzadigde , _o _----_- _._,

damp van 64 • De d9~p, komende van

ere

bovenste schotel heeft de samen-stelling: 8848 mol hGl en 7700 mol

tr; c:'llooretheen + 70 mo] dichloor

-etherm (tesamen 7770 mol -Lrichloor

-etheen) • Deze damp wordt naar een

condensor geleid w3Jtrin 7680 mol trichloC'rethe'?n wor't geconden-seerd en afgekoeld tot 200• 8848

irol lICl + 70 mol dichloc\retheen +

20 mol i ricl!loorei::'?(:m (tes",D2r'

90 Dol trichlooret~~'n) bltven

'7asvo" "ip" cn vlorder'. e' 'e:r:ee! ~'3'lf

-- '--' 0

,o:e1'oel,:1 tot 20 .::et ketelproduct, besta<>nde uit 7682 mol tr:-;lü oor-etheen + 22 rJol dichlo()rethe,~r

(= 1104 mol trichlooret\e'n),168 mol

tetrachloc'retheen er 295 mol

penta-chlonrbut,rJ.ieen , wordt met behulp

Vqn cor.denserende stoom-opkook-o ,-

-'-" temperatullr

(90 )

gehouder. Ir: de

fi:>;1Ï'::tr hiermL"st sta"<n de

voorko-mende stof-en warmtestroDel" •

6 h

",'armtwinhoud van de v0?(li)~s- 329.10 joule/uur.

~Warmteinhoucl van '~etgeen de kolom aan de onderzijde verlaat.

T'richl ooretheen • c bij 25 0

=

126,4 joule/mol. c m'd" l ' - 129 ? J'oule/mol p o . / 1 c ,:;;e ... l , , e Q - , - • c b" 90

=

132,0 Joule mo. P '. 6

-rgtale hoeveelheid warmte

=

7704.129,2 (90-25)

=

64,7.10 joule/uur.

Tetrachlo retheen.

c bii 250 = 146,2

.joulE~tol.

'd' ld 151 2 p b" 900 ₁₅₆_{2 .} ₁ _/' ₁ _c _{gerfll ae} ₌ _,

c

D

=

,

JOU e DO . P

Tgtale hoe-'e lhe',' ,,'hwmte

=

168 • 151,2 (90-25)

=

fentachloorlvtqdie-n.

joule/mol.

1,7.106joul8/uur.

c bij

25

0

=

196 joule/mol. cP bij 900

=

225 .jollle/nol.

',L'gtale hoeveelhei,-; IT:1.rmte.

=

c r;e i ,~lr' = 211 joule/mol.

2§5 . ?11 • )90-25) = 4,1.106 joule/uur.

Totale warr1i8in' ,ou - V'l.;"1 ;'}r;t,,,,e8n de "olon aBT, de orferz~Ve vec.-l::v ,t

=

6 6 6 6

64,7.10 + 1,7.10 + 4,1 .10

=

70,5 .10 joule/nur.

-L..'.'larmteinhoud var; )le" c~e,,";~ de kolo''} :l.1.n d bovenzijde verlaat.

-J

c = 6,70 + 0,84.10-T ? ~

d~

= 6,70(T _'1' ) + 0,42('32-1'j)

dIL

=

264calfmol

=

1,1.10 Joule/T'lol. 3 6 ' ,,_

Tot'üe ',varmf:einhoud van het ECl =,8848 . 1,1.10

= 9

,7.10 joule/uur .. "--- '

"I'richlooretheen

k,'.larmte die vrij zou kO!~en bij cond

3

nseren. Condensatiewarmte rJi.i 6

₃

0

=

33,0. ~O joule/mol. Totaal:/7770 '. 33,0.10

=

?55.10 joule/T'lol.

I~

,

~I

-,

T~

'.,

0 -::f /

6 b /

a

~

6

ei (', ,

b.' farmte di:~ '/rii zou kon n

-;;- bi,i

25~

=

126;4 jonle/rnol

cP bii 63

=

130,6 joule/mol

Tgtale hoeveelheid W3.Tnte =

cp Gemir' drüd

=

128,5 joule/mol.

( . 6 .

7770 • 12G,5 6 -25)

=

39.10 ,Jo·üe/mol.

6' C té

r, de tridacop = 255.10' + ~8.10o

=

294.1° jonlc, mol.

De tOt,Ol!'" :1c:e:e:,:,':ëeid '7:=tr:'!te r:.ie "e k,-,lC.'JTI aT' de bovenzijde verla

-t

is

(23)

-11 -.,-..-" r • 1 I , 10-1, -:'-" J 0\1_;: "/ r:IO..:. •

:::

-

/:

,

7 .

10-

joulr', 'U:1~~. ~ l·.:r;.Jr·q-'··Q·\'·~;}~liLj: r;lij ne.''\,':'': : :çc el) . ;." -~ .-;. ,~, 0,:, c: ~,'.:.L r '::,.; o '-, -:':'~'l() 'n '.J .' .• "' ~ r

=

~),

7

, ' ',1 '~ _{n '} '-'.1. 'l~ë ~

.

-, - l ~ ==

53 C

8crt"clE' c.:' c'

"~

"xrl

=

0 ,

0,43~

\~ 07 .~(~ }.::~_1i: ,:::~'.~.' '1"" ,.~.t -)!.!~=,p +1 ... ~ ,1 '-~~;:

,

->r,<~

=

')

,

17

;'r,L'!

':./!"l

0 ç,

11 C', O~

53C

'-

~,

17

7

',-; , : ï ' _...1 ' _-'-"

,-'-.T~:I~-r2:! tej_rl.~·~! ,:..,_,; lr8+,81 rr'O(l~lC t

',";.~~ 1~~!'tev~'~-'lic8 ~. cl. 0 [-; ::\7 i~\~;: ::-.10'

377 .

10

, ,~o"..~l i::/ "Lr1_1L'_• . '\("':1°:' - l 1-") v ... -,I . •

,

i

0l.11 8/l.iX : ,"r"'. , 1 I JOu 8:',',:r. -(~C\\:'I:-'F~J.~~~~'_~ . T ~ :_"',',~-~.~ '1l ~:. },.e ll:'~, iy<~':;_ .,~ ~

~r ., • . 02 _~...!...l~ . ~I""'~ .1C~ j01..:1:~,./r:l:.t .•

S.

1 C'-' joulr:,'tl";--. -ic"10/" 11 l ' v .- .~ -I"..~ - • J I:; -,~, V(:;T~~c:·.il

=

377

'1C'" 3~!~.1C--' ~-OG: O~",,'~t~)' ir' l(~J ~~c\lC' ' " ,

.

) ~ :~rnt8EllèCl'.; '" _J8ze ~ _..:..₈ 70 _,) A 10':) (!. 'I~Jl, :'~ ü,'~';' ~l JC"L~10!1 ~~l,-~r" .. ZlfJ ,-" r. ' 7 A " " · '

= ,,

-,)

.

1'--1·j_f:: _{"7!3,Y'r'lt8ir<-':'}_O_l_l~ _:-._i_·-ll' p:l... .. ·in? 01'"1 :{·1"> ~,. 0 I:) . '.,re~·~nV2. ·',1."loc's'~~ iOT·l,-'.r _

I :~-_ i:--3 -

<

,

7 .

1C --. j~:'l~10, \ ~l}r )8 ~C ~ !c·l '-_:', (}-:-. l ~r:: '2.(' .. C-P cC ,- ~l-' + n C! 1 C -~" , ... , ! ' .... , '-. ~ •

=

::.

_Cl

_,

7

_.

C( " _-:---1

r

,

:

_'

I

r

-3

4 ,

'::'

~~~ c :~, ~·l.ll? , ',-;:.- .~ "c :':.~lo ... 0')' _ /~ , ",7 • 1 C -' + ~ "r,::.ri'l·~~,;..~;' ~:)o :~O<?;'; l' c'l, i, ''èi ' 7 ~ _, C _·_,_i,1~ _._•1C-)(~ , , J \-2- '1' j C'!J

,

0/-

cl. '·1 •

,C':"4e

.1" ('C-,,1 • ·1): 2:'. i; \ . ,-",

.1

C'

~" "î(-:-. r-"'l L' ~: 1" -.... 0 ; J. .,:'

'.

"'=-

~"'.' J ~'8-'.r~.i ·'l~';.·: 1+·~1. 1.(),~!1-7 31C.1C/ 4, 1~ .1C): .:C-1~) " 1 '1e1_'1_oi1'2_1' J' 1'" ::clc" ( ' .. ':'

.

3) "

.

,-jou , l ' Cl.. / (); U.l; roT i:,-, .. " f.·~f· 4\J .... ·• 2860 k,::;,,\:',r. --ierir, r~08t ::19" r"7 1 ",0 :'). u jonle/Ullr 7 'or -'?Y1 ~?rz~0~~~e S~O~~ ~ ':' 10') 'Ïn111,'

I,

..

,

, • . v ,-~~ '. - .::> :'ct··,\ :1.}_ f3r·(.,:" '_,--, J~~ -} ... {; ··(~ll 0'l',: I """' 'I' ~) ;-~'L .r ,---.']: ,- /' -... =-=_t' _-~,)7. 'I~_\....I':: _II~ _. _,~ _-_.'1_'-~' ₌ r.

(24)

\-.../ e 2 lwlom. '. I Çy~ f..

1 War~"'~eiv'owl V".Jl d~ voe,1iC'/?,': Deze is 70,5.10° joule/uur. (zie

bij " 1 El

-t~lom;;

on' 'Or no 2).

2. '\V[~rmteiJ:::oud v~,n net~-~:"n :ie >0101"', il'ill de nr',' -:rzi,-icie verl :ê.t: Pentp,cl'-:.loorbutad'e "D.

C bij 250₀ = 196 ,joule/mol.

Ca'e~:i

-'

c8;,d

=

~35

.

joule/uur

.

cP bi ~ 204 = 274 joule/mol. p " , 6 .

TBt:üe h0eveelheid '·'.'.r:!te

=

301 • 235 (210-25)

=

13.10 Joule/uur •

.it.

\/armtein:'o"d vap ;'etg~"r c's kolom~,è"n 'e bovenzi i de v'2rlaat.

Trichlooretheen.

1.',' t ) . · . " "1 1 --"""''''' l'l' ~ co"," ~"~e'oeY1

.ê:.!.. "lI'JTl e Ule 'rrl .. ' ze 1 ,C'Ö>lk'":' .' ,; " 3~' ," J. ,.,'.

Condenso.tie\7o.r:.t~ bL 8R

=

-31, 4.10 ,iou~e/uur. 6 .

Total'? '-osVeell.eld .. : ri"1.te

=

9240.31,4.10

=

290.10 Joule/uur.

b. \'[,:tr-'t'? die vrij ;101). l~o;:'r;p b~'; afk001en v~.n

es

o iot 250•

~

'bij ?So

=

126,4 joule/mol. . l' ld 129 8 . 1 / 1

cP bij 8So

=

133,2 ,ioul·'/mol. cp [,'8:-rllL ',e

=

,

.Jou

6

ma •

Tgtale ilC'8veeF:e:i.d l'n.n'lte = 9~40

•

129,8 (88-25)

=

76.10 joule/uur.

Totale W';Ti::tei',houd V2,]". de tricLlorr'C)-G"c-::o'cl'np

=

6

3:6.106 /

290.1(' + 76.10

=

joule uur.

Tetr~.c 1 _t4looret:_,een_•

.ê:.!.. ',!armt:. eEe v~"; hZ

?':

~?§en _b),3_'_6,'i 8cor1"od3n~erlen/. ₁

COJl' en '~:uJ.eFar'~ G" .l.l c<: = - , . J3u e mo ~

Tot;:üe hoeve L1e:i.,'j ','~r"t::: = 208.36,8.10

=

8.10 joule/uur.

&

D"1I'T:1te dir, vrij

c bi,j 250

=

146,2

cP bij 8po

=

155,0

TBt'le hoeveel' aid

zou ~omc,n bi.j 3.fkoelen van 8So tot 25°.

• 10". joule/rlOl. r'c>,,' ,1' ld 150

6 .

,1 / , 1

100 . 1 / 1 C ,e ,L._.e

=

,

,lol.ue];]o .

• , ,lOU e mo . p

6 .

" c T , 8 = 208 • 150,6 (88-25) = 2.10 .Joule/uur.

Totale hoev:;81'\':?id c,I .. r'·~:e d~e de kolom .}, 'n .je tr;v8Ylzijde verlaat

=

31'6

o . 106 + 10 10• 6

=

771'

)

o. 10,6 ' JOu, 8; . ] ; . V.uT.

~ Warmte inhoud van de reflux.

De war:T:eir;'oud v,"n :~, 'tg'<'-"Yl ('8 Co:"'.:,;(,sor ','erl't is:

Tric'lor.r th?"n : 76.106 ,4müe/n_nr_(zie_{o:rder no} ₃₎

Tetr",cloor"t':éèo:r:: 2.10 joule/uur ( ide,"l

78.106 ,joule/mao

D:; ',,:"".r ,-t;ci'-,o'1c1 va.r

'

:~

1'C/"ln~~

= 1/6 • 72.106

=

13.106 ,joule/uur.

Je>j

(25)

Processchema: Bereiding van trichlooretheen uit tetrachloorethaan

4

.

1

959

[]

~

I

...

1

\l

/

I

.

~

I,

H~

­

r

r

1:

/

,

---

11

'--11r-'4

1

r

+-

-

r

-lf.-:::L--:':.

,

~

~I

!

,

1

I

I

F

~

-.J

~~

~

t

f

-

---L

r

I

~L

'"

I

~

--_:+­

L

'

:

-

~J~

n~'

r

-

El

i

I 1

I

~rf

l

-1-

'-

t

Ir

:

1

_

EI

'

,,·,

--_:+