Dokument pobrany przez: Zadanie

MODEL ODPOWIEDZI I SCHEMAT PUNKTOWANIA

Poziom rozszerzony

Zadanie

Odpowiedzi Uwagi

Punktacja

]DF]\QQRĞü za zadanie

1

±]DSUDZLGáRZHX]XSHáQLHQLHWDEHOL

=DSLVRJyOQ\NRQ¿JXUDFML

HOHNWURQyZZDOHQF\MQ\FK 1D]ZDJUXS\ 6\PEROEORNX

HQHUJHW\F]QHJR :]yURJyOQ\

WOHQNX

QV¹ litowce s X2O

Q±G³ QV² wanadowce d X2O5

QV²QS² ZĊJORZFH p XO2

1.1 ]DSRSUDZQH

X]XSHáQLHQLH

ZLHUV]\±SNW

ZLHUV]\±SNW ]DZLHUV]

±SNW

2

2 ±]DQDSLVDQLHZ]RUXLRNUHĞOHQLHURG]DMXZLą]DQLD

Z]yUCaCl²       URG]DMZLą]DQLDjonowe

2.1 1

1

3

±]DSRSUDZQ\Z]yUHOHNWURQRZ\

Cl Cl

Cl Cl

8F]HĔRWU]\PXMHSXQNW

]D]DSLV

B B

B B

3.1 1

2

±]DSRGDQLHZNWyU\PUR]SXV]F]DOQLNXFKORUVLĊOHSLHMUR]SXV]F]DLRGQLHVLHQLHWHM

ZáDĞFLZRĞFLGREXGRZ\F]ąVWHF]NL&O²

&KORUOHSLHMUR]SXV]F]DVLĊZUR]SXV]F]DOQLNXQLHSRODUQ\P&]ąVWHF]ND&O² ]DZLHUDZLą]DQLHNRZDOHQF\MQHPDEXGRZĊQLHSRODUQą

3.2 1

4 ±]DSUDZLGáRZHUyZQDQLHSU]HPLDQ\ ²³⁵92

U +

Qĺ

La +

Br + 2 ·

n

t pobrany przez:

5

±]DSUDZLGáRZHZ\SHáQLHQLHFDáHMWDEHOL

Zdanie P/F

6SRĞUyGSRZ\ĪV]\FKL]RWRSyZQDMZLĊNV]ąWUZDáRĞüZ\ND]XMHL]RWRS$ F

&]DVSRáRZLF]QHJRUR]SDGXGODL]RWRSX&Z\QRVLGZDODWD P

3RSLĊFLXODWDFKQDMZLĊFHMUR]SDGQLHVLĊL]RWRSX% F

5.1 1

1

6

D]DSRSUDZQHX]XSHáQLHQLH]GDĔ

3U]HGVWDZLRQHQDU\VXQNX,QDNáDGDQLHVLĊRUELWDOLDWRPRZ\FK2p^x / 2p_\ / 2pzDWRPyZ

WOHQX ] RUELWDODPL ]K\EU\G\]RZDQ\PL DWRPX ZĊJOD SURZDG]L GR SRZVWDQLD ZLą]DĔ

W\SXıʌ

1DU\VXQNX,,SU]HGVWDZLRQRVSRVyEWZRU]HQLDZLą]DĔW\SXıʌNWyUHSRZVWDMąZZ\- QLNXF]RáRZHJRERF]QHJRQDNáDGDQLDVLĊRUELWDOLDWRPRZ\FKS^x / 2py / 2pzDWRPyZ

WOHQX]RUELWDODPLatomowymi]K\EU\G\]RZDQ\PLDWRPXZĊJOD

6.1 1

2 E]DSRSUDZQHX]XSHáQLHQLH]GDĔ

$WRPZĊJODZF]ąVWHF]FHWOHQNXZĊJOD,9Z\ND]XMHK\EU\G\]DFMĊsp / sp² / sp³&]ą- VWHF]ND&2²PDEXGRZĊOLQLRZąNąWRZąSáDVNąSU]HVWU]HQQą

6.2 1

7

D]DSRGDQLHSUDZLGáRZHMRGSRZLHG]LLSRSUDZQHX]DVDGQLHQLH

3RSRGQLHVLHQLXWHPSHUDWXU\XNáDGXZDUWRĞü.zmaleje.

8]DVDGQLHQLH3RGZ\ĪV]HQLHWHPSHUDWXU\XNáDGXGODSURFHVyZHJ]RHQHUJH- W\F]Q\FK]JRGQLH]UHJXáąSU]HNRU\SRZRGXMHSU]HVXQLĊFLHVWDQXUyZQRZDJL

UHDNFMLZOHZRZVWURQĊWZRU]HQLDVXEVWUDWyZ±ZDUWRĞü.PDOHMH

OXELQQHSRSUDZQHX]D- VDGQLHQLHRGQRV]ąFHVLĊ

GRUHJXá\SU]HNRU\

7.1 1

2

E]DSRGDQLHSUDZLGáRZHMRGSRZLHG]L

3R]ZLĊNV]HQLXFLĞQLHQLDZXNáDG]LHZ\GDMQRĞüSURFHVXZ]URĞQLH. 7.2 1

8 ±]DSRSUDZQ\]DNUHVWHPSHUDWXU±ž&   OXE   SRZ\ĪHM ž&GRž& 8.1 1 1

t pobrany przez:

9

±]DSRSUDZQąPHWRGĊ

±]DREOLF]HQLDLZ\QLN]MHGQRVWNą1,57 mol dm³

C V n

m Z

mol dm

mol

dm mola

c

=1 ₃ = 0,04 dm³ =1 ₃ ⋅0,04 dm³ =0,04 zzyli

mol dm

p

n C

C d M C

k = 0,04 mola

1 3

1

100 2 87 2 87

= ⋅

⋅ =

=

% ,

, mmol

dm mola

mole HCl

3

3

1

3 3

2 87

3

V = 1 dm n

0,02 dm 0,04 dm

= ,

–

−

−

= =

=

x x

n C

= 6

2

moli

moli mola mola

mol

2

2

6 2 87 3 13

3 13

– , ,

, d

dm³ = 1, 57 mol dm³

OXELQQDSRSUDZQD

PHWRGD 9.1 1

1

2

10

±]DNDĪG\SRSUDZQLHX]XSHáQLRQ\ZLHUV]WDEHOL

:DUXQNL :]RU\]ZLą]NyZ

3RZSURZDG]HQLXGRZRG\REQLĪDZDUWRĞüS+ NO², Mn2O71+42SO4, C6H5OH

5HDJXMH]PRFQ\PNZDVHPRUD]PRFQą]DVDGą =Q2$O2+3

10.1 2 x 1

2

11

±]DSUDZLGáRZHREVHUZDFMHZRE\GZyFKSUREyZNDFK

3UREyZND:\G]LHODVLĊEUXQDWQ\JD]SRZVWDá\UR]WZyUPDEDUZĊQLHELHVNą

3UREyZND:\G]LHODMąVLĊSĊFKHU]\NLEH]EDUZQHJRJD]XSRZVWDá\UR]WZyU

MHVWEH]EDUZQ\

8F]HĔRWU]\PXMHSXQNW

JG\QDSLV]HĪHZSUR- EyZFHSRZVWDáUR]WZyU

REDUZLH]LHORQRQLHELH- skiejOXEzielonej.

11.1 2 x 1

2

12

±]DSUDZLGáRZHUyZQDQLDUHDNFML

3UREyZNDCu + 2NO^3± + 4H⁺ = Cu²⁺ + 2NO2 + 2H2O 3UREyZND2Al + 6H⁺ = 2Al³⁺ + 3H2

12.1 2 x 1

2

t pobrany przez:

13

D]DSUDZLGáRZHUyZQDQLDSURFHVyZUHGXNFMLLXWOHQLDQLD

5yZQDQLHSURFHVXUHGXNFML I² + 2e^±ĺ,^±  [

5yZQDQLHSURFHVXXWOHQLDQLDI² + 12OH^±ĺ,2^3± + 6H2O + 10e^±

OXELQQ\SRSUDZQ\]DSLV 13.1 2 x 1

E]DSUDZLGáRZ\GREyUZVSyáF]\QQLNyZVWHFKLRPHWU\F]Q\FK 3 6,² + 12.2+ 10.,2.,2³ + 6+²2

OXE3,² + 6.2+ 5.,.,2³ + 3+²2

13.2 1

14

D]DSUDZLGáRZHUyZQDQLHZIRUPLHF]ąVWHF]NRZHM

NaHCO3 + HCl = NaCl + CO2 + H2O

14.1 1

3 E]DRNUHĞOHQLHEDUZ\ZVNDĨQLNDLSUDZLGáRZHUyZQDQLHUHDNFML

%DUZDZVNDĨQLNDQLHELHVND

8]DVDGQLHQLHBaH² + 2H2O = Ba²⁺ + 2OH^± + 2H2

           OXE%D2+²ĺ%D²⁺ + 2OH^±

14.2 1

F]DSUDZLGáRZHREVHUZDFMH:\WUąFLáVLĊEUXQDWQ\RVDGNWyU\ZWHPSHUDWXU]H

SRNRMRZHMSRGRGDQLXQDGPLDUXRGF]\QQLNDQLHUR]SXV]F]DVLĊ /XELQQHSRSUDZQH

RNUHĞOHQLHEDUZ\

8F]HĔRWU]\PXMHSXQNW

MHVOLQDSLV]HĪHosad po dodaniu nadmiaru odczynnika rozpuszcza VLĊWZRU]ąFUR]WZyU REDUZLHĪyáWHM.

14.3 1

15

±]DSRSUDZQąPHWRGĊ

±]DREOLF]HQLDLZ\QLN]MHGQRVWNą0,16 cm³

Ag =0,0001 mol

1 dm = 10 mol dm

= Ag Cl

+

3

–4 3

r

+ –

 



 

 ⋅

I  

 

 

 

 



⋅ ⋅

czyli Cl =

Ag =1,6 10

10 = 1,6 10

– r

+

–10 –4

I ––6

3

3

Cl H

–6

mol dm

= 1 dm czyli = = 1,6 10 mola

pH = 2 =>

– +

V n n ⋅

H

H = 10 mol

dm =1,6 10

10 dm = 1,6 10 dm

+ –2

3 k

–6 –2

3 –4

 



⋅ ⋅

V ³³= 0,16 cm³

OXELQQDSRSUDZQD

PHWRGD 15.1 1

1

2

t pobrany przez:

16

±]DSUDZLGáRZHX]XSHáQLHQLHVFKHPDWyZ

NaNO2(aq)

KMnO_4(aq)

KOH(aq)

K₂Cr₂O_7(aq)

H2SO4

NaNO2(aq)

K₂Cr₂O_7(aq)

1 2 3

-HĪHOLXF]HĔZSUREyZFH

QUZĞUyGRGF]\QQLNyZ

QLHXZ]JOĊGQL+²62⁴WR

RWU]\PXMHSXQNW

8F]HĔQLHWUDFLSXQNWyZ

]DEUDN]DSLVXDT

16.1 3 x 1

3

17

±]DSRSUDZQąPHWRGĊ

±]DREOLF]HQLDLZ\QLN]MHGQRVWNą0,281 mola V1 Â  mol

dm³šs

3RSLHUZV]HMVHNXQG]LHXE\ZDPROD1²2⁵]SU]HVWU]HQLUHDNF\MQHMRREMĊWRĞFL

GP³.

± PROD±SR]RVWDMH1²2⁵SRVHNXQG]LH V2 Â  mol

dm³šs

± 0,281 mola±SR]RVWDMH1²2⁵SRVHNXQG]LH

17.1 1

1

2

18

D±]DSRSUDZQąPHWRGĊ

±]DREOLF]HQLDLZ\QLN]MHGQRVWNą149,33 dm³ m_r =30 100

20š = 150 g

m_ZRG\ J±J J

2EOLF]HQLHáąF]QHMREMĊWRĞFLJD]yZ

J+²2±GP³ +²L2²

J±x x 149,33 dm³

OXELQQDSRSUDZQD

PHWRGD 18.1 1

1

3

E]DZ\EyUZáDĞFLZHMVXEVWDQFMLNaNO³ 18.2 1

t pobrany przez:

19

±]DSRSUDZQąPHWRGĊ

±]DREOLF]HQLDLZ\QLN]MHGQRVWNą 0,059 V

E E C V

E E

Ag Ag C

Ag Ag C

|

|

, log ,

,

+

+

= ° + = +

= ° +

1

2

0 059

1 0 80

0 0

1

5 59

1 logC₂ = +0 80, V−0 059, = +0 741, V 6(0 9±9 0,059 V

OXELQQDSRSUDZQD

PHWRGD 19.1 1

1

2

20

±]DSUDZLGáRZRX]XSHáQLRQ\U\VXQHN

klucz elektrolityczny

Ag Ag

C_1Ag⁺ C_2Ag⁺

.LHUXQHNSU]HSâ\ZXHOHNWURQyZ

( + ) katoda

( – ₎

anoda

20.1 1

1

21

±]DSRSUDZQ\Z]yULQD]ZĊL]RPHUX

:]yU

CH₃

CH₃ H₃C

1D]ZD1,2,3-trimetylocyklopropan

21.1 1

1

t pobrany przez:

22

±]DSUDZLGáRZHX]XSHáQLHQLH]GDĔ

5HDNFMDPHW\OREHQ]HQX]FKORUHPSRGZSá\ZHPĞZLDWáDSU]HELHJD]JRGQLH]PHFKD- QL]PHPQXNOHR¿ORZ\PHOHNWUR¿ORZ\Pwolnorodnikowym3RGZSá\ZHPĞZLDWáD

]F]ąVWHF]HNFKORUXSRZVWDMąwolne rodnikiF]\QQLNLQXNOR¿ORZHF]\QQLNLHOHN- WUR¿ORZH NWyUH DWDNXMą IUDJPHQWalifatyczny  DURPDW\F]Q\ PHW\OREHQ]HQX:ĞUyG

RUJDQLF]Q\FKSURGXNWyZWHMUHDNFML]QDMG]LHVLĊchlorofenylometanFKORURPH- W\OREHQ]HQFKORURPHW\OREHQ]HQ

 5HDNFMD PHW\OREHQ]HQX ] FKORUHP Z REHFQRĞFL FKORUNX JOLQX SU]HELHJD ]JRGQLH

] PHFKDQL]PHP QXNOHR¿ORZ\P  HOHNWUR¿ORZ\P  ZROQRURGQLNRZ\P 3RG ZSá\- ZHPNDWDOL]DWRUD]F]ąVWHF]HNFKORUXSRZVWDMąZROQHURGQLNLF]\QQLNLQXNOR¿ORZH

F]\QQLNLHOHNWUR¿ORZHNWyUHDWDNXMąIUDJPHQWDOLIDW\F]Q\aromatycznyPHW\OREHQ- ]HQX:ĞUyGJáyZQ\FKRUJDQLF]Q\FKSURGXNWyZWHMUHDNFML]QDMG]LHVLĊFKORURIHQ\OR- PHWDQFKORURPHW\OREHQ]HQFKORURPHW\OREHQ]HQ

22.1 2 x 1

2

23

D]DSRSUDZQLH]DSLVDQHUyZQDQLHUHDNFML

CH

CH3 CH3 + HCl(stĊĪ)

OH

CH

CH3 CH3 + H2O Cl

ZnCl2

23.1 1

2

E]DSUDZLGáRZąREVHUZDFMĊ=PĊWQLHQLHSRMDZLDVLĊSRNLONXPLQXWDFK 23.2 1

24

±]DQDSLVDQLHUyZQDQLDUHDNFML

6C + 3H +1

2O = C H OH

grafit 2(g) 2(g) 6 5 (s)

-HĞOLXF]HĔQLHXZ]JOĊG- QLVWDQXVNXSLHQLD UHDJHQWyZRWU]\PXMH

SXQNW

24.1 1

±]DSRSUDZQąPHWRGĊ 3

±]DREOLF]HQLDLZ\QLN]MHGQRVWNą±N-PRO  OXE  ±N-

¨+^R ¨+^1R¨+^2R±¨+^3R

¨+^R ±±±± ±N-

24.2 1

1

t pobrany przez:

25

D]DSRSUDZQąQD]ZĊV\VWHPDW\F]QąRUD]Z]yUVXPDU\F]Q\RGF]\QQLND

1D]ZDNHWRQXpropanon     :]yURGF]\QQLND*ULJQDUGDCH³MgBr

25.1 1

3 E]DSRSUDZQLH]DSLVDQHUyZQDQLDGZyFKHWDSyZ

5yZQDQLHHWDSX MgBr + CO2 = C O OMgBr

5yZQDQLHHWDSX + HBr = C + MgBr2

O OH C

O OMgBr

25.2 2 x 1

26

D]DZ\EyURGSRZLHGQLHMSUREyZNL4 26.1 1

5

E]DZVND]DQLHQXPHUXSUREyZNLRV]D¿URZ\P]DEDUZLHQLX2 26.2 1

F]DSRSUDZQLHVIRUPXáRZDQHREVHUZDFMH:SUREyZFHQLHZLGDü]DPLDQ

QDWRPLDVWZSUREyZFHSRMDZLDVLĊ¿ROHWRZH]DEDUZLHQLH.

OXELQQHSRSUDZQHRNUH-

ĞOHQLHEDUZ\ 26.3 1

G]DSRSUDZQLHX]XSHáQLRQHZQLRVNL]GRĞZLDGF]HQLD

&XNUHPNWyU\QLHZ\ND]\ZDáZáDĞFLZRĞFLUHGXNXMąF\FKMHVWVDFKDUR]D

:SUREyZFHNWyUD]DZLHUDáDIUXNWR]ĊSRZVWDáFHJODVWRF]HUZRQ\RVDG tlenku PLHG]L,DZSUREyZFHZNWyUHME\áDsacharozaRWU]\PDQRF]DUQ\RVDGtlenku PLHG]L,,.

26.4 ]DSRSUDZQ\FK

X]XSHáQLHĔ±SNW

LSRSUDZQHX]X- SHáQLHQLD±SNW

OXEEUDNSR- SUDZQ\FKX]XSHá- QLHĔ±SNW

27

D]DZ\EyURGSRZLHGQLHJRNZDVXLSRSUDZQHX]DVDGQLHQLH

CCl3&22+SRQLHZDĪPDQDMZLĊNV]ąZDUWRĞüVWDáHMG\VRFMDFML 27.1 1 E]DSRSUDZQąRGSRZLHGĨZUD]]X]DVDGQLHQLHP 2

,PZLĊFHMDWRPyZFKORUXZF]ąVWHF]FHNZDVXHWDQRZHJRW\PPRFZLą]DQLD

2±+ZJUXSLHNDUERNV\ORZHMPDOHMH

27.2 1

t pobrany przez:

28

±]DSUDZLGáRZHX]XSHáQLHQLHWDEHOL

Zdanie P/F

&]ąVWHF]NDGRS\Z\ND]XMHF]\QQRĞüRSW\F]Qą P

3RGZ]JOĊGHPEXGRZ\F]ąVWHF]NDGRS\MHVWȕDPLQRNZDVHP F

3RGZSá\ZHPZRGQHJRUR]WZRUXFKORUNXĪHOD]D,,,SU]\MPXMHJUDQDWR-

ZR¿ROHWRZH]DEDUZLHQLH P

28.1 1

1

29

±]DSRSUDZQHX]XSHáQLHQLHUyZQDQLD

+H₃N C H + OH^– + H₂O

CH₂OH COO^–

H₂N C H CH₂OH COO^–

29.1 1

1

30

±]DSUDZLGáRZ\Z]yUIRVIROLSLGX

H₂C O

HC O

H₂C O

C₁₇H₃₅ C

O

C₁₇H₃₅ C

O P O OH

OH

30.1 1

1

t pobrany przez: