• Nie Znaleziono Wyników

Industrial and Engineering Chemistry : industrial edition, Vol. 38, No. 6

N/A
N/A
Protected

Academic year: 2022

Share "Industrial and Engineering Chemistry : industrial edition, Vol. 38, No. 6"

Copied!
244
0
0

Pełen tekst

(1)

(2) HELPS Y O U SA V E TIME H ere is a M anual that will h e lp you to figure practically an y h e a t ex c h a n g e r pro b lem w ith a g re a t saving in time. T he d ata it contains re p resen ts the ex p e rie n c e of P faudler E n g in eers w ho h av e both d esig n ed a n d u sed h ea t e x c h a n g e rs in the C h em ical P rocess In dustries. Som e of th e inform ation does not a p p e a r in an y text book, re p resen ts a re al contribution to the technology of the subject. All of the m aterial is a rra n g e d to give you quickly th e facts n e e d e d to fig u re your h eat ex c h a n g e r req u irem en ts. This M anual is av ailab le to you w ithout obligation b u t w e do ask you to in d icate your title a n d to identify com pany affiliation. U se the coupon below or w rite us. As supply is lim ited, d o n 't delay ! THE PFAUDLER CO., Rochester 4, N. Y. Branch Offices: 330 West 42nd St., New York 18, N.Y.; 111 W. Washington St., Chicago 2, 111.; 1325 Howard St., San Francisco 3, Calif.; 455 Paul Brown Bldg., St. Louis 1, Mo.; 7310 Woodward Ave., Detroit 2, Mich.; 1318-lst Nat'l Bank Bldg., Cincin­ nati 2, O.; 1041 Commercial Trs. Bldg., Philadelphia 2, Pa.; 751 Little Bldg., Boston 16, Mass.; Box 982, Chattanooga 1, Tenn.; Enamelled Metal Products Corp., Ltd. Artillery House, Artillery Row London, S.W. 1, England.. Partial list of contents: Therm al d e sign exam ples Tem perature correction curves H eat transfer film coefficients P h y sic a l properties for miseellonc« co m p o u n d s. In stallation , operation and mainic» practices. A d v a n ta g e s an d limitations of varii typ es o f heat exchangers..

(3) i l . s j. i H i n ¡ j u. IN D U ST R IA L. a n d. E N G IN E E R IN G. V O L U M E 33, N U M B E R 6. EDITOR: W A L T E R J. M U R P H Y Assistant to Editor: N . A . PARKINSON. ISSUED JUNE 1°. 1946. INDUSTRIAL EDITION. a. C O N S E C U T IV E. N U M BER. 11. Departm ents E d i t o r i a l s ........................................................... H e a d l i n e s ..................................................... ^. 2. I. & E. C. R e p o r t s .......................................... Executive Editor:. JAM ES M . CROW E. Managing Editor:' D.. O . MYATT. Associate Editors. W ashington:. C H EM ISTRY. .. Instrum entation.. R O B E R T F. G O U L D. AL. A s W e S e e I t ...................... E q u ip m e n t and D e sig n .. L E G G IN. N e w York: HARRY STENERSON R ic h a rd L. Demmerle. *5. ....................................................................................................................................... *o á. C h a r le s O w e n B r o w n .................................. *6 9. R alp h H . M u n c h ................................................. * 75. W a ste U tiliz a tio n .. H a r o ld R. M u r d o c k ......................................................... 81. P lan t M a n a g e m e n t.. W a lt e r v o n P e c h m a n n .................................................... *8 7. From the E d it o r 's D e s k ........................................................... *. *140. Indícales page number In the advertising section.. Chicago: RICHARD L. KENYON. Technical A rticle s. San Francisco: FREDERICK G. SAWYER Assistant Editors. C o rrelatin g Filtration T h e o ry with Industrial Practice.. B. F. R u t h .................. 5 6 4. M ake-up: BERTHA REYNOLDS. A u t o c la v e for V is u a l O b s e rv a t io n o f H ig h Pressure R e a c t i o n s ....................... M anuscript Editing: HELEN K. NEWTON. i c l d i r ^ Io n t x c h a n g e P ro ce ss for Extracting C in c h o n a A l k a l o i d s. W . F. C a ld w e l l. 572. M anuscript Reviewing: STELLA ANDERSON. N o rm a n A p p l e z w e i g and S ilv io E. R o n z o n e Fib rillar Structure of R a y o n F i b e r s ...................................... 576. Editorial Assistant:. CORA GLASNER. Contributing Editors C H A R LE S O W E N BR O W N. L. M . W e lc h , W . E. R oseveare, and H . M a r k L o w e r F la m m a b ility L im its of M e t h y lc h lo r o s ila n e s ......................................... 580. E- W . B alis a n d H . Á . L ie b h a fsk y N o m o g r a p h for Form ulas C o n ta in in g Fractional E x p o n e n ts. 583. W . H e r b e r t B u rr o w s. 586. R A LP H H . M U N C H H A R O LD R. M U R D O C K W ALTER V O N P E C H M A N N. A d viso ry Board W. L. BAD G ER. H . R. M U RD O CK. H. E. BARN ARD. C . F. PRUTTO N. W. H . D O W. A . S. R IC H A R D SO N. GASTON DUBO IS. W . A . S C H M ID T. GUSTAVUS J . ESSELEN. R. N . SH R EV E. High Speed Rain Abrasion oí Glass Cloth Laminates R.M c G . R ob e rtso n , R. J. L o b isse r, and R. E. Ste in M o d if i e d C h ro m ic A c i d A n o d i z i n g P ro ce ss for A lu m in u m. 590. C . J. S lu n d e r a n d H . A . Pray 5 9 2 Free E va p o ra tio n into A i r o f W a te r from a Free H o riz o n ta l Q u i e t Surface L. M . K. Boelter, H . S. G o r d o n , and J. R. G riffin 596 R u st P re v e n tiv e O ils . G . P. P ilz a n d F. F. F a r l e y .........................................6 0 1 M o le c u la r V o lu m e s o f M o n o n u c le a r A r o m a t ic H y d r o c a r b o n s N a n c y C o r b in , M a r y A le x a n d e r, a n d G u s ta v E gio ff A c t i o n o f A n t if o u l in g Paints. J o h n D. Ferry and D ayton E. C a rritt. 610 612. F e e d in g Y e a sts from W o o d S u g a r S tilla g e .. 617. PER K. FR O LIC H. L . V . STECK. C. F. KETTERING. E. C . S U L L IV A N. 0 . E. M A Y. Fu n gistatic V a p o r s for C o n tro l of M o l d in P a c k a g e s and E q u ip m e n t. E. R. W EIDLEIN. C. S. M INER. J O H N M . WEISS. T h e o d o r e C . Sche ffe r and C a th e rin e G . D u n can M e t h o d s o f P ro d u c in g U n ifo rm V e l o c it y D istrib u tio n . R. L. S to k e r . . . . B e n z o ic A c i d from P h o s g e n e a n d B e n z e n e ................................. W a lt e r H . C . R u e g g e b e rg , Russell K. Frantz, a n d A b r a m G in s b u r g. E. F. Kurth a n d V . H . C h e ld e lin. 624. C h e m ic a l P ro pe llants.. he American Chemical Society assumes no responsibility 'or the statements and opinions advanced by contributors to its publications. V ie w s expressed in the editorials reports are those of the editors and do not neceswrily represent the official position of the American Chemical Society. Copyright 1946 by American Chemical Society 37,100 copies of this Issue printed. Fre de rick B e llin g e r, H . B. Friedm an, W . H . Bauer, J. W . Eastes, a n d S. M . E d m o n d s S t a y b w o o d — H e a t - S t a b iliz e d W o o d ................................................. 619 622. 627. A lf r e d J. Stamm, H o r a c e K. Burr, and A lb e r t Á . K lin e S o lv e n t Extractio n of C o tto n s e e d a n d P e a n u t O i l. 630. L- E. V ix , E. F. P o lla rd , J. J. S p a d a r o , and E. A . G a s tr o c k S o lu b iliz a tio n o f In s o lu b le O r g a n ic L iq u id s b y D e te rg e n ts. 635. Jam es W . M c B a in an d Paul H . R ichards M a te ria l or H e a t Transfer b e tw e e n a G ra n u la r S o lid a n d F lo w in g F lu id. 642. E. W . T h ie le. 646. D. E. W illia m s, F. L. M a c L e o d , É lise M o r r e li, a n d F. P. J o n e s V it a m in C o n te n t o f P e a s ......................................... 651. Fu se d Tricalcium P h o sp h a te F e r t i l i z e r .................................. X' i ' lcnowJed3i. with thanks the action of Patterson undry and M ach in e Com pany in releasing the front cover of this issue for editorial purposes.. fills month's cover photo depicts a filtration step in pigtnt manufacture. It was taken b y Robert Yarnall Richie. Plant of E . I. du Pont de Nemours & Company, Inc.. C . H . M a h o n e y , E. P. W a lls , H . A H u n te r, an d I . E . Sco tt 6 5 4 Tem perature E ffic ie n c y in D istilla tio n . M e lv in N o r d ................................. 6 5 7 P e p tiza tio n o f Pe a n u t and C o tto n se e d Proteins. Society at: Easton, pa. Editorial Headjiechpm (W/l ^ Washington 6 , D. C .; telephone, Republic 5301; New YnrU -iT k i v i° l y ° ric Editorial Branch, 60 East 42nd Street S e J c J ™ N B l I l ‘ « t e * « .« . Murray H ill 2-4662. Chicago Editorial Branch Office- a • % .d l' Chicago 4, III., telephone, Wabash 7376. Business ^ e riis iw o lf c » P lo ^ f <?155 1£ ih StAee!' N Washington 6, D. C . ’ •4430 d Slreet' N e w York 18' N - y -' telephone, Bryant ^ 3 ''lB 7 0 Sr mMer Post, 9 ? ice at P i-' “ "d er the A c t of Edition monthlv on i V S ‘ >A < H ,"dl,St' i l Edii ion montMy ° " ,hc 1st' Analytical >i<Jed (o r^ cZ-.? , J ,5 Acceptance for mailing at special rate of postage pro. Rem ,S i * Cli° j 11S 3' ° f October 3, 1917, authorized Ju ly 1 3 ,1 9 1 8 . ^address in d 'n / orf ers. for subscriptions and for single copies, notices of changes lent to ih„ a Professional connections, and claims for missing numbers should be "«th e American Chemical Society, 1155 16th S tre e t;N . W „W a sh in g to n ?, D .C. Thomas D. Fontaine, G e o r g e W . irvin g , jr., a n d K. S. M a r k le y. 658. Changes of address for the Industrial Edition must be received on or before the 16th ^ L n.2 ' m(r i ■‘‘ " ‘r e A n a ,',tlio)l Edition not later than the 30th of the i Claims for missing numbers w ill not be allow ed (1 ) if received honored ,T ■ £ '” Ue io,Wrin3 delivery hazards, no claims can be tfcjn r o V M eri ln c 5nllnenl.i l Europe, A sia , or the Pacific Islands other r e r e i w d T j f L ,1 i .SS 4 “ 6. 10 fi llure of 1 ° [ice of change of address to be for cla^m is '"m l« l„s f r o m 'f il« " * * precedins sente" « . or <3> if '« » " unit nnP tio n S _ l'ldu£tri ai and Analytical Edition sold only as a L n Union l o O'? ' p.onm‘; mbers J 4 .0 0 . Postage to countries not in the Pan-American yn>on 5 2.25. Canadian postage $0.75. Single copies—current issues InS0 80 A n a l S P r Ana.,ytical Ec*ition $ °-5 0, back numbers Industrial Edition 5 0.80. Analytical Edition prices on request; special rates to memters.. Che,mical Society also publishes Chemical and Engineering News, Chemical Abstracts, Journal o( the American Chemica Society. Rates on request.

(4) 4. INDUSTRIAL. AND. ENGINEERING. CHEMISTRY. Vol. 38, No. 6. F LO W R A T E S O F CELITE FILTER A ID S , ih o w . tng the w id e ra n go of flow rates possible with v a rio u s gra d e s of this m odern filter material. IT H Celite*—you can write your own clarifi­ cation formula. 9 grades of Celite Filter Aids W in varying degrees of fineness produce the exact com bination of clarity and flow you require. It is the great diversity in the shapes and sizes of the microscopically small Celite particles which largely determ ine their efficiency as a m odern filtra­ tion aid. These particles interlace and overlap to form a fine filter coating, with openings finer than the finest filter cloth. Team ed up with m odern filter­ ing equipment, they trap out suspended impurities, *Reg. U .S.P at.O ff.. Johns-M anville. allow only clear liquid to pass through. Today, there is hardly an industry employing a filtering process that does not benefit through the use of Celite Filter Aids. By providing the clearest filtrates at the fastest flow rates, they help increase production and low er costs in the filtering of syrups, fruit juices, pharmaceuticals, beverages, water, fats and oils, lubricants, and many jOHHS-MAKVlLtt other products. For further inform ation, write Johns Manville, Box 290, New Y ork 16, N. Y. PR.0ou.

(5) IN D U S T R IA L. and. E N G IN E E R IN G. C H E M IS T R Y. W a n , a m i P o d iu m * W ater and G. I. Salads. When the Army puts into effect a plan it is cooking up for American troops in Japan, we predict that the average soldier will turn military tradition topsy­ turvy by bragging of the newest raw deal he has had. And if he writes home about the luscious tomatoes he has seen on the “sacred isle”, probably he will be referring to the great im­ provement in quality of the fresh vegetables and salads served him at G.I. messes. They will be grown on the Island of Honshu in Army-operated hydroponic farms, the largest in existence. The Army first used hydroponics at Coral Gables, Fla., "here a small unit, patterned after commercial American in­ stallations, was built as a diversion for patients of a con­ valescent hospital. The potentialities of the unit for provid­ ing fresh food in out-of-the-way places were recognized by the Army Air Forces. Larger installations were constructed later, first on Ascension Island (2 acres), then on Coconut Island of the Hawaiian group (1 acre), Iwo Jima (2 acres), Georgetown, British Guiana (3.25 acres), etc. These projects now are not solely for the AAF, but are operations of the entire theater in which they are located. Less than 14% of Japan is arable, and that area has been farmed to death; also, Japanese fertilizing prac­ tices posed a serious sanitation problem for the foods that are eaten raw. Many of those foods do not ship well, and it seemed apparent that it was better to use water as a nutrient carrier in Japanese farms than to use it to float food ships from America. The basic unit of the installation in Japan is a gently slop­ ing, rectangular, shallow concrete bed, 9 to 11 inches deep and 4 feet wide, divided into sections 120, 100, and 80 feet long. The beds are filled within 2 inches of the top with /s-5/ 8 inch river pebbles. The plants are grown in these Pebbles by periodically moistening them with a water solu­ tion of the following fertilizer-grade chemicals per thousand gallons of solution : Potassium nitrate Calcium sulfate Magnesium sulfate Monocalcium phosphate Ammonium sulfate Total. 9 6 4 2 1 23. lb. 3 oz. lb. 6 oz. lb. 6 oz. lb. 10 oz. lb. 3 oz. lb. 12 oz.. Crop yield is roughly 5 pounds of vegetables per pound of. fertilizer. The beds are moistened Wo or three times daily, usually in the morning, from a 150,000-gallon storage tank serving ninety beds. The first section of the bed is filled from the bottom, drained into the second and then the third sec­ tions, and next into a sump, from which it is returned to the storage tank by a 550-gallon-per-minute centrifugal pump. Corrosion is no problem, but if iron pipes are used, enough iron goes into solution to satisfy the plant’s trace element requirement for this material. Chemical control of solution composition is extremely simple with colorimetric tests and calibrated charts. T\\ o faims totaling 1440 beds will be set up—one of 55 acres at Chofu (14 miles from Tokyo) and one of 25 acres at Otsu (6 miles from Kyoto, the unbombed cultural center of Japan). The entire cost of the project will be borne by the Japanese. Of approximately 1000 per­ sons required to operate the farms, only about 70 will be Americans, the remainder Japanese. The farms are designed to satisfy all the raw food requirements of the oc­ cupying American forces, and will provide 800,000 individ­ ual servings per week. Half of all the crops grown the first year will be tomatoes, another 15% lettuce, and the remainder evenly divided among rad­ ishes, cucumbers, peppers, and onions. Carrots and spinach may be added next year. Transportation facilities are good enough so that time from loading point to discharge point anywhere in the American occupation zone is less than that normally allowed between icing points in this country. When American military occupation of Japan ends, the farms will be returned to the Japanese. Lieutenant Colonel Ewing Elliott, in charge of the project for the Eighth Army, hopes that the results will indicate a way for Japan to produce more of its own food requirements. The water farms may be built on areas unsuitable for conventional agriculture, and 75% of the cost of operation is labor, notoriously cheap in the Orient. In fact, this particular item of reparations could turn out to be a valuable investment in the future economic health of Japan. D.O.M. {Continued. on page 8) *. inie^pAetaiioe. manUthf. c L fe ii ¿0*. cAe+niitl, cJtemicxd ewfuvzenA, a*uL e^cecuiùMU. i+t the. chem ical pA aducinf and cUettucal oatvium iw f ¿ndu4J>Uci.

(6) 6. INDUSTRIAL. AND. ENGINEERING. CHEMISTRY. Vol. 38, No. 6. It has a bo n n et fitted w ith a substantial forged steel yoke; a flanged forged steel p ack in g gland (elim i­ n atin g exposed th re a d in g on valve yoke, and. affording. protection. against c o rro sio n w hen placed in ex­ posed lo catio n s); and swivel bolts fo r h o ld in g the p ac k in g gland. It has no gaskets to blow , as in valves with flanged b o n n et connections. Stems, plugs and seat rings on all C hapm an List 960 Gate Valves are o f heat treated stainless steel to insure. m ore. efficient. w orking. qualities.. The Chapm an Valve M fg. Com pany P atent N o. 1,866,292. In d ia n O rch a rd , M ass..

(7) June, 1946. INDUSTRIAL. AND. ENGINEERING. CHEMISTRY. Your Bulk Muteriul Cun Be Economically Elevated By One Of These Units • L ink-B elt engineers have had extensive experience in th e design, m an u factu re and application of bucket elevators for varied service requirem ents. If your conditions call for th e use of a b ucket elevator, le t L ink-B elt show you th e m ost efficiently perform ing size an d type for y o u r needs. R efer to pages 862-916 of our general catalog No. 800 for com plete engineering data, specifications an d inform ation on how to select b u cket elevators.. L IN K -B E LT COMPANY Chicago 8, Indianapolis 6, Philadelphia 40, A tlanta, D allas 1, M inneapolis 5 San Francisco 24, Los Angeles 33, Seattle 4, T oronto 8. Offices in Principal Cities!. The Bulk-Flo is used where mass conveying is possible. I t consists of m alle­ able iron or steel flights attached to a chain. T he m aterial is fed directly into the lower horizontal portion of the cas­ ing, thereby elimi­ nating a feeder and is discharged a t the opening in the upper portion of the casing, ju st before the flights reach the head wheel.. The Rotor Lift. |s a H e l i c o i d (screw) e le v a to r *'hich h a n d l e s nany products th at formally can be •onveyed by a hori^ntal screw con­ d o r. It consists “ a vertical screw friven from either top or bottom , operating in a solid lr split casing. T he jjaterial is fed to tne vertical screw J screw f e e d e r "«r the foot of lift and is dis, a t the top faead end.. The Perfect Discharge Bucket Elevator. The Continuous Bucket Elevator. The Centrifugal Discharge Bucket - Elevator. o p e r a te s a t slo w e r sp e e d s an d is used w h e re m a te r ia ls w ill n o t readily discharge a t centrifugal speeds. M alleable iron or steel buckets are m ounted between two strands of chain. M aterial is fed directly into buck­ ets at the foot of the elevator or scooped up in the boot and d isc h a rg e d o v e r a sn u b b e d h e a d w h eel which inverts th e posi­ tion of the buckets o v e r th e d is c h a rg e chute.. is used where higher capacity a t slower speed is desired or where the m aterial is friable. I t consists u s u a lly o f s te e l buckets m ounted on either a chain or belt. M aterial is fed di­ rectly into the buck­ ets a t the foot of the e le v a to r an d d is ­ charged over a head wheel onto the pre­ c e d in g b u c k e ts , whose front and pro­ jecting sides form a chute, thereby direct­ ing the m aterial into a fix ed d isc h a rg e spout.. is used for most prod­ ucts. I t consists of either m alleable iron or steel b u c k e ts m o u n te d on either a chain or belt. The m aterial is fed ei­ ther directly into the buckets at th e foot of the elevator or scooped up in the boot and is discharged over the head w h eel b y c e n tr ifu g a l action.. lin k A. belt. ELEVATORS.

(8) S. t. t. 'U o U m i m. Today. PA LM ER Therm om eters are used for. A ccurate R esearch • W ith th e Ethyl C o rp o ratio n it's a c c u ­ ra c y first in th eir fam ed R esearch L abora­ tories. P alm er T herm om eters m eet h ig h est stan d ard s for a c cu ra cy , du rab ility a n d dep en d ab ility . P alm er's P a te n te d "R ed-R eading-M ercury" featu re perm its quick, easy re a d in g s at g re a te r d istan ces — ev en th ro u g h sm oke a n d steam . W h e th e r. re s e a rc h or m an u factu rin g processes, you g et th e sam e fine p re ­ cision in all P alm er Therm om eters . . . Industrial, R ecord­ in g a n d Dial Styles. A nd w h e rev er you look, you will al­ w ays find P alm er H igh Q u ality is sta n d a rd th e n a ­ tion over! W rite for C atalog. T H E P A L M E R CO. MFRS.; INDUSTRIAL. LABORATORY. RECORDING S DIAL THERMOMETERS. 2512 NORWOOD AVE.. CINCINNATI, NORWOOD, O. CANADIANBRANCH: KINGANDCtORCSl STS,. TORONTO. Operation Antimalarial. Malaria, the most extensive of all maladies in peacetime and a scourge to warm-climate troops, was largely removed from the field of tactical importance in the recent war. This advance was made possible through a program in chemotherapeutic research that was outstanding for its combination of intensity, organization, and cooperation. Since 1930 a related research program in Germany had failed to improve upon the unsuitably toxic pamaquine (Plasmochin) as a curative, and quinacrine (Atabrine), with its problems of application (partially psychological be­ cause of skin coloring) as a suppressive. Nevertheless, in 1940 the National Research Council took action that led ulti­ mately in 1944 to a full scale unified program under the Committee on Medical Research, of the Office of Scientific Research and Development. Universities, industrial and clinical laboratories, and research institutes were synchronized into a systematic program and organization. About 14,000 compounds,, drugs, or reputed remedies (exclusive of duplications) were tested, of which one third to one half were synthesized specifically for the program. Pre­ liminary testing on birds was complex. Not only were re­ sults of activity tests on avian malaria not directly applicable to the human, but variations existed from one avian parasite to another and even from host to host. Any material with possible activity against malaria was tested, from “old wives' remedies” such as African bitter apple and good bourbon whisky, to known active drugs (such as pamaquine) and their • homologs. Critical positive or negative characteristics were ob­ served through stepwise testing on two different strains of avian parasites in each of two different hosts. With favor­ able results, toxicity tests on mice and rats (and in some cases monkeys) followed. Active tolerable drugs were submitted to pharmacological tests in dogs, rabbits, and monkeys. la this program more than 25,000 avian tests were conducted, and over 2000 rats, mice, dogs, rabbits, and monkeys were used. Chemical candidates surviving this screening were examined in precise and extensive chemical tests in humans. Of the 14,000 compounds, approximately 100 have been found worthy of human test since 1942, as compared with about 25 carried that far in the German program of the past twentyfive years. The system yielded results. Well over sixty series of compounds of a wide variation of structures showed ac­ tivity against avian malaria, and a t least ten have been found active for man. This was a scientific advance, as it had previously been the concensus th a t only quinoline type structures were effective (quinine, pamaquine, and qumacrine are thus related). Practical results were gratifying» as there are now at least three curative drugs which appear superior to pamaquine: SN 13276 or 6-niethoxy8-(5/-isopropylaminopentylamino)-quinoline; SN 13429 or 6-methoxy-8-(4/-isopropylamino-l-methylbutyIamino)quinoline; and SN 9972 or 4 , 8-isopropylamino-l-methjlbutylamino-5,6-dimethoxyquinoline. Three drugs g a'e strong indications of being superior to quinacrine as sup­ pressives: SN 7618 or (Continued on page ^.

(9) lune, 1946. INDUSTRIAL. AND. ENGINEERING. CHEMISTRY. For effective, economical. specify a GIRDLER plant H E autom atic well-head gas dehy­ n atu ra l gas transm ission lines, liquid or dration u n it shown a t th e left is a solid carbon dioxide production, vari­ typical exam ple of how i t pays to getous chemical operations involving gases, G i r d l e r on th e job. N o operator is m etallurgical operations involving con­ needed for this factory assem bled' 'pack­ trolled atm ospheres, and for the dehy­ age” u n i t . . . fifteen m inutes atten tio n d ratio n of special gases such as n itro ­ once each week keeps i t in running gen, hydrogen, and carbon monoxide. order. T he only u tility required is a F or d irect evidence of w h at this m inute fraction of th e gas for fuel. No w ealth of experience m eans to you, steam . No electric power. No solutions. w rite to d ay giving a brief outline of T here are practically no m oving parts. your specific dehydration problem . D ehydration p lants of every s i z e solid dessicant system s (like th e one illustrated), diethylene glycol system s, refrigeration system s or com binations G irdler offers processes fo r gas m anufacture, of these—have been designed for sim­ purification, separation, and dehydration. C on­ ple operation and built for economical su lt G ird ler a b o u t y o u r p roblem s concerning perform ance by G irdler specialists in hydrogen sulphide, carbon m onoxide, carbon d i­ oxide, inert a n d controlled atmospheres, natural gas processing. G irdler dehydration gas, refinery gases, liquid hydrocarbons, hydro­ plants are being used for high pressure gen, nitrogen. O riginators o f th e Girbotol Process.. T. W e. DON'T. G U E S S. ABOUT. G A S. the G I R D L E R C O R P O R A T I O N G as P rocesses D ivision, D e p t. IE -6 , L ouisville 1, K y . D istrict Offices: 150 B roadway, N e w Y ork 7, N . Y . 2612 R uss Bldg., S a n Francisco 4, C alif. 21 E . Second S t., T u lsa , Okla,. 9.

(10) fe. s. s. Today 7-chloro-4-(4'-diethylam ino-l-niethylbutylamino)-quino­ line, a drug made by the Germans who, apparently, did not fully appreciate its efficacy; SN 8137 or 7-chloro-4(3/-dietliylamino-2-hj'droxypropylamino)-qumoline; and SN 10751 or 4-(7-chloro-4-quinolylamino)-a-diethylaminoo-cresol. In addition, a t least one other drug in each class has been shown superior in avian activity tests to those listed, and they are now being tested pharmacologically and clinically. Much has been achieved, but a great deal of additional work is needed before malaria finally can be brought under firm control. OSRD is disbanding, and no means of support is now in view for completing the program, particularly the costly but indispensable clinical tests. The benefits of this enterprise already are far-reaching: if it is-carried through to completion, the malaria menace may be banished entirely. R.L.K.. Looking at a b rig h t new stainless steel vessel, you get no idea w hatever about how long it w ill endure under your production conditions. And yet the way th at vessel w ill "take it” need not be accepted on faith. Go into your fabricator’s plant. See if he has all the special equipm ent and the trained mechanics required to w ork stainless steel as it should, be w orked; because it’s d u rin g fabrication th at the corro­ sion resistant qualities of stainless steel are either safeguarded or allowed to deteriorate. We w o rk exclusively as fabricators of stain­ less steel. Experience has tau g h t us how to overcome the difficulties th at inevitably arise in w o rk in g w ith this sensitive alloy. W e’ve equipped o u r p lan t and trained our m en for this job. T h e result is m ore en d u rin g process­ in g equipm ent for you, b u ilt for greater effi­ ciency in your application. S. B llck m a n , In c., 1206 Gregory A ve., W eeh aw ke n , N. J,. Less M ercaptan, More Octane. In striving to rid gasoline of mercaptans, the refiner has leaned rather heavily on aque­ ous caustic wash and the procedurc'known as doctor sweeten­ ing. These methods have disadvantages. Caustic treatment alone does not eliminate all of the mercaptans, and those which remain in gasoline become a costly nuisance. Their most un­ desirable characteristic (even when they are converted to odorous disulfides) is that they inhibit lead susceptibility. In the sweetening process, as a result, the octane number of gasoline may be lowered one or two points. This will explain the growing interest of the oil industry in the caustic-methanol method of mercaptan removal. In all respects it is an extraction technique as contrasted to processes based upon conversion of the undesired constituents into other materials. In the caustic-methanol method the mercaptans are almost completely removed. They are not con­ verted to disulfides. The use of caustic alone usually re­ moves only the lower boiling mercaptans. The caustic-methanol idea, as incorporated in the Unisol process, was originated and developed by the Atlantic Re­ fining Company; according to Universal Oil Products Com­ pany which licenses its use, eight extraction units of this type are in operation while three others are under construction. The Unisol mercaptan removal process consists essentially of five steps: (1) preliminary caustic washing to remove hy­ drogen sulfide, aliphatic acids, and (if desirable) phenols; (2) extraction of mercaptans and removal of methanol from the gasoline; (3) regeneration of caustic; (4) m e rc a p ta n sepa­ ration; (5) methanol recovery. Mercaptan removal takes place in a packed column with a caustic solution of about 4S° Be., introduced at the top of the column. I t flows downward, countercurrent to gasoline rising from the bottom of the column. Methanol, about 30 to 40% by .volume of the caustic solution, is introduced at the mid­ point of the column and divides it in two sections. Mercaptan extraction takes place in the lower half of the column while dissolved methanol is removed from gasoline m the upper half with fresh caustic. Gasoline leaves the top 0 the column free of caustic, and the reagent shows no tendency to absorb the fuel. (Continued on page w.

(11) INDUSTRIAL. AND. Still another . . .. ENGINEERING. CHEMISTRY. Heat transfer job expedited. by continuous, closed method T ' H i s v e rs io n o f t h e V o t a t o r s lu s h. fre e z e s f r u i t p u re e s ; ju ic e s , c o n c e n rates, a n d p u lp s in s e c o n d s , a s th e y '°w t h r o u g h t h e c o m p a c t , c o m p le te ly losed m a c h in e . C o n t a i n e r s a r e fille d n a c o n ti n u o u s b a s is , a n d go d o w n t h e onveyor lin e a t t h e r a t e o f 3 6 0 0 p o u n d s. w h o u r. O n e u s e r r e p o r t s t h a t h o ld tim e t h e r e a f t e r , f o r a s o lid fre e z e , fas c u t f ro m tw e lv e h o u r s a t — 10 ° to ■20° P to o n ly six h o u r s a t + 8 ° P . U n ifo rm r e s u l ts a r e a s s u r e d , fe rm e n Jhon a n d o ff-fla v o rs a r e p r e v e n t e d , a ll. t h e n a t u r a l q u a li t ie s o f f r e s h f r u i t a r e p r e s e r v e d . P r o d u c t io n c o s t is c u t __ e s p e c ia lly in r e g a r d t o r e f r i g e r a t i o n . C a p a b l e o f e x tr e m e l y e ffe c tiv e h e a t t r a n s f e r , c o n ti n u o u s , c lo s e d V o t a t o r e q u i p m e n t is a c h i e v i n g s im ila r s u c c e s s in t h e p r o c e s s in g o f la r d , p h o t o g r a p h i c e m u ls io n s , m a r g a r in e , v e g e ta b le s h o r t ­ e n in g , s h a v i n g c r e a m , p r i n t i n g in k , t e x ­ tile. p r i n t i n g g u m s , p o lis h e s , p a ra ffin. w a x . I f y o u r p r o c e s s in g p r o b le m fa lls i n to o n e o f t h e s e c a te g o r ie s , p l a n s a re r e a d y f o r a p l a n t - t e s t e d V o t a t o r ir.-. s t a l l a t i o n c e r t a i n t o p u t p r o d u c ti o n o n a m o r e p r o f i ta b l e b a s is . T h e G ird le r C o rp o ra tio n , V o ta to r D iv is io n , D e p t . I E - 6 , L o u is v ille 1, K y . B r a n c h e s : 1 5 0 B r o a d w a y , N e w Y o r k 7; 6 1 7 J o h n s t o n B ld g ., C h a r l o t t e 2, N . C .; 2 6 1 2 R u s s B ld g ., S a n F r a n c is c o 4 ., C a l..

(12) YOU GET ACCURATE WEIGHTS ¿Led>ucaiLii G antialied. w it h. EDTBAUER-DUPLEX A u to m a tic. NET WEIGHER Series “ C ” W eighers, w ith electrically con­ trolled discharges, are available in 4 sizes to provide weighed discharges of dry, powdered, gran u lar or pellet m aterials from 3 ounces to 75 pounds per discharge, a t rates u p to 26 discharges per m inute. Possible accuracies are. ¿. J. a. m. Today Caustic is recovered in a regeneration column where open, superheated steam is employed to strip the solution of methanol, mercaptans, and some water. On its way from the bottom of the extractor the caustic-methanol solution passes through a heat exchanger where the solution is heated, and regenerated caustic returning to the extractor is cooled. Mercaptan separation is achieved through condensation of the mercaptan-methanol-water vapors from the regenera­ tion column, which produces a two-phase system—a lower aqueous methanol phase and an upper mercaptan oil phase. The two phases are separated by skimming off the mercaptan oil, which is run off into a disposal system in which it is burned or recovered for sale. The aqueous methanol phase is fractionated, and the recovered methanol is circulated back to the extraction column. There are some undesirable features of the caustic-methanol method. Corrosion became a problem in the earlier plants; the deterioration in the bottom of the caustic recovery section was severe because of its carbon steel construction. Repairs had to be made frequently. However, C. D. Lowry, Jr., and F. C. Moriarty of Universal advise that experience has proved corrosion may be avoided by the use of proper alloys in the high temperature zones. The extraction column also is rather tall, and the installations made thus far contain as many as 40-54 vertical feet of carbon Raschig rings. On the other hand, there are distinct advantages in utilizing the Unisol process for mercaptan removal. H. W. Field, of Atlantic Refining, says it conserves gasoline, tetraethyllead, and reagents, which would be lost through some of the other refining methods. Tetraethyllead today is under strict allo­ cations because of the lead shortage. Among the chemicals saved are litharge, caustic for doctor sweetening, and copper salts for copper sweetening processes. The gasoline losses, according to Lowry, are so low that they approximate the volume of the mercaptans removed. Caustic consumption is low, extractor temperatures run between 80° and 100° F., and the total cost of chemicals and utilities in the process is within the'range of 1 to 1.5 cents per barrel. The methanol, being volatile, can be recovered if i t ' becomes necessary to discard the caustic because of contamination with sulfide or aliphatic acids in the feed. H.W.S.. from Vio to Vs of 1% . E ith er disc or pin-type power feed can be furnished to assure a continuous supply of dry m aterials to th e weighing hopper. Efficiently handles a wide range of crystals, granulated, or pow dered chemicals.. B . F . G. u m. p C o .. Engineers and M anufacturers Since 1872 415 S O U T H C L I N T O N S T R E E T , C H I C A G O 7, I L L I N O I S. Cats’ Eyes from Rat Poison. When the Allies’ wartime research on radar became too great to hide completely from the Germans, our counterespionage service obligingly “let slip” th at the operating principle was based on infra­ red radiation. This effectively diverted the enemy from radar research as we knew it, b u t boomeranged by spurring them on to the highly successful development of infrared methods of detection and observation. Much has been published recently on our similar d e v e l o p m e n t of the “sniperscope” and “snooperscope” , based on a nearinfrared searchlight and viewer assembly that proved so effective in the last stages of the war. After the German surrender an investigator from Techni­ cal Industrial Intelligence Committee ran across a re la te German development (Continued on page 4.

(13) wnen you buy a Q U IM B Y S C R E W PUM P you get something more than just a pump. You get the benefit of more than fifty years experience in pump designing. Quimby originated the screw pump in 1 894. For more than half a century, the Q U IM B Y Screw. m?tv/ QUIMBY. FLOATING LINK. P e r m it s H ig h e r P r e s s u r e s — H ig h e r S p eed s— L ow er V iscosities. A revolu­ tio n a ry new fe a tu re t h a t will v a s tly in­ crease th e efficiency, te m p e ra tu re range, a n d flexibility of th e screw p u m p . T h e F L O A T IN G L I N K is a n exclusive fea­ tu re of Q U IM B Y G e ar-in -H e ad P um ps, a n d is a v ailab le fo r th e conversion of p re sen t p u m p s. W rite fo r com plete in fo rm a tio n . ★ Patent Pending. Pump has been progressively improved until today, with the introduction o f the revolutionary FLO ATIN G LINK*, it is without an equal. W hen you buy a screw pump, be sure it’s a Q U IM B Y — there is no substitute. Quimby has a completely ad ap tab le line of screw pumps in a wide range of sizes and types, as well as a complete line of ROTEX and Centrifugal Pumps. If you have a pumping problem, ask Q U IM B Y about it.. The KN O W H O W o f Pum ping since 1894. H. K . P O R T E R C O M P A N Y , In c, PITTSBURGH. 22,. PENNSYLVANIA. Q uim by Pum p Division District. N E W A R K 5 , N. J . O f f i c e s in P r i n c i p a l. Cities.

(14) S W. i i i d. Today. utilizing infrared radiation. The collecting lens system for this instrum ent consists of elements ground from single crystals of a eutectic mixture of 42% thallium iodide and 58% thallium bromide. The result is a beautiful rose-colored crystal, soft enough to be cut with a sharp knife and sawed, yet capable of being ground and polished like glass. The refractive index is (about 2.2 to 2.5) both in the visible and infrared spectra. The Germans claim it is transparent to infra­ red radiation up to 30-micron wave length. Scientists of the Engineer Board, Fort Belvoir, Va., have success­ fully made single crystals up to 2 inches in diameter and hope to make them up to 8 inches. The method used is Massachusetts Tech’s Stockbarger process, which consists essentially of lowering a molten mixture of the material through a carefully controlled tem perature gradient that encourages formation of a single crystal. Research aimed a t uncovering other crystalline materials with similar properties is planned. In this work the em­ phasis will be on water-soluble salts, which in general are easier to grow than the thallium compound crystals. So little is known about fundamental chemical-optical rela­ tions th at research now is in the pioneering stage. The Engineer Board investigators had an unexpected windfall of thallium shortly before V-E day, when a German submarine bound for Japan was captured in the Atlantic off the North American coast. Among other items in a cargo th at must have made our military scientists lick their chops in delight were 200 pounds of a 50-50 alloy of lead and thallium. But most of the thallium compounds used in our country’s studies of this intriguing new optical material was obtained from rat poison. D.O.M.. : -. - -. : v. Synthetic Sun Tans. There will soon be no need travel to Florida or California to acquire th at desirable nut-brown tone on your skin—th at is, if the chemists have their way. Old Sol, or a reasonable facsimile thereof, will be as far as the nearest fluorescent light fixture. For some years commercial sun lamps have been avail­ able which utilize a high intensity mercury discharge to emit radiation th at will tan the body. These lamps, however, consume 100 to 500 watts or more of power am! have a low efficiency in converting this into useful sun tan radiation. In addition, their operation requires special­ ized equipment. An extensive investigation of ultraviolet emission by means of fluorescent lamps was undertaken some years ago by the Sylvania Electric Products Company, and it was found possible to convert electrical power to a desired radiation with fluorescent powders or phosphors, ft "as also discovered th a t this conversion was more efficient than the conventional one, since it was capable of producing the same sun tan radiation with about half of the usual power consumption. The problem was essentially a phy-'*CJ chemical one of producing a stable powder th at will enn radiation of the desired wave length and brightness ' maximum conversion efficiency. (Continued on jiage 1.

(15) June, 1946. INDUSTRIAL. AND. ENGINEERING. CHEMISTRY. -< m M ie T H R E S H O L D O F CHEMICAL PROGRESS.... T o the chemist of today Furfural and the other available Furans offer the same opportunity for chemical discovery as did ben­ zene seventy years ago. F o r m any years chem ­ ical industry has neglected Furfural and its de­ rivatives, prim arily because they frequently did not behave in the m anner w hich would have been predicted from consideration of the ring substituent. Chemists are now beginning to realize that this unorthodox, behavior might open up interesting and valuable developments. In the meantime the physical properties of. Furfural, such as its preferential solvent action on unsaturated compounds, its effectiveness as a dispersant, as a w etting agent and bactericide have so extended its use and reduced the cost of m anufacture that Furfural is the cheapest pure aldehyde available today. Because of its low price and because of its chemical activity w hich is a function o f both the unsaturated ring and the aldehyde group, chemists will find it w o rth while to w ork w ith Furfural. Samples of Furfural will be furnished w hen requested on your business letterhead. P R O P E R T I E S OF Q U A K E R. FURFURAL. (F u rfu rald e h yd e , C (H 30 -C H O ) A m b e r-c o lo re d liquid o f h ig h « a b ilit y a n d u nu.uol pu rity. in a series on the Durans arc also available to those in­. H C ------ C H. II* 1 II xo '. H C ’ , ' C -C H O. terested. 1 hey contain interesting and inform ative data as indicated b y the titles: _ „ Bulletin 201. General Information About Furfural. B u lle t in 2 0 2. Introduction to the Chem­ istry of the Furans. B u lle t in 2 0 3. Physical Data on Furfural.. Molecular W eight..................94.08 reejmg om ,> C - . . . ............ 37 Boiling Range {9 9 % )° C .. 157 to 1 67 Specific Gravity {20/20°C). . . . 1.161 Flash Point (open cup)°C............56 Refractive Index (20/D)....... 1.5261 SurfoceTension at 20°C (dynes/cm) 49 Viscosity at 38°C (centipoises).. 1.35. leum hydrocarbon, end glycerol; 8 . 1 3 % by wt. In water at 20°C.. Solub ility: Completely miscibfe with ethyl alcohol, ether, acetone, benzol. butyl acetate, china wood oil and. A n a ly s l« Furfural, minimum % .............. *99.5 W ater, maximum % ................... Q 2 Organic Acidity, Maximum equ«v/l........................... 0.023 Ash, maximum % ...................0.006 Mineral Acidity....................... None Sulfates.................................None Ketones................................. None. mast organic solvent, except petro-. *A s determined by A.O.A.C. method.. S ta n d a rd C o n ta in e r« 9 . 4 5 , 90, and 520 lb. Drums fCarload of Drums 80 to 88 . .41,400 to45,740 lbs. Tank cor 8,000 gal........................... 78,000 lbs Tank car 10,000 go l............... .......98,000 lbs.. B u lletin 201 is o f g en eral in te re st to all users of chem icals. B ulletins 202 and 203 c o n tain in fo rm a tio n o f in te re s t p rim a rily to th e resea rc h w o rk e r.. tO D T requires maximum loading Drum s n o n -re t u rn a b le. The Quaker Qafs G>mp 1 9 1 0 B O A R D O F T R A D E B ID G . 141 W. J A C K S O N B IV D ., C H IC A G O 4, ILL IN O IS. URFURAL. .. FU R F U R Y L A L C O H O L. F U R O IC A C ID. .. TETRAHYDROFURFURYL A LC O H O L.

(16) IF YOU USE D IS T ILLED W ATER The C O C H R A N E D E M IN E R A L IZ E R will give you the equivalent of distilled water at a fraction of the cost.... GET THE FACTS. I. & E. C. Reports on the Chemical World Today. I t was noticed that, when a phosphor was subjected to radiation of a given wave length, the fluorescent radiation emitted always had a longer wave length than the incident radiation. A common example is the irradiation of cer­ tain phosphors by “black light” of 3400-3800 Â. wave length and the spontaneous emission by these phosphors of visible light with w’ave lengths anywhere from 4000 Â. (blue) to 7000 Â. (red). The choice of the phosphor depends upon the desired application, since it is necessary to consider the effects of air, ozone, heat; and gaseous discharges upon the phos­ phors during either utilization or manufacture. The adaptability of the powder to mechanical treatm ent such as milling and grinding for use in paints or other suspen­ sions must also be taken into account. In the main, the phosphors investigated consisted of metallic phosphates or silicates activated by thallium, lead, or cesium. A representative lot of optimum com­ position of each of the types studied was prepared in a lacquer suspension and applied to glass bulbs in a con­ ventional manner. Lime glass was used in the case of the black light phosphors, and germicidal glass passing all wave lengths down to approximately 2000 Â. (in the ultraviolet range) was employed for the sun tan phosphors.. W rite fo r a copy of this Cochrane Publication 4181. 20 HOURS L A M P BU R N ED. These bulbs were then made into lamps and su b jected series of tests, including spectral, energy distribution studies and lamp life observations. A phosphor of com­ position Ca 3(PCu)2 (thallium-activated) showed a reason­ ably high output value of good maintenance c h a ra c te r­ istics. With, a redesigned model of the two-lamp fixture using aluminum reflectors with an increased a m o u n t o current flow, it was possible to produce with 140 watts an erythem a (sunburn) of a pinkness comparable to that o tained by a 300-wTa tt mercury type lamp. I t is expected th at installations of this lamp can e adapted to bathroom use to give automatic 5 -minute ex posures during shaving or more general exposures durwn showering. Although no immediate tourist trade up heaval is foreseen, the American bathroom may become competition for the winter resort of the future. to a. COCHRANE. CORPORATION. 3132 North Seventeenth St.. P H ILA D ELPH IA 32, PA.. <-/ / / Je ciu ^ U ).^.

(17) June, 1946. INDUSTRIAL. AND. ENGINEERING. emember 7942? Aviation gasoline w as critically needed and the muscles of the petroleum refining industry flexed. But, looming as a major menace to the program, w as a shortage o f iso-butane. Some­ thing had to be done ... and fast. A new process to convert abundant normal butane to iso-butane w as adopted. Then, Porocel Corporation w as assigned the job of perfecting the manufacturing technique and producing the vital isomerization catalyst m large quantities. Within six months the technique w as perfected, a special plant w as built to produce the catalyst, and the first car-load w as roll­ ing to the refiners. Because of prompt action in an emergency, a gravely needed product w as m ade available in ample quantities. Furthermore, high operating flexibility of the catalyst resulted in iso­ butane production records o f double the anticipated capacity in many plants. The w a y w as paved for a substantial increase in the flow o f aviation gasoline. This is one example of the results obtained when "orocel Corporation's laboratory research, practical. P O R O C EL. CHEMISTRY. experience and flexible plant facilities are applied to problems o f catalyst manufacture. It is a typical example, too, o f the superiority of Porocel as a catalyst carrier. Its natural. ore. ruggedness, high. adsorptive activity, uniform dispersal qualities, free­ dom from impurities, inertness and extremely low cost are the characteristics that insure economy and operating efficiency. New applications for Porocel, either as catalyst car­ rier or direct catalyst, are regularly being discovered. It is possible that we can perfect and manufacture the catalyst you need. W hatever your catalytic problem, our staff o f experienced engineers will be g la d to assist you. Just address: Attapulgus C lay Com pany (Exclusive Sales Agent), Dept. C, 2 6 0 S. Broad St., Phila. 1, Pa. 'Anhydrous A i d s Impregnated on Porocel (Deironed, activated bauxite) and sold under the trademark IS Q C EL. C O R P O R A T IO N , BAUXITE CATALYSTS, CATALYST CARRIERS, ADSORBENTS and DESICCANTS.

(18) 18. INDUSTRIAL. AND. ENGINEERING. CHEMISTRY. Vol. 38, No. 6. The F A C T S Behind the Glycerine Sho rta ge. VV\WVVVVWlWVVVVVWVVVVVVVVVVYWlW\/VVVVWVVVWVVVVVVVVWVVVWVVVWVVWV\a\WVVWl/VWVVVWVVVYanaWV. A s everybody knows, the war and the w idespread dis­ ruptions following it have caused a serious w orld-wide shortage of fats and oils, from which glycerine is derived. This is the reason why enough glycerine cannot be produced at present to supply im m ediately all the heavy dem ands o f the reconversion period. Ju st as bread is short because of the world-wide sh o rt­ age of w heat so, tem porarily, the fu ll dem and for glycerine cannot be supplied because of th e shortage of fats and oils. As this situation gradually corrects itself, glycerine will be in good supply again and fully at your service.. G L Y C E R IN E. P R O D U C E R S ’ A S S O C IA T IO N. 295 Madison A ve., N ew York 17, N . Y .. Research Headquarters, Chicago, III..

(19) A D V E R T IS E M E N T — This entire page is a paid advertisement _ 1. o ^ j Prepared M onthly by V . S. Industrial Chemicals Inc. U.S.I.CHEMICAL NEWS ____________A M o n th ly S e n e s for C hem ists a n d E xecutives of th e S olvents a n d C h e m ic al C o nsum ing In d u s trie s. *. 1946. Two P h en olic R esins Now Are Available for Immediate Shipm ent. U. S .1. Opens New Laboratory To Evaluate Wide Range of Products. 100% R o sin -F ree, T h ey P ro v id e D u ra b ility , C h em ical R esistan ce. Installs Complete Facilities For Evaluation Of Chemicals and Insecticides at Baltimore, M aryland. Arofene 700 and A rofene 775, two wellknown U.S.I. pure phenolic resins, are now available for im m ediate shipm ent. B oth resins are entirely free from rosin a n d rosin deriva­ tives. Used principally in sp ar varnishes, chem ical-resistant finishes, ethyl cellulose fin­ ishes, and in varnishes for fortifying alkyds, they im part excellent durab ility and re m a rk ­ able resistance to salt w ater, acids, strong alkali, a n d o th er corrosive substances. P ro d ­ ucts m ade w ith these resins exhibit good color and drying properties.. Arofene 700 Arofene 700 is a heat-hardening, heatreactive 100% phenolic resin w hich, in com­ bination w ith drying oils, gives h a rd durable finishes. I t provides outstan d in g resistance to chemical reagents in a w ide variety of form u­ lations, and produces varnishes of m axim um durability. V arnishes m ade w ith this resin are unusually p ale and exhibit fa r less afteryellowing than is norm ally expected from a pure phenolic. T hey possess good gloss, and wth tung or oiticica oils, the inclusion of small am ounts of linseed oil produces h ig h ­ est gloss. To obtain the best results, A rofene 700 should be processed w ith a preponderance of hard oils,” such as tung or oiticica. V arnishes ™h oil contents com posed largely of “ soft oils, such as linseed or dehydrated castor, are practical, b u t are m uch slower drying. The addition of A rotene 7UÜ to o th er resins m varnish form ulations, reduces the cooking cycle of the varnish, or enables the m anu­ facturer to acquire high varnish viscosities which otherw ise would be im possible. Its in ­ corporation in this m anner, also adds to the durability and resistance of the varnish. M anufacturers have found A rofene 700 Weal for su p er spar varnishes, alkali-resistant ( Continued on next page). As one of the first steps in its broad program of expansion, U.S.I. has organized an unusually complete laboratory for the evaluation of a wide range of products. The new laboratory, located at Baltimore, Maryland, occupies. THE MONTH IN INSECTICIDES C o a ts fo r seeds, c o n ta in in g b u ilt-in insec­ ticides, fu n gicid es, fertilizers, a n d hor­ m on es m a y h a v e fa r-re a c h in g effects . . . Benzene he xac h lo rid e is reported to be seven tim es m ore effective a g a in s t flies than D D T . . . The effectiveness o f rotenone o il s p ra y s in co m b a tin g C a lifo rn ia red sca le is s a id to b e increased b y the a d d i­ tion o f b utyl p h th a la te . . . M e t h y l b ro ­ m id e is used to control the p in e a p p le m e a ly b u g . . . The A r m y ’s sm o ke a p p a r a ­ tus is n o w b e in g used to d e live r su pe r­ h eated oil y a p o rs for tre a tin g ve ge tatio n . . . A ra p id field m ethod fo r a s se s s in g the sp re a d in g p o w e r o f a n tim a la ria l o ils is d e ve lo p e d . . . C y c lo p e n te n y la m in e s are identified a s a n e w g r o u p o f insecticides . . . A n o th e r effective insecticide fo r house flies is m a d e from S a b id illo se e d s . . . A series o f n e w insecticides are u se d for chicken louse control.. 1m feet of 1floor space and , ore than --- 9000 ---- sq 1u — are “ * V V 1, v*. IVU* o pavo a u u is equipped w ith the last w ord in chem ical, physical, and entom ological testing facilities. F o u r m ajor fields of activity are now being investigated in the laboratory: the study of solvents and plasticizers; the testing of a n ti­ freeze com pounds and other autom otive p rod­ u c ts; technical service fo r custom ers; and evaluation, com pounding, and developm ent w ork on insecticides and insectifuges. P roceeding on the belief th at the success of any new -product program depends in large m easure on the accu rate evaluation of th e com m ercial perform ance of new products, U.S.I. has assem bled an exceptionally fine staff of chem ists, biologists, and entom ologists to carry on this work. A ctivities of the new T echnical D evelopm ent L aboratory will be closely in teg rated w ith those of the com pany's research groups at Stam ford, Conn., B alti­ m ore, M d., N ew ark, N. J., and w ith the Dodge a n d O lcott laboratory a t Bayonne, N. J.. R ats’ C ancer K illed By A lcohol E xtract A n alcoholic ex tract w hich destroys tum ors and cancers and sets up im m unity against th eir grow th in inbred albino ra ts has been announced in a technical pap er published r e ­ cently. T h e extract has been tested success­ fully on rats, but is not ready for use on hum ans, the authors said. T hey stated fu r­ th e r th at th eirs w ere the first successful ex­ perim ents of this type.. This in g e n io u s d istilla tio n se t-u p p ro v id e s a c c u * rate a n a ly s e s o f o r g a n ic s o lv e n ts q u ick ly.. Improved T h yro id P roduct Prepared by N ew Pi-ocess To m inim ize m any of the objectionable Physiological effects of thyroid preparations to com bat excess w eight, a new brom iated thyroid com pound has recently been Invented. T h is com pound is reported to lessen “e increased pulse rate, p alpitations, emo°nal upsets, and m uscle trem ors which some«mes follow thyroid injections. According to the patent, the brom inated Ptoauct is prep ared by treating a com m ercial ™a_ered thyroid w ith ethyl alcohol and MWile a t room tem peratures. A fter standing _ J | night, the m ixture is filtered, and the nr. Inater*a l *s allowed to dry at room temJ fature. T he final product is stated to be no , «rent from the original desiccated g landu­ le material, except th a t it contains 0.2% to ^ ¿ a d d e d brom ine.. T he A d m in is t r a t iv e G ro u p o f U .S .I.'« T echn ica l D e v e lo p m e n t L a b o r a to ry m a p s ou t the tests w h ic h w ill d e te rm m e the p e r fo rm a n c e -v a lu e o f a n e w p rod uct. Left to righ t- N C Sch ultze A s s is t a n t D ire ctor o f the L a b o ra to ry , W . E. D o v e , D ire ctor o f the E n to m o lo g ic a l D iv isio n ^ D, g ! Z in k D irector o f the T echn ica l D e v e lo p m e n t D e p a rtm e n t, N. C. M c A lis te r, Jr., A s s is ia n t to.

(20) A D V E R T I S E M E N T — This entire page is a paid advertisement.. U.S.I. CHEMICAL NEWS M akes A lcohol Solutions O f H ydrogen P eroxide A recently-issued patent describes a m ethod by w hich strong alcohol solutions of hydrogen peroxide can he prepared. T hese solutions a re rep o rted to be useful in m any in d u strial organic processes in which the aqueous hy­ drogen peroxide of com m erce has been found unsuitable. H ydrogen peroxide is of particu lar value as a catalytic reagent in m any poly­ m erization reactions, and as an oxidizing agent for use in oxidizing and decolorizing certain types of com pounds. T he process of p reparing the solution con­ sists, basically, of treating the boron ester of an alcohol w ith com m ercial aqueous hy­ drogen peroxide. Boron hydroxide precip i­ tates, leaving a nonaqueous solution of the peroxide. E thyl, butyl, and amyl alcohol are stated to produce satisfactory solutions.. New L a b o ra to ry ( C ontinued from preceding page) T w o o f the m a n y tests w h ic h a re n e c e ss a ry for the p ro p e r e v a lu a t io n o f a n a n ti-fre e z e are b e in g co nd u cted here. O n the left, the la b o r a ­ tory w o rk e r is d e te rm in in g the effe ctiven ess of a n ti-fre e z e c o rro sio n in h ib ito rs. The tech n icia n on the rig h t is m e a s u r in g the fo a m in g te n d e n c y o f a n e x p e rim e n ta l a n ti-fre e z e b y m e a n s o f a s e t-u p that s im u la te s the w o rs t p o s s ib le fo a m ­ in g c o n d itio n s e n co u n te re d in a n a u to m o b ile .. varnishes, and ethyl cellulose finishes. It has also been used w idely as a fortifying resin to increase the alkali and m oisture resistance of alkyds and other resins. A ro fe n c 7 7 5 M anufactured to m eet U. S. N avy Speci­ fication 52R11, A rofene 775 is an oil-soluble, 100% phenolic resin of the type w hich is non­ reactive w ith oils. As the sole resin com ­ ponent in the m anufacture of varnishes, it insures excellent chem ical resistance and durability, as well as good color and drying properties. As a fortifier in m odified resin varnishes, it im proves the durab ility and re ­ sistance of the original product. A rofene 775 can be used w ith all the usual varnish oils, although it should not be used w ith straig h t tung oil. A ll tung oil varnishes should contain 20% or m ore of an oil such as linseed. Since this resin is readily soluble and “non-reactive” w ith oils, relatively sim ple cooking procedures can be em ployed w ith excellent results. O utstanding sp ar varnishes and m arine p aint vehicles are produced using A rofene 775. T h is phenolic has also been employed w idely in the m anufacture of finishes resis­ tant to boiling w ater, salt-spray, alkali, organic solvents, and acids. In addition A rofene 775 has been used advantageously in fortifying a w ide variety of varnish form ulations. Specifications and sam ples of both resins a re available on request.. U 60. C. A l l k n o w n in s e c t i­ cide s a n d in se c tifu g e s a n d m a n y e x p e r i­ m e n ta l p ro d u c ts run the g a m u t o f teèts in th e E n t o m o lo g ic a l L a b o ra to ry . The jdrs s h o w n h ere co ntain a ll s ta g e s o f the co m ­ m on sp e cie s of cock­ ro a c h e s. R e s u lts of t e s t s p e r f o r m e d on t h e s e in s e c t s h e lp g u id e re se a rch e rs in the d e v e lo p m e n t o f to­ m o r r o w ’s insecticides.. 42ND. ST .,. NEW. YORK. 17.. N.. ALCOHO LS Am yl A lcoh ol Butanol (N orm a! Butyl A lcohol) Fusel O il—-Refined. A C E T IC ESTER S Am yl Acetate Butyl Acetate Ethyl Acetate. Ethanol (Ethyl A lcohol) Specially Denatured— all regular and anhydrous formulas Com pletely Denatured— all regular ano’ anhydrous formulas Pure— 190 proof. C.P. 9 60r, Absolute •Super Pyro Anti-freere . *Solox Proprietary Solvent. O X A L IC ESTER S Dibutyl Oxalate Diethyl Oxalate. *A N SO L S Ansol M Ansoi PR. usr. Y.. P H T H A L IC ESTER S Diamyl Phthalate Dibutyl Phthalate Diethyl Phthalate O T H E R ESTERS •Diatol Diethyl Carbonate Ethyl Choloroform ate Ethyl Formate. "" ‘. A resilient floor covering is claim ed to have the cushioning feel of a n expensive deep-pile rug, a n d yet be w a sh a b le a n d tough enough to with­ sta n d the h eav y traffic of offices and lobbies. It is d escribed a s being com posed of a durable p lastic su rface on a n 8-inch la y e r of sponge. (No. 080) USI A n e w textile preserv ativ e, claim ed to be the m ost versatile, efficient, a n d long-lasting textile p reserv ativ e thus far known, is said to afford d u rab le protection a g a in s t fungi, soil-inhabiting organism s, an d jungle rot. It is described as being unaffected by w a te r sp ray s, w eather ex­ posure, sunlight, a n d laundering, and to be com patible w ith w ater-repellent an d fire-re­ ta rd a n t finishes. (No. 081J. C h e m ic a ls ,. In c. ■— _. B mBtß B ■ EAST. To cure troublesom e foam ing, a new compound is m arketed w hich is sa id to be effective in con­ centrations a s low a s 1 p a rt p e r million. It is described a s a viscous, tasteless, colorless, chem ically inert, a n d non-volatile organic ma­ terial. (No. 073) USI To im part crispness to fabrics, a new textiletreating resin is offered w hich is claim ed to elim inate the necessity of starch . It is said to perform satisfactorily on such cotton garments a s shirts, children's playclothes a n d women's house dresses, a n d to be perm anent. (No. 074). A new wool dye is sa id to be eg u ally fast to w ash in g , se a w ater, a n d se a w a te r spotting. It is d escribed a s a m etallized dye, recommended for m en's a n d w om en's w e a r, tropical suitings, b ath in g a n d sw eatin g y arn s, a n d upholstery fabrics. (No. 077) USI A self-curing neoprene putty for patching parts of goods m olded from N eoprene, Buna S. Hycar, a n d rubber, an d for use a s a caulking and g ask et cem ent, is now av a ila b le . It is stated to h a v e good w ater, oil, acid, alk ali, and flame resistan ce. (No. 078) USI A w eatherproof a n d w aterproof glue, claimed to be inexpensive an d to h a v e superior binding strength, is claim ed to last longer than the pieces of plyw ood w hich it bonds. It is stated to have p a s se d the 3-hour boiling test w ith surplus strength. (No. 079) USI. O n e section of U .S .I.’s B a ltim o re L a b o r a to ry is d e v o te d to the p ro d u c t-e v a lu a tio n of a ll ty p e s o f p lasticize rs. T he tech n icia n s h o w n h ere is te stin g a p la sticize r in the “ creep b o x . ”. In d u s t r ia l. F urther inform ation on these item s m ay be obtained by luriting to U.S.I.. USI A new m ulti-purpose plasticizer, w hich the m anufacturer claim s can be used a s a softener, a n d a s a n im prégnant for w aterproof a n d grease­ proof p a p e r coating a s w ell, is described as a viscous, clear-am ber, resinous oil. (No. 075) USI To rem ove p ain t a n d enam els is the purpose of a new com pound w hich is sta te d to be non-in­ flam m able. It is claim ed that this com pound can p en etrate, loosen, a n d rem ove 8 coats of paint in approxim ately 30m inutes. (No. 076). P h e n o lic R esins ( C ontinued ¡rom preceding page). T E C H N IC A L D E V E L O P M E N T S. (U.S.I.J. BRANCHES. IN T E R M E D IA T E S , Acetoacetanilide Acetoacet-ortho-anisidide Acetoacet-ortho-chloranilide Acetoacet-ortho-toluidide Acetoacet-para-chloranilide Alpha-acetylbutyrolactone S-Chloro-2-pentanone 5-Diethylamino-2-pentanone Ethyl Acetoacetate Ethyl Benzoylacetate Ethyl Alpha-O xalpropionate Ethyl Sodium Oxalacetate Methyl C yclop rop yl Ketone ET H ER S Ethyl Ether Ethyl Ether A bsolute— A.C.S.. IN. ALL. P R IN C IP A L. C IT IE S. FEED C O N C E N T R A T E S ’ C urbay B-G *C u rb a y Special Liquid •Vacatone 40 ACETONE C h e " :cally Pure R E S IN S Este- G u r u - a l l types C o n g o G um s— raw, fused & esterified •AropJaz— alkyds and allied materials •Arofene— pure phenolics •Arochem — m odified types Natural Resins— all standard grades O T H ER PRODUCTS C ollod io ns Ethylene Ethylene Glycol Urethan Nitrocellulose Solutions.

(21) June, 1946. INDUSTRIAL. AND. ENGINEERING. CHEMISTRY. A L U M IN A S. FOR. C A T A L Y T IC. 21. PU RPO SES. A C T IV A T E D A L U M I N A S <F S E R IE S ). (tot cCefiettcUtty, <ut LUCK when you employ chemically controlled Alorco Aluminas JNatures a lo t lik e A u n t Bessie— pro b ab ly averages out well as a com pounder, b u t lik ely to vary enough to m ake in d iv id u al results m ighty u ncertain. T h ere’s no such u n certain ty w hen you’re w orking w ith Alorco A lum inas in y o u r catalytic processes—as catalysts, carriers, and auxiliary catalysts. Each lot is exactly lik e th e previous one, because of o u r accurate control of p roduction. R efer to th e list of Alorco A lum inas shown in the table and decide w h at characteristics you need. W e’ll send sam ples fo r tria l and then m ake certain th a t you get id en tical p ro p erties tim e after tim e. ALUM INUM ORE COM PANY, S ubsidiary of A l u m i n u m C o m p a n y o f A m e r i c a , 1911 G ulf B uilding, P ittsb u rg h 19, Pa.. These alum inas p ro d u c e d from crystalline alum i­ num tri-hyd rate a re catalytically active. H a rd granu le s a re a v a ila b le in g r a d e d mesh sizes up to on e inch. V a rio u s g r a d e s a re distinguished b y surface a re a , p orosity a n d s o d a contents a s low a s .1 % . A C T IV A T E D A L U M I N A S ( II S E R IE S ). These alum inas a re la r g e ly am orphous. They h a ve high surfa ce a r e a a n d sorptive ca p a city, high resistance to h e a t a n d live steom . E x p e ri­ m ental lots a r e n ow a v a ila b le in m inu s-20 mesh particles o r a s sph erica l b a lls ' A " to Z i " in diam eter. T A B U L A R ' A L U M IN A S {T S E R IE S }. -These alum inas a re a form o f corundum , h a v in g high strength a n d resistance to a b ra sio n . They a re unaffected b y h igh tem peratures. T h e y are a v a ila b le in g r a d e d mesh gra n u le s a n d as sph erical balls. B a lle d a n d g ra n u la r form s h a ve p o ro sity o f either less than 1 0 % o r a p p r o x i­ m a te ly 3 0 % . OTHER, A L U M IN A S. H y d ra t e d Alum inas, C - 7 0 0 Series, h a v e p articles less than .5 micron. T h e y b ecom e active a fte r b e in g h e a te d to a p p ro x im a te ly 3 0 0 ° C . M o n o ­ h y d ra te d Alum inas, D Series, h a v e p articles a p ­ p ro x im a te ly on e micron in diam eter. T h e y a re sub sta n tia lly inactive ca ta ly tic a lly but h a ve co n sid e ra b le porosity.. S U B S I D I A R Y O F A LU M I N U M. COMP ANY OF AMERI CA.

(22) INDUSTRIAL. AND. ENGINEERING. CHEMISTRY. Vol. 38, No. 6. FOR HIGHER CLEANING STANDARDSBE SPECIFIC Upper: L e ft, cleaner motors. R ight, whiter coveralls. L ow er: De-inked p ap er stock. L eft, with Metso; right, with caustic.. “ M e tso Q ra n. .. .. M otors, p ap e r pulp, floors, coveralls—no m atter w hat it is —it m ust com e cleaner when g iv en a M etso D e te rg e n t b ath . H e r e ’s w hy. The balanced com ponents o f M etso, one p a rt o f sodium oxide com bined an d w o rk in g w ith o n e p art soluble silica insure acce erated cleaning. T h is alkaline pow er, plus the pro p erly proportione soluble silica speeds up w ettin g action, em ulsification, deflocculation, an d th en soluble silica perform s the ad ded unique function of pre­ ve n tin g the rem oved d irt from re d ep o sitin g on the cleaned object.. s o d iu m. 5B ,o ) . ° ' ' e; 0 “' s . p .« "* m etasU icate-. r a n u la r. Hin 100 I * lb ’ . bb aa gg s a n d 300 l b ‘. Start n ow to evaluate these benefits o f M etso balanced soluble silica cleansers in a d eterg en t o p eratio n in your plant. Specify M etso.. .. b a rre ls .. PH ILA DELPHIA Q U A R T Z C O M P A N Y. s9". 5IWV S. ' 5W,3„°;. cate . u 2. 1. 4. 5. 7. g r a n u ia r a n «. . ^. free flow ® 8 ’ l b . s t e e l d ru m s-. %. in 400. D ept. C, 119 South T h ird Street, P hila. 6, Pa. C hicago Sales Office: 205 W est W ack er D rive. ,. BALANCED. DETERGENTS.

(23) June, 1946. ANDLING HOT SU LFITES SINCE NOVEMBER 18, 1929 6 " A lo y c o A lo y c o c a lc iu m. Check. "Y ". V a lv e. b is u lf it e. t a in in g 6 to 7 % 5 to. V a lv e. and. h a n d le. s o lu t io n. 6" hot. con­. t o t a l S 0 2, a n d. à°/0 f r e e S O 2 . A ls o , n o t e. 1 0 ' A lo y c o B lo w V a lv e. in r e a r .. Photos Courtesy o f Eastern Corporation. ALSO INSTALLED NOVEMBER 18,1929 2^ ". A lo y c o. Si. R e lie f V a l v e. h a n d le s. hot. b is u lf it e. c a lc iu m. ® Are you valve conscious? D o corrosion, contam inatio n a b ru p t te m p e ra tu re changes an d o th er rigorous service conditions give you valve trouble? I f so, it will p ay you to get in touch w ith us an d find o u t how Aloyco V alves m the correct analysis of stainless steel can help you install them an d forget th e m .’’ T he photographs here show Aloyco Stainless Steel alves in operation in th e pap er mills of E a ste rn C o r­ p o ratio n since 1929— an d still going strong. T h ey are used in th e toughest spots in the sulfite mill for blowdown an d relief line service.. s o lu t io n c o n t a in i n g about 3 % ïh e. %. t o t a l S 0 2.. in c h. angle. Aloyco Valves are available in a wide range of stainless steels an d corrosion resistan t alloys. L arge selection o f types and sizes for 150 p.s.i. to 600 p.s.i. service. W rite to d ay for detailed inform ation.. s a m p lin g v a l v e s h o w n is a ls o a n A lo y c o .. HOT R ELIEF AND COLD ACID T h is. 8". Aloyco. "Y ". V a lv e. d le s r e l i e f. han­ con­. t a in in g u p t o 8 5 % S O j a n d c o ld a c id ..

(24) 24. INDUSTRIAL. ÄND. ENGINEERING. CHEMISTRY. Vol. 38, No. 6. . . .H ow w ill it work.

(25) June, 1946. INDUSTRIAL. AND. ENGINEERING. CHEMISTRY. w hen it grow s up?. P -I. .. I . - p la n t. r e s u lt s. can. , r ° m PM 0' p la ilt ' ° fa m is h a c c u ra te. c o m m e ' c ia l in f a r m a t ia n. q u a lit y ; b u t t h e y m a y s t ill f a il ta e s t a b lis h fo r. e n g in e e r in g. l : ~. fu ll- s c a le. o p e r a t io n c a n b e c r i t ic a l, a n r e a c t ia n s , y ie ld a n d. m a n y o f th e d e s ig n. fa c to rs. : Cal inSr anCe a9ainS' expensive pi,,a,ls °" d tl6,°ys. ” a ° s ” ‘ ° m. ■n l a r g e - s c a l e u n . t. ? and. r 9 ' n e e r in g p la n t d e s ig n. a n °d "re c o dB f d 9 e r ' ' n Ï. a" d fo r w id e ly. b ' ° a '‘ " '. o ra a rd z t P i '0 ' P r ° C e S S e S in ' ° o r g a n iz a t io n s h o u ld c o m m e n d it s e lf to y o u .. 1“ Badger & SONS CO.. r e q u ir e d. e q u ip m e n t .. E s t. 1841. BOSTON 14 • New York • San Francisco . London. *■> u t i l i z e t h e. 1 - W W . e x p e r ie n c e d d iv e r s if ie d p r o c e s s in d u s t r ie s .. * ' e X p e ' ie " ' e ' s ü c œ s s fu l. P R O C E S S E N G IN E E R S A N D. ^ g ra te d. fa c ilit ie s ,. 'h is p r o g r e s s iv e. C O N STR U C TO R S FO R. THE. CH EM ICAL, PETRO -CH EM ICAL AND PETROLEUM INDUSTRIES.

(26) 26. INDUSTRIAL. AND. ENGINEERING. Unlike the fam iliar orthophosphates and pyrophos­ phates, Calgon* is a glassy ra th e r th a n a crystalline sodium phosphate. H idden in the unknown stru ctu re of this sodium phosphate glass are properties of great industrial utility. Calgon sequesters m etallic ions in the form of soluble complexes; it aids in th e dispersion of pigm ents; it is adsorbed on m etal surfaces, thus inhibiting corrosion. These properties are developed in Calgon by the m ethod of preparation. Soda ash and phosphoric acid are fused together, and this red-hot m elt is cooled quickly, to prevent crystallization. L et th e m elt cool slowly, so th a t crystallization does take place—and these useful properties are lost. F u n d am en tal scientific knowledge concerning the "w h y ” of Calgon’s exceptional properties is still far from com plete, b u t sixteen years of experience have provided th e "how ” of effective and economical appli­ cation o f these properties in th e conditioning of w ater. CHEMISTRY. Vol. 38 No. 6. for the m ost varied uses and in th e processing of industrial products of the m ost varied types. Our chem ists will be glad to give you any information which is available concerning the use of Calgon in processes in which you are interested.. X -ray diffraction p attern s—which ''finger' p rin t” distinctively each crystalline sub­ stance— show Calgon to be devoid of crystalline structure. 1 W A T E R -S O L U B L E S O D IU M M E T A P H O S P H A T E. 2. W A T E R -IN S O L U B L E S O D IU M M E T A P H O S P H A T E. 3. CALGON G LA SS. * 7 . M TRcg. U .S . Pel-. A S U B S ID IA R Y O F H A G A N C O R P O R A T IO N. H A G A N BU ILD ING P ITT SBU RG H 3 0 , PA..

(27) June, 1946 I N D U S T R I AL. ÄND. ENGINEERING. CHEMISTRY. C ° h e o s io n p r o b le m s e n c o u n te r e d in h a n d lin g ac id v a p o rs a r e re a d ily solved th rough the u se of SK corrosion re sistan t S team Jet V acuum P um ps. Lined w ith K arbate, H a v eg or o th er corrosion re sist­ in g m ateria ls, destru ctiv e v ap o rs n ev e r com e in contact w ith th e m etal b ra cin g w hich su p p lies stren g th a n d shock-resist­ an t qualities. SK H igh V acuum Ejectors for corrosive service a re m a d e in sin g le a n d m ulti­ sta g e s w ith sto n ew a re, H aveg, ru b b e r lin ed or p lastic lined in ter-co n d en sers for v a c u a a s low a s 1 m /m of mer-. You c a n h a v e confidence in SK C orrosion R esistant Ejectors a s th ey a re b a c k e d b y m a n y y e a rs ' ex p e rien ce in th e d esig n a n d m a n u fa c tu re of jet equipm ent. The S chutte & K oerting C o m p a n y h a v e p io n eered the d evelopm ent of H igh V acuum Ejectors a n d le a d e rsh ip in this field* h a s b e e n m a in ta in e d b y co n stan t pro d u ct im p ro v e­ m ent. SK e n g in e e rs a r e re a d y to h elp in solving y o u r v ac u u m problem s. W rite to d a y for Bulletin 5-EH w hich illu stra te s a n d d e­ scrib e s m a n y ty p e s of SK S te am Jet. S C H U T T E H t e ? EMIPMtKT-SnWIKHS I tm O S O S AHD ttu m / X S ’ 1,15 * w m k i q j 1m r o w w dim tors « f i x tjjes . m m ■ i m » m tfius m m m i m ■ ee*ï pumps. o. 27. &. K O E R T I N G. CO.. £*tÿcttee't& Î 760 Thom pson Street. P h i l a d e l p h i a 22, Pa..

Cytaty

Powiązane dokumenty

FOR THAT TOUGH CORROSION PROBLEM SP ECIFY GENERAL CERAM ICS COMPANY CHEMICAL STONEWARE OR PORCELAIN GENERAL CERAMICS COMPANY STONEWARE CASCADE TOWERS A vailable in sizes up to 48"

The change in the wet-bulb temperature caused by the presence of a soluble salt is an increase in temperature sufficient to equalize the vapor pressure of the salt

terized b y an induction period in which sm all am ounts of carbon dioxide are produced a t a steadily increasing rate, suggesting th e form ation of an interm ediate on

From wjr data we find that 870,000,000 pounds of ferrous sulfate and '>90,000,000 pounds of sulfuric acid are available in the annual production of spent pickling liquor.. Those

4 .-FLUID HANDLING General Ceramics Armored Centrifugal Pumps For Moving Corrosive Liquids When flowsheets call for the continuous, trouble-free movement of corrosive liquids, it

By the use of high quality eggs dried from the frozen state lyophilized, egg powders were obtained that could be reconstituted to egg pulp equal to the starting mate­ ESPITE the

ties were investigated. The unsaturation, as estimated from analytical data by the method of Kemp and Peters {15), showed that for complete vulcanization at

It was the purpose of the present investigation to determine the retention of ascorbic acid during canning operations at three California and four Arizona grapefruit